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Green Synthesis of Silver (Ag) Nanoparticles Using Extract of Apple and Grape and with Enhanced Visible Light Photocatalytic Activity

  • M. ParthibavarmanEmail author
  • S. Bhuvaneshwari
  • M. Jayashree
  • R. BoopathiRaja
Article

Abstract

Silver nanoparticles of 15–25-nm size with spherical shape were synthesized from green synthesis method using apple and grape fruits extract. Synthesized Ag NPs were systematically investigated their optical, surface morphological, photocatalytic, and antibacterial properties. Powder XRD results reveals that Ag nanoparticles with face-centered cubic crystal structure and the results are matched well with the standard value (JCPDS no. 04-0783). The spherical shaped morphology and the average diameter of around 15–25 nm were confirmed through SEM and TEM images. The photocatalytic activities of the catalysts were investigated through the degradation of phenol and congo-red (CR) dye aqueous solutions under visible light irradiation. The results demonstrated that grape extract assisted AgNPs showed more recyclability, high stability (only loss ~ 3%), and superior photocatalytic efficiency towards phenol (95%) and CR (98%) dyes than compared to apple extract assisted AgNPs. The AgNPs were further evaluated for antibacterial activity against Staphylococcus aureus and Escherichia coli, and the results accomplished that AgNPs were more active against all pathogenic bacteria. Hence, it can be used for medical applications.

Keywords

Ag nanoparticles Green synthesis Photocatalyst Visible light Antimicrobial 

Notes

Compliance with Ethical Standards

Conflict of Interest

The authors declare that they have no conflict of interest.

