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Environmental Earth Sciences

, 78:640 | Cite as

Comparative study on the removal of toxic metal ions by advanced carbon allotropes and g-C3N4 adsorbents: a case study from Sarcheshmeh copper mine

  • Afshin Akbari DehkharghaniEmail author
Original Article
  • 14 Downloads

Abstract

The sorption properties of graphene oxide nanosheets (GO), functionalized multi-walled carbon nanotubes (f-MWCNTs) and exfoliated graphite like C3N4 (g-C3N4) have been studied to evaluate their potential in treating acid mine drainage (AMD). Few-layered GO nanosheets and exfoliated g-C3N4 were simply fabricated via modified Hummers’ and thermal decomposition methods, respectively. MWCNTs were functionalized in the mixture of both sulfuric and nitric acids. Fabricated nanoadsorbents were characterized by various techniques and then used for metal ion removal of prepared solutions and real AMD samples from Sarcheshmeh copper mine. To investigate the sorption activity, batch adsorption experiments were applied. GO exhibited much higher adsorption capacity toward metal ions than other adsorbents. Besides high surface area, specific groups existing on the GO surface are likely to suggest supplemental parameters, which highly improve the loading capacity in comparison to the f-MWCNTs and exfoliated g-C3N4 adsorbents. Langmuir and Freundlich kinetic models have been implemented to depict and understand the adsorption reaction of metal ions. The results showed that the sorption analysis for all metal ions obeyed the second-order kinetics, and the sorption isotherms were in agreement with Langmuir and Freundlich isotherms. Additionally, cost assessment was done. Fast adsorption kinetics, large adsorption capacity, excellent reusability and the low cost create potentials for GO and g-C3N4 nanoadsorbents to be effective at removing metal ions from aqueous solutions.

Keywords

Advanced carbon allotropes Graphitic carbon nitride Adsorption process Acid mine drainage 

Notes

Acknowledgements

This research in the form of research design “Comparative study on the removal of toxic metal ions by advanced Carbon allotropes and g-C3N4 adsorbents: A case study from Sarcheshmeh Copper Mine” has been done with the support of Islamic Azad University, Central Tehran Branch.

Supplementary material

12665_2019_8656_MOESM1_ESM.docx (14 kb)
Supplementary material 1 (DOCX 13 kb)

