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Environmental Earth Sciences

, 78:542 | Cite as

Comparative study of mineral and surface waters of Araxá spa, Minas Gerais State, Brazil

  • Daniel Marcos BonottoEmail author
  • Fábio de Oliveira Thomazini
Thematic Issue
  • 36 Downloads
Part of the following topical collections:
  1. Mineral and Thermal Waters

Abstract

The natural mineral waters of the springs Dona Beja (DBS) and Andrade Júnior (AJS) from Araxá city, in the Brazilian State of Minas Gerais (MG), are well known since the nineteenth century when started the studies of their healing properties for the tuberculosis treatment. In Brazil, the period 1930–1950 corresponded to the construction peak of thermal and non-thermal spas for therapeutic and leisure purposes. In 1944, the President Getúlio Vargas inaugurated a large spa at Barreiro area in Araxá city. The DBS waters have low salinity, high radioactivity, discharge sustained by the recharging rainwater, and expected low residence time in the aquifer due to the maximum recharge–discharge distance of 2–3 km. The AJS waters are hypothermal/thermal, alkaline, sulfured, highly saline, exhibiting deep circulation and discharging in a site dominated by slightly weathered rocks. Barreiro area is also characterized by the exploration of phosphate fertilizer (begun in 1947–1948) and niobium (identified in pyrochlore in 1953). Since the 60s and 70s, the demand for these resources increased, favoring the release of contaminants into the environment. As a consequence, several professionals and institutions belonging to different sectors of the society have pointed out potential environmental problems due to possible contamination of the DBS and AJS waters, with implications for reducing the tourism activities in the region that take an important role on the municipality economy. This study compared the major hydrochemical characteristics of the DBS and AJS waters with those of other surface waters and rainwater occurring in that area for identifying possible degradation of their quality due to the anthropogenic inputs taking place there.

Keywords

Dona Beja spring Andrade Júnior spring Niobium mining Phosphate fertilizers production Water quality Mixture of waters 

Notes

Acknowledgements

DMB thanks CNPq (Grant Nos. 301992/2016-9, 400700/2016-6) (National Council for Scientific and Technologic Development) and FAPESP (Grant No. 2018/25332-0) (Foundation for Supporting Research in São Paulo State) in Brazil for financial support of this study. Two anonymous referees are greatly thankful for helpful comments that improved the readability of the manuscript.