References

  1. 1.
    Abdel Messih, M. F., Ahmed, M. A., Soltan, A., & Anis, S. S. (2017). Facile approach for homogeneous dispersion of metallic silver nanoparticles on the surface of mesoporous titania for photocatalytic degradation of methylene blue and indigo carmine dyes. Journal of Photochemistry and Photobiology A Chemistry, 335, 40–51.CrossRefGoogle Scholar
  2. 2.
    Aronne, A., Fantauzzi, M., Imparato, A. D., De Stefano, L., D'Errico, G., Sannino, F., Rea, I., Pirozzi, D., Elsener, B., Pernice, P., & Rossi, A. (2017). Electronic properties of TiO2-based materials characterized by high Ti3+ self-doping and low recombination rate of electron–hole pairs. RSC Advances, 7, 2373–2381.CrossRefGoogle Scholar
  3. 3.
    Bi, Y. P., Hu, H. Y., Ouyang, S. X., Lu, G. X., Cao, J. Y., & Ye, J. H. (2012). Photocatalytic and photoelectric properties of cubic Ag3PO4 sub-microcrystals with sharp corners and edges. Chemical Communications, 48, 3748–3750.CrossRefGoogle Scholar
  4. 4.
    Choi, Y., Ho, N., & Tung, C. (2007). Sensing phosphatase activity by using gold nanoparticles. Angewandte Chemie, International Edition, 46, 707–709.CrossRefGoogle Scholar
  5. 5.
    Choudhary, T. V., Sivadinarayana, C., Chusuei, C. C., Datye, A. K., Fackler, J. P., Jr., & Goodman, D. W. (2002). CO oxidation on supported nano-au catalysts synthesized from a [Au6(PPh3)6](BF4)2 complex. Journal of Catalysis, 207, 247–255.CrossRefGoogle Scholar
  6. 6.
    Domínguez, M. I., Romero-Sarria, F., Centeno, M. A., & Odriozola, J. A. (2009). Gold/hydroxyapatite catalysts: Synthesis, characterization and catalytic activity to CO oxidation. Applied Catalysis. B, Environmental, 87, 245–251.CrossRefGoogle Scholar
  7. 7.
    Elemike, E. E., Onwudiwe, D. C., Ekennia, A. C., & Nnaji, N. J. (2017). Phytosynthesis of silver nanoparticles using aqueous leaf extracts of Lippia citriodora: Antimicrobial, larvicidal and photocatalytic evaluations. Materials Science and Engineering: C, 75, 980–989.CrossRefGoogle Scholar
  8. 8.
    Fayaza, M., Tiwary, C. S., Kalaichelvan, P. T., & Venkatesan, R. (2010). Blue orange light emission from biogenic synthesized silver nanoparticles using Trichoderma viride. Colloids and Surfaces B Biointerfaces, 75, 175–178.CrossRefGoogle Scholar
  9. 9.
    Haller, G. L., & Resasco, D. E. (1989). Metal-support interaction: Group VIII metals and reducible oxides. Advances in Catalysis, 36, 173–235.Google Scholar
  10. 10.
    Li, J., Fang, W., Yu, C., Zhou, W., & Yu, X. (2015). Ag-based semiconductor photocatalysts in environmental purification. Applied Surface Science, 358, 46–56.CrossRefGoogle Scholar
  11. 11.
    Jin, L., Zhu, G. Q., Hojamberdiev, M., Luo, X. C., Tan, C. W., Peng, J. H., Wei, X. M., Li, J. P., & Liu, P. A. (2014). Plasmonic ag-AgBr/Bi2O2CO3 composite photocatalyst with enhanced visible-light photocatalytic activity. Industrial and Engineering Chemistry Research, 53, 13718–13727.CrossRefGoogle Scholar
  12. 12.
    Kathiravan, V., Ravi, S., & Ashokkumar, S. (2014). Synthesis of silver nanoparticles from Melia dubia leaf extract and their in vitro anticancer activity. Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy, 130, 116–121.CrossRefGoogle Scholar
  13. 13.
    Kholoud, M. M., El-Nour, A., Eftaiha, A., Al-Warthan, A., & Reda Ammar, A. A. (2010). Synthesis and applications of silver nanoparticles. Arabian Journal of Chemistry, 3, 135–140.CrossRefGoogle Scholar
  14. 14.
    Li, S., Zhou, P., Zhang, W., Chen, S., & Peng, H. (2014). Effective photocatalytic decolorization of methylene blue utilizing ZnO/rectorite nanocomposite under simulated solar irradiation. Journal of Alloys and Compounds, 616, 227–234.CrossRefGoogle Scholar
  15. 15.
    Parthibavarman, M., Karthik, M., Sathishkumar, P., & Poonguzhali, R. (2018). Rapid synthesis of novel Cr doped WO3 nanorods an efficient electrochemical and photocatalytic performance. Journal of the Iranian Chemical Society, 15, 1419–1430.CrossRefGoogle Scholar
  16. 16.
    Parthibavarman, M., Sathishkumar, S., & Prabhakaran, S. (2017). Enhanced visible light photocatalytic activity of tin oxide nanoparticles synthesized by different microwave optimum conditions. Journal of Materials Science: Materials in Electronics, 29, 2341–2350.Google Scholar
  17. 17.
    Parthibavarman, M., Vallalperuman, K., Sathishkumar, S., Durairaj, M., & Thavamani, K. (2014). A novel microwave synthesis of nanocrystalline SnO2 and its structural optical and dielectric properties. Journal of Materials Science: Materials in Electronics, 25, 730–735.Google Scholar
  18. 18.
    Smitha, S. L., Nissamudeen, K. M., Philip, D., & Gopchandran, K. G. (2008). Studies on surface plasmon resonance and photoluminescence of silver nanoparticles. Spectrochimica Acta Part A, 71, 186–190.CrossRefGoogle Scholar
  19. 19.
    Sudrik, S., Chaki, N., Chavan, V., & Chavan, S. (2006). Silver nanocluster redox-couple-promoted nonclassical electron transfer: An efficient electrochemical Wolff rearrangement of alpha-diazoketones. European Journal of Chemistry, 12, 859–864.CrossRefGoogle Scholar
  20. 20.
    Tauc, J., Grigorovici, R., & Vancu, A. (1966). Optical properties and electronic structure of amorphous germanium. Physica Status Solidi, 15, 627–637.CrossRefGoogle Scholar
  21. 21.
    Tju, H., Shabrany, H., Taufik, A., & Saleh, R. (2017). Degradation of methylene blue (MB) using ZnO/CeO2/nanographene platelets (NGP) photocatalyst: Effect of various concentration of NGP. AIP Conference Proceedings, 1862, 030037.CrossRefGoogle Scholar
  22. 22.
    Wang, Y. J., Shi, R., Lin, J., & Zhu, Y. F. (2011). Enhancement of photocurrent and photocatalytic activity of ZnO hybridized with graphite-like C3N4. Energy & Environmental Science, 4, 2922–2929.CrossRefGoogle Scholar
  23. 23.
    Williams, D. (2008). The relationship between biomaterials and nanotechnology. Biomaterials, 29, 1737–1738.CrossRefGoogle Scholar
  24. 24.
    Zhu, M. S., Chen, P. L., Ma, W. H., Lei, B., & Liu, M. H. (2012). Template-free synthesis of cube-like ag/AgCl nanostructures via a direct-precipitation protocol: Highly efficient sunlight-driven plasmonic photocatalysts. Applied Materials & Interfaces, 4, 6386–6392.CrossRefGoogle Scholar

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© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.PG and Research Department of PhysicsChikkaiah Naicker CollegeErodeIndia

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