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Potential effect of environmental pollution on the degree of dissolution of iron and aluminium oxides in lateritic soils

  • Chukwuebuka EmehEmail author
  • Ogbonnaya Igwe
  • Ekenedilichukwu Samuel Onwo
Original Article
  • 28 Downloads

Abstract

Problems associated with surface and groundwater pollution by aluminium and iron is becoming a serious environmental challenge facing the limited sources of quality drinking water. Al and Fe sesquioxides predominates in most of the lateritic soils within the tropical region. Their degree of dissolution and mobility into the surface and groundwater system is determined by the chemistry of the prevailing aqueous environment. This work assessed the potential effect of environmental pollution on the chemical composition of rain and its resultant runoff, hence its contribution to the degree of dissolution of Al and Fe oxides. This was achieved by first determining the sources of pollutants which could possibly affect the physicochemical composition of runoff using remotely sensed information and field observations. Thereafter rain and runoff water samples were collected from theses pre-determined sources, and were analysed for their physicochemical compositions. Similarly, soil samples were also collected from the field and analysed for their mineral and chemical compositions. An empirical method was then employed to determine the degree of dissolution of Fe and Al oxides in aqueous solutions of varying hydrogen ion concentration which was prepared using the combinations of sulphuric acid, nitric acid, ammonium hydroxide, and deionised water. The results revealed that the degree of dissolution of Fe and Al oxides in lateritic soils increases with increasing acidity and/or alkalinity of the aqueous solutions. Increase in the acidity and/or alkalinity of the prevailing rain and runoff was attributed to their high level of ammonium, sulphate, and nitrate content which was introduced into the environment through anthropogenic activities.

Keywords

Environmental pollution Iron oxide Aluminium oxide Dissolution pH Urban runoff 

Notes

Acknowledgements

Authors are grateful to Mr. Asadu, and Mrs. Chiamaka of the Department of Geology, and Mr. Ofomata of Energy research centre of the University of Nigeria, for providing laboratory assistant. They are also grateful to Mr. Chidi Okeugo for providing assistant during the field work and to Miss Anulika Okpalanozie for proofreading and improving the English quality of this work. They also appreciate the effort of petroleum technology development fund and Mrs. Chineyenwa Azubuike for providing financial assistant.

References

  1. Abdalla MA, Jaafar MH, Al-Othman ZA, Alfadoul SM, Ali Khan M (2011) New route for preparation and characterization of magnetite nanoparticles. Arab J Chem 4:235–237CrossRefGoogle Scholar
  2. Akpan-Idiok AU, Ibrahim A, Udo IA (2012) Water quality assessment of Okpauku river for drinking and irrigation uses in Yala, cross rivers, state, Nigeria. Res J Environ Sci 6(6):210–221CrossRefGoogle Scholar
  3. Aluko OO, Sridhar MKC, Oluwande PA (2003) Characterization of leachates from a municipal solid waste landfill site in Ibadan. Niger J Environ Health Res 2(1):32–37Google Scholar
  4. Aniebone VO (2015) Hydrogeochemistry and quality assessment of some ground water samples from Enugu and environs, South–Eastern Nigeria. Glob J Geol Sci 13:15–21CrossRefGoogle Scholar
  5. APHA (1998) Standard methods for examination of water and wastewater, 19th edn. American Public Health Association, WashingtonGoogle Scholar
  6. Arias MM, Barral T, Dias-Fierros F (1995) Effects of iron and aluminium oxides on the colloidal and surface properties of kaolin. Clays Clay Miner 43(4):406–416CrossRefGoogle Scholar
  7. Arlauckas SM, Hurowitz JA, Tosca NJ, McLennan SM (2004) Iron oxide weathering in sulfuric acid: implications for mars. In: 35th lunar and planetary science conference, League City, Texas, abstract no.1868Google Scholar
  8. Arua I, Rao VR (1987) New stratigraphic data on the Eocene Ameki formation, south-eastern Nigeria. J Afr Earth Sc 6(4):391–397Google Scholar
  9. Averill B, Eldredge P (2011) General chemistry: principles, patterns, and applications, vol 1. Saylor Foundation, Arlington, p 854Google Scholar
  10. Brady JB, Boardman SJ (1995) Introducing mineralogy students to x-ray diffraction through optical diffraction experiments using lasers. J Geol Educ 43(5):471–476CrossRefGoogle Scholar
  11. Buechel KH, Moretto H, Werner D (2000) Industrial inorganic chemistry. VCH, New York, pp 29–43CrossRefGoogle Scholar
  12. Buhmann C (1994) Parent material and pedogenic processes in South Africa. Clay Mins 29:239–246CrossRefGoogle Scholar
  13. Bühmann C, Escott BJ, Hughes JC (2004) Soil mineralogy research in South Africa, 1978–2002—a review. S Afr J Plant Soil 21(5):316–329CrossRefGoogle Scholar
  14. Burns DA, Aherne J, Gay DA, Lehmann CMB (2016) Acid rain and its environmental effect: recent scientific advances. Atmos Environ 146:1–4CrossRefGoogle Scholar
  15. Cornell RM, Schwertmann U (2003) The iron oxides, 2nd edn. Wiley-VCH, Weinheim, p 664CrossRefGoogle Scholar
  16. Cronan CS, Schofield CL (1979) Aluminum leaching response to acid precipitation: effects on high elevation watersheds in the Northeast. Science 204:304–306CrossRefGoogle Scholar
  17. Driscoll CT, Schecher WD (1990) The chemistry of aluminum in the environment. Environ Geochem Health 12(1&2):28–49CrossRefGoogle Scholar
  18. Efe SI, Mogborukor JOA (2012) Acid rain in Niger delta region: implication on water resources quality and crisis. Afrrev Stech 1(1):17–46Google Scholar
  19. Egashlra K, Kaetsu Y, Takuma K (1983) Aggregate stability as an index of erodibility of Ando soils. Soil Sci Plant Nutr 29(4):473–481CrossRefGoogle Scholar
  20. Elueze AA, Nton ME, Adejumo SA (2007) Hyrogeochemical assessment of surface and groundwater quality in Agbowo–Orogun area of Ibadan, Southwestern Nigeria. Glob J Geol Sci 5(1&2):13–23Google Scholar
  21. Emeh C, Igwe O (2017) Variations in soils derived from an erodible sandstone formation and factors controlling their susceptibility to erosion and landslide. J Geol Soc India 90(3):362–370CrossRefGoogle Scholar
  22. Emeh C, Igwe O (2018) Effect of environmental pollution on susceptibility of sesquioxide-rich soils to water erosion. Geol Ecol Landsc 2:115–126.  https://doi.org/10.1080/24749508.2018.1452484 CrossRefGoogle Scholar
