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Electrocatalysis

, Volume 9, Issue 6, pp 682–688 | Cite as

Electrodeposited Ternary Fe-Mo-P as an Efficient Electrode Material for Bifunctional Water Splitting in Neutral pH

  • Abheek Datta
  • Ramesh Kumar Singh
  • Hanan Teller
  • Shmuel Rozenfeld
  • Rivka Cahan
  • Alex Schechter
Original Research
  • 347 Downloads

Abstract

Designing novel and cost-effective material for electrochemical water splitting in neutral pH are highly essential for the hydrogen production and useful fuel cell construction. Synthesis of the bifunctional and earth-abundant efficient catalyst systems for the same remains one of the biggest challenges to the science community. Herein, we report the electrodeposition of ternary Fe-Mo-P onto the surface of carbon cloth material to form a stable and highly active bifunctional catalyst towards electrochemical hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) at pH 7. A set of catalysts were prepared by varying the relative atomic ratio of the elements and the best catalytic activity was observed with 60 atomic % Fe in the electroplating bath which rivals that of Pt/C in the overall electrochemical water splitting. The best catalyst also shows 24-h stability in the overall electrochemical splitting of water which indicates the potential of this class of materials.

Graphical Abstract

Keywords

Electrodeposition Bifunctional catalyst Electrochemical water splitting Neutral pH OER HER 

Notes

Funding Information

This research was supported by the Research Authority of Ariel University, Israel, and the Israel Ministry of National Infrastructures, Energy and Water Recourses (grant number: 216-11-015).

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of Chemical SciencesAriel UniversityArielIsrael
  2. 2.Department of Chemical Engineering & BiotechnologyAriel UniversityArielIsrael

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