References

  1. AAEC (Australian Atomic Energy Commission Research Establishment) (1983) Radionuclide migration around uranium ore bodies: analogue of radioactive waste repositories. Ann Rep, AAEC, Sydney, p 36Google Scholar
  2. APHA (American Public Health Association) (1989) Standard methods for the examination of water and wastewater. APHA, Washington, DCGoogle Scholar
  3. Baskaran M (2011) Handbook of environmental isotope geochemistry. Springer, New YorkGoogle Scholar
  4. Beato DAC, Viana HS, Davis EG (2000) Evaluation and hydrogeological diagnosis of mineral waters aquifers from Barreiro, Araxá, MG, Brazil. In: ABAS (Brazilian Association of Groundwater) (ed) Proc. I Joint World Congress on Groundwater. ABAS, Fortaleza, pp 1–20 (in Portuguese)Google Scholar
  5. Bonotto DM (2006) Hydro(radio)chemical relationships in the giant Guarani aquifer, Brazil. J Hydrol 323:353–386CrossRefGoogle Scholar
  6. Bonotto DM (2010) The Poços de Caldas hot spot: a big blast for nuclear energy in Brazil. Nova Science, New York, p 228Google Scholar
  7. Bonotto DM (2015) 226Ra and 228Ra in mineral waters of southeast Brazil. Environ Earth Sci 74:839–853CrossRefGoogle Scholar
  8. Bonotto DM (2016) Hydrogeochemical study of spas ground waters from southeast Brazil. J Geochem Explor 169:60–72CrossRefGoogle Scholar
  9. Bonotto DM (2017) The dissolved uranium concentration and 234U/238U activity ratio in groundwaters from spas of southeastern Brazil. J Environ Radioact 166:142–151CrossRefGoogle Scholar
  10. Bonotto DM, de Lima JLN (2010) Hydrochemistry and weathering rates on Corumbataí River basin, São Paulo State, Brazil. J Hydrol 383:291–306CrossRefGoogle Scholar
  11. Bonotto DM, Garcia-Tenorio R (2019) Investigating the migration of pollutants at Barreiro area, Minas Gerais State, Brazil, by the 210Pb chronological method. J Geochem Explor 196:219–234CrossRefGoogle Scholar
  12. Bonotto DM, Silveira EG (2003) Preference ratios for mercury and other chemical elements in the Madeira river, Brazil. J S Am Earth Sci 15:911–923CrossRefGoogle Scholar
  13. Bonotto DM, Caprioglio L, Bueno TO, Lazarindo JR (2009) Dissolved 210Po and 210Pb in Guarani aquifer groundwater, Brazil. Radiat Meas 44:311–324CrossRefGoogle Scholar
  14. Borovec Z (1981) The adsorption of uranyl species by fine clays. Chem Geol 32:45–58CrossRefGoogle Scholar
  15. Cowart JB, Osmond JK (1980) Uranium isotopes in groundwater: their use in prospecting for sandstone-type uranium deposits. US DOE, Rep. GJBX-119, vol 80, p 112Google Scholar
  16. Cresswell RG, Bonotto DM (2008) Some possible evolutionary scenarios suggested by 36Cl measurements in Guarani aquifer groundwaters. Appl Radiat Isot 66:1160–1174CrossRefGoogle Scholar
  17. Dannemann FK (2013) Dona Beja–Araxá-Minas Gerais. http://www.recantodasletras.com.br/resenhas/1677087. Accessed 15 Dec 2018 (in Portuguese)
  18. DFPM (Division for Supporting the Mineral Production) (1966) The mining code, the mineral waters code and how applying research in a mineral deposit, 8th ed. DFPM, Rio de Janeiro (in Portuguese)Google Scholar
  19. DNPM (National Department of Mineral Production) (1987) Major mineral deposits of Brazil. DNPM, Brasília (in Portuguese)Google Scholar
  20. Fernandes FRC, Enriquez MA, Alamino RCJ (2011) Mineral resources & territorial sustainability, v. 1. CETEM/MCTI, Rio de Janeiro, pp 283–305Google Scholar
  21. FUNTEC (Minas Gerais Technological Center Foundation) (1984) Ecological conflict diagnosis report including recommended works and measures for mitigation of the ecological impact due to mining, v. 1 and 2. Technical Report. ECOS–Geology, Consulting and Services Ltd., Araxá (in Portuguese)Google Scholar
  22. Gibbs RJ (1970) Mechanisms controlling world water chemistry. Science 170:1088–1090CrossRefGoogle Scholar
  23. Hach (1992) Water analysis handbook. Hach Co., Loveland, p 831Google Scholar
  24. Ivanovich M, Harmon RS (1992) Uranium series disequilibrium: applications to environmental problems, 2nd edn. Clarendon Press, OxfordGoogle Scholar
  25. Krauskopf KB, Bird DK (1995) Introduction to geochemistry. McGraw-Hill Inc., New York, p 647Google Scholar
  26. Langmuir D (1978) Uranium solution-mineral equilibria at low temperatures with applications to sedimentary ore deposits. Geochim Cosmochim Acta 42:547–569CrossRefGoogle Scholar
  27. Lemos Jr MA (2012) Studies for evaluating the capacity of the niobium wastes reservoir. M.Sc. Dissertation, School of Mines, Federal University of Ouro Preto, Ouro Preto (in Portuguese)Google Scholar
  28. Magalhães MC (1945) The spa of Araxá. Medical Association of Argentina, Buenos Aires, p 124 (in Portuguese)Google Scholar
  29. Mourão BM (1992) Hydrological medicine—modern therapy of mineral waters and healing spas. Municipal Secretary of Education, Poços de Caldas (in Portuguese)Google Scholar
  30. Osmond JK, Cowart JB (1976) The theory and uses of natural uranium isotopic variations in hydrology. Energy Rev 14:621–679Google Scholar
  31. Osmond JK, Kaufman MI, Cowart JB (1974) Mixing volume calculations, sources and aging trends of Floridan aquifer water by uranium isotopic methods. Geochim Cosmochim Acta 38:1083–1100CrossRefGoogle Scholar
  32. Piper AMA (1944) A graphic procedure in the geochemical interpretation of water-analyses. Trans Am Geophys Union 25:914–928CrossRefGoogle Scholar
  33. Rice EW, Baird RB, Eaton AD, Clesceri LS (2012) Standard methods for the examination of water and wastewater, 22nd ed. American Public Health Association/American Water Works Association/Water Environment Federation, Washington, DC, p 1496Google Scholar
  34. Santos MS, Carneiro LG, Medeiros G, Sampaio C, Martorell ABT, Gouvea S, Cunha KMD (2011) PIXE analyses applied to characterize water samples. Proc. International Nuclear Atlantic Conference—INAC, ABEN (Brazilian Association of Nuclear Energy), Belo Horizonte, pp 1–6Google Scholar
  35. Szalay A (1964) Cation exchange properties of humic acids and their importance in the geochemical enrichment of UO2 2+ and other cations. Geochim Cosmochim Acta 28:1605–1614CrossRefGoogle Scholar
  36. Traversa G, Gomes CB, Brotzu P, Buraglini N, Morbidelli L, Principato MS, Ronca S, Ruberti E (2001) Petrography and mineral chemistry of carbonatites and mica-rich rocks from the Araxá complex (Alto Paranaíba Province, Brazil). An Acad Bras Cienc 73:71–98CrossRefGoogle Scholar
  37. USGS (United States Geological Survey) (2018) Mineral resources on-line spatial data: Araxá. https://mrdata.usgs.gov/mrds/show-mrds.php?dep_id=10068132. Accessed 29 Jan 2018
  38. van de Wiel HJ (2003) Determination of elements by ICP-AES and ICP-MS. National Institute of Public Health and the Environment (RIVM), Bilthoven, The Netherlands, p 37Google Scholar
  39. Viana HS, Davis EG, Beato DAC, Cabral JAL (1999) Araxá Project: geoenvironmental study of mineral springs. CPRM (Brazilian Geological Survey), Belo Horizonte, pp 1–125 (in Portuguese)Google Scholar
  40. WHO (World Health Organization) (2011) Guidelines for drinking water quality, 4th edn. WHO Press, Geneva, p 541Google Scholar
  41. Young HD (1962) Statistical treatment of experimental data. McGraw Hill, New York, p 172Google Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Instituto de Geociências e Ciências Exatas-IGCEUniversidade Estadual Paulista-UNESPRio ClaroBrazil

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