  23. Enete AA, Madu II, Mojekwu JC, Onyeukwu AN, Onwubuya EA, Eze F (2011) Indigenous agricultural adaptation to climate change: study of Imo and Enugu state in Southeast Nigeria. Africa Technology Policy Studies Network Working Paper. Series No. 53Google Scholar
  24. Environmental Protection Agency (2001) Parameters of water quality interpretation and standards, Environmental Protection Agency, Ireland. www.epa.ie. Accessed 11 Mar 2018
  25. Eze HI (2007) Effect of rain fall intensity and energy on gully development in North eastern Enugu state, Nigeria. Nigerian J Technol 26(1):91–96Google Scholar
  26. Fitzpatrick RW, Schwertmann U (1981) The distribution and nature of secondary magnetic minerals in sesquioxidic soils along the eastern seaboard of South Africa. In: Proceedings of 10th national congress soil science society of Southern Africa, East London. Technical communication No 180, Department of Agriculture, pp 167–168Google Scholar
  27. Frenkel H, Levy GJ, Fey MV (1992) Clay dispersion and hydraulic conductivity of clay-sand mixtures as affected by the addition of various anions. Clays Clay Mins 40:515–521CrossRefGoogle Scholar
  28. Gidigasu MD (1972) Mode of formation and geotechnical characteristics of laterite materials of Ghana in relation to soil factors. Eng Geol 6:79–150CrossRefGoogle Scholar
  29. Goldberg S (1989) Interaction of aluminium and iron oxides and clay mineral and their effect on soil physical properties: a review. Commun Soil Sci Plant Anal 20(11–12):1181–1207CrossRefGoogle Scholar
  30. Göransson A, Eldhuset TD (1987) Effects of aluminium on growth and nutrient uptake of Betula pendula seedlings. Physiol Plantarum 69:193–199CrossRefGoogle Scholar
  31. Hall KJ, Anderson B (1988) The toxicity and chemical composition of urban stormwater runoff. Can J Civ Eng 15:98–106CrossRefGoogle Scholar
  32. Herrmann J (1987) Aluminium impact on freshwater invertebrates at low pH: a review. In: Landner L (ed) Speciation of metals in water, sediments and soil systems. Lecture notes in earth sciences, vol 11. Springer-Verlag, Berlin, pp 157–175Google Scholar
  33. Hill KM (2010) Understanding environmental pollution, 3rd edn. Cambridge University Press, New York, p 562CrossRefGoogle Scholar
  34. Hillman RS (2001) Hematopoietic agents: growth factors, minerals, and vitamins. In: Hardman JG, Limbird LE, Gilman AG (eds) Goodman and Gilman’s, the pharmacological basis of therapeutics, 10th edn. McGraw-Hill, New York, pp 1487–1518Google Scholar
  35. Hoque M, Ezepue MC (1977) Petrology and palaeo-geography of the ajali sandstone. Nig J Min Geol 14(1):16–22Google Scholar
  36. Horner RR, Skupien JJ, Livingston EH, Shaver HE (1994) Fundamentals of urban runoff management: technical and institutional issues. Terrene Inst, WashingtonGoogle Scholar
  37. Ibe KK, Akaolisa CCZ (2010) Sandclass classification scheme for Ajali sandstone units in Ohafia area, Southeastern Nigeria. J Geol Min Res 2(1):016–022Google Scholar
  38. Igwe CA (2005) Erodibility in relation to water-dispersible clay for some soils of Eastern Nigeria. Land Degrad Dev 16:87–96CrossRefGoogle Scholar
  39. Igwe CA, Zarei M, Stahr K (2009) Mineralogy and geochemical properties of some upland soils from different sedimentary formations in South-eastern Nigeria. Aust J Soil Res 47:423–432CrossRefGoogle Scholar
  40. Jia Y, Xi B, Jiang Y et al (2018) Distribution, formation and human-induced evolution of geogenic contaminated groundwater in China: a review. Sci Total Environ 643:967CrossRefGoogle Scholar
  41. Kjeldsen P, Barlaz MA, Rooker AP, Baun A, Ledin A, Christensen TH (2002) Present and long-term composition of MSW landfill leachate: a review. Crit Rev Environ Sci Technol 32(4):297–336CrossRefGoogle Scholar
  42. May HM, Helmke PA, Jackson ML (1979) Gibbsite solubility and thermodynamic properties of hydroxyaluminum ions in aqueous solutions at 25 °C. Geochim Cosmochim Acta 43:861–868CrossRefGoogle Scholar
  43. Mbagwu JSC, Auerswald K (1999) Relationship of percolation stability of soil aggregates to land use, selected structural indices and stimulated rainfall erosion. Soil Till Res 50:197–206CrossRefGoogle Scholar
  44. Norgate TE, Jahanshahi S, Rankin WJ (2007) Assessing the environmental impact of metal production processes. J Clea Prod 15(8):838–848CrossRefGoogle Scholar
  45. Nwajide SC (1979) A lithostratigraphic analysis of the Nanka sands of southeastern Nigeria. J Min Geol 16(2):103–109Google Scholar
  46. Nwajide SC (1990) Cretaceous sedimentation and paleogeography of the central benue trough. In: Ofoegbu CO (ed) The benue. Tough structure and Evolution International Monograph Series, Braunschweig, pp 19–38Google Scholar
  47. Offodile ME (2002) Groundwater study and development in Nigeria, vol 453. Mecon geology and engr. Services ltd., Jos, p 223Google Scholar
  48. Okagbue CO, Ezechi JI (1988) Geotechnical characteristics of soils susceptible to erosion in Eastern Nigeria. Bull Int Assoc Eng Geol 38:111–118CrossRefGoogle Scholar
  49. Okoye JI, Ene GI, Ojobor CC (2016) Physico-chemical and microbiological evaluation of borehole water samples in Enugu, South-Eastern, Nigeria. J Environ Sci Toxicol Food Technol 10(11):16–19Google Scholar
  50. Onwuka OS, Uma KO, Ezeigbo HI (2004) Portability of shallow groundwater in Enugu, Southeast Nigeria. Global J Environ Sci 33(1):33–39Google Scholar
  51. Osweiler GD, Carson TL, Buck WB, Van Gelder GA (1985) Clinical and diagnostic veterinary toxicology. Kendall/Hunt Publishing Company, Dubuque, IowaGoogle Scholar
  52. Oti NN (2002) Discriminant functions for classifying erosion degraded lands at Otamiri, Southeastern Nigeria. Agro Sci 3(1):34–40Google Scholar
  53. Park JY, Seong GH, Baik HH (2001) Characterization of iron(III)oxide nanoparticles prepared by using ammonium acetate as precipitating agent. Korean J Chem Eng 18(2):215–219CrossRefGoogle Scholar
  54. Reyment R (1965) Aspects of the geology of Nigeria. University of Ibadan Press, Ibadan, p 144Google Scholar
  55. Rondeau V, Commenge D, Jacqmin-Gadda H, Dartigues JF (2000) Relation between aluminum concentrations in drinking water and Alzheimer’s disease: an 8-year follow-up study. Am J Epidemiol 152(1):59–66CrossRefGoogle Scholar
  56. Schellmann W (1986) A new definition of laterite. In: Banerji PK (ed) Lateritisation processes. Geological survey of India memoir 120. Pub. by order of the Governor-General of India, 1859, Calcutta, pp 11–17Google Scholar
  57. Schellmann W (2018) An introduction to laterite, products and processes of intensive rock weathering. http://www.laterite.de/. Accessed 13 Mar 2018
  58. Stumm W, Morgan JJ (1970) Aquatic chemistry. Wiley-Interscience, New YorkGoogle Scholar
  59. Tiwari S, Manoj KS, Bisht DS (2007) Chemical composition of rainwater in Panipat, an industrial city in Haryana. Indian J Radio Space Phys 37:443–449Google Scholar
  60. Townsend FC, Reeds LW (1971) Effects of amorphous constituents on some mineralogical and chemical properties of a Panamanian latosol. Clays Clay Miner 19:303–310CrossRefGoogle Scholar
  61. Ubani EC, Onyejekwe IM (2013) Environmental impact analyses of gas flaring in the Niger delta region of Nigeria. Am J Sci Ind Res 4(2):246–252Google Scholar
  62. Wang T, Mülle DB, Graedel TE (2007) Forging the anthropogenic iron cycle. Environ Sci Technol 41(14):5120–5129CrossRefGoogle Scholar
  63. World Health Organization (1996) Guidelines for drinking-water quality, Health criteria and other supporting information, vol 2, 2nd edn. World Health Organization, GenevaGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Chukwuebuka Emeh
    • 1
    Email author
  • Ogbonnaya Igwe
    • 1
  • Ekenedilichukwu Samuel Onwo
    • 1
  1. 1.Department of GeologyUniversity of NigeriaNsukkaNigeria

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