References

  1. Abdel Salam M, Al-Zhrani G, Kosa SA (2014) Removal of heavy metal ions from aqueous solution by multi-walled carbon nanotubes modified with 8-hydroxyquinoline: kinetic study. J Ind Eng Chem 20:572–580CrossRefGoogle Scholar
  2. Abedin Khan N, Hasan Z, Jhung SH (2013) Adsorptive removal of hazardous materials using metal-organic frameworks (MOFs): a review. J Hazard Mater 244:444–456CrossRefGoogle Scholar
  3. Agha Beygli R, Mohaghegh N, Rahimi E (2019) Metal ion adsorption from wastewater by g-C3N4 modified with hydroxyapatite: a case study from Sarcheshmeh acid mine drainage. Res Chem Intermed 45:2255–2268CrossRefGoogle Scholar
  4. Akbari Dehkharghani A (2019) Exfoliated graphitic carbon nitride for the fast adsorption of metal ions from acid mine drainage: a case study from the Sungun copper mine. Mine Water Environ 38:335–341CrossRefGoogle Scholar
  5. Cheng Z, Wu Y, Wang N, Yang W, Xu T (2010) Development of a novel hollow fiber cation-exchange membrane from bromomethylated poly(2,6-dimethyl-1,4-phenylene oxide) for removal of heavy-metal ions. Ind Eng Chem Res 49:3079–3087CrossRefGoogle Scholar
  6. Dai YM, Liu WJ, Pan TC, Jehng JM (2012) Surface activation on multi-wall carbon nanotube for electrochemical capacitor applications. Appl Surf Sci 258:3027–3032CrossRefGoogle Scholar
  7. de los Ríos AP, Hernández-Fernández FJ, Lozano LJ, Sánchez S, Moreno JI, Godínez C (2010) Removal of metal ions from aqueous solutions by extraction with ionic liquids. J Chem Eng Data 55:605–608CrossRefGoogle Scholar
  8. Fu F, Wang Q (2011) Removal of heavy metal ions from wastewaters: a review. J Environ Manag 92:407–418CrossRefGoogle Scholar
  9. Gopalakrishnan A, Krishnan R, Thangavel S, Venugopal G, Kim SJ (2015) Removal of heavy metal ions from pharma-effluents using graphene-oxide nanosorbents and study of their adsorption kinetics. J Ind Eng Chem 30:14–19CrossRefGoogle Scholar
  10. Hong J, Chen C, Bedoya FE, Kelsall GH, O’Hare D, Petit C (2016) Carbon nitride nanosheet/metal–organic framework nanocomposites with synergistic photocatalytic activities. Catal Sci Technol 6:5042–5051CrossRefGoogle Scholar
  11. Hu R, Wang X, Dai S, Shao D, Hayat T, Alsaedi A (2015) Application of graphitic carbon nitride for the removal of Pb(II) and aniline from aqueous solutions. Chem Eng J 260:469–477CrossRefGoogle Scholar
  12. Iannazzo D, Pistone A, Ziccarelli I, EsproC Galvagno S, Giofré SV, Romeo R, Cicero N, Bua GD, Lanza G, Legnani L, Chiacchio MA (2017) Removal of heavy metal ions from wastewaters using dendrimer-functionalized multi-walled carbon nanotubes. Environ Sci Pollut Res 24:14735–14747CrossRefGoogle Scholar
  13. Li T, Zhao L, He Y, Cai J, Luo M, Lin J (2013) Synthesis of g-C3N4/SmVO4 composite photocatalyst with improved visible light photocatalytic activities in RhB degradation. App Catal B Environ 129:255–263CrossRefGoogle Scholar
  14. Li X, Pi Y, Wu L, Xia Q, Wu J, Li Z, Xiao J (2017) Facilitation of the visible light-induced Fenton-like excitation of H2O2 via heterojunction of g-C3N4/NH2-iron terephthalate metal-organic framework for MB degradation. Appl Catal B Environ 202:653–663CrossRefGoogle Scholar
  15. Lv Q, Hu X, Zhang X, Huang L, Liu Z, Sun G (2019) Highly efficient removal of trace metal ions by using poly(acrylic acid) hydrogel adsorbent. Mater Des 181:107934CrossRefGoogle Scholar
  16. Minamisawa M, Minamisawa H, Yoshida S, Takai N (2004) Adsorption behavior of heavy metals on biomaterials. J Agric Food Chem 52:5606–5611CrossRefGoogle Scholar
  17. Motsi T, Rowson NA, Simmons MJH (2009) Adsorption of heavy metals from acid mine drainage by natural zeolite. Int J Miner Process 92:42–48CrossRefGoogle Scholar
  18. Ning RY (2002) Arsenic removal by reverse osmosis. Desalination 143:237–241CrossRefGoogle Scholar
  19. Pyrzynska K (2019) Removal of cadmium from wastewaters with low-cost adsorbents. J Environ Chem Eng 7:102795CrossRefGoogle Scholar
  20. Rahimi E, Mohaghegh N (2016) Removal of toxic metal ions from Sungun acid rock drainage using mordenite zeolite, graphene nanosheets, and a novel metal–organic framework. Mine Water Environ 35:18–28CrossRefGoogle Scholar
  21. Rahimi E, Mohaghegh N (2017) New hybrid nanocomposite of copper terephthalate MOF-graphene oxide: synthesis, characterization and application as adsorbents for toxic metal ion removal from Sungun acid mine drainage. Environ Sci Pollut Res 24:1–9CrossRefGoogle Scholar
  22. Rudd ND, Wang H, Fuentes-Fernandez EMA, Teat SJ, Chen F, Hall G, Chabal YJ, Li J (2016) Highly efficient luminescent metal–organic framework for the simultaneous detection and removal of heavy metals from water. ACS Appl Mater Interfaces 8:30294–30303CrossRefGoogle Scholar
  23. Shen C, Chen C, Wen T, Zhao Z, Wang X, Xu A (2015) Superior adsorption capacity of g-C3N4 for heavy metal ions from solutions. J Colloid Interface Sci 456:7–14CrossRefGoogle Scholar
  24. Simate GS, Ndlovu S (2014) Acid mine drainage: challenges and opportunities. J Chem Eng Environ 2:1785–1803CrossRefGoogle Scholar
  25. Skousen J, Zipper CE, Rose A, Ziemkiewicz PF, Nairn R, McDonald LM, Kleinmann RL (2017) Review of passive systems for acid mine drainage treatment. Mine Water Environ 36:133–153CrossRefGoogle Scholar
  26. Wang HQ, Zhang LY, Fang XM, Zhang AN (2017) Modified water treatment residual as flocculant for Microcystis aeruginosa removal and water purification. Int J Environ Sci Technol 14:2543–2550CrossRefGoogle Scholar
  27. Zhang Y, Jiao Z, Hu Y, Lv S, Fan H, Zeng Y, Hu J, Wang M (2017) Removal of tetracycline and oxytetracycline from water by magnetic Fe3O4 @ graphene. Environ Sci Pollut Res 24(3):2987–2995CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Department of Petroleum, Mining and Material EngineeringCentral Tehran Branch, Islamic Azad UniversityTehranIran

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