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Removal of ferricyanide ions from aqueous solutions using modified red mud with cetyl trimethylammonium bromide

  • Nazanin Deihimi
  • Mehdi IrannajadEmail author
  • Bahram Rezai
Original Article
  • 51 Downloads

Abstract

The reuse of red mud, an industrial waste found in alumina productions, is an efficient method to decrease the disadvantages of the industrial operation. In this study, red mud has been modified (ABC) with the surfactant of cetyl trimethylammonium bromide (CTAB) and used as a new adsorbent for the removal of ferricyanide anions from aqueous solution. The CTAB changed the charge of red mud to positive charge in a concentration above the critical micelle concentration that efficiently reduced the negative charge repulsion force between the adsorbent surface and ferricyanide anions. The equilibrium studies using two- and three-parameter models showed that the adsorption process followed the Freundlich model in which ferricyanide adsorption onto ABC was heterogeneous with a multilayer adsorption. The kinetic studies have been carried out with the consideration of pseudo-first-order, pseudo-second-order, Elovich and intraparticle diffusion models, which displayed the chemisorption interaction by intraparticle diffusion as a controlling step. Thermodynamic studies indicated that the ferricyanide adsorption process onto ABC was endothermic and spontaneous.

Keywords

Cyanide Experimental design Kinetics Langmuir isotherm Red mud Surface adsorption 

Notes

References

  1. Antunes E, Jacob MV, Brodie G, Schneider PA (2017) Silver removal from aqueous solution by biochar produced from biosolids via microwave pyrolysis. J Environ Manag 203:264–272CrossRefGoogle Scholar
  2. Asgari G, Roshani B, Ghanizadeh G (2012) The investigation of kinetic and isotherm of fluoride adsorption onto functionalize pumice stone. J Hazard Mater 217–218:123–132.  https://doi.org/10.1016/j.jhazmat.2012.03.003 CrossRefGoogle Scholar
  3. Botz M, Mudder T, Akcil A (2016) Cyanide treatment: physical, chemical, and biological processes. In: Gold ore processing, 2nd edn. Elsevier, Oxford, pp 619–645Google Scholar
  4. Chen G, Han B, Yan H (1998) Interaction of cationic surfactants with iron and sodium montmorillonite suspensions. J Colloid Interface Sci 201:158–163CrossRefGoogle Scholar
  5. Deihimi N, Irannajad M, Rezai B (2018) Characterization studies of red mud modification processes as adsorbent for enhancing ferricyanide removal. J Environ Manag 206:266–275CrossRefGoogle Scholar
  6. Eriksson LT, Claesson PM, Eriksson JC, Yaminsky VV (1996) Equilibrium wetting studies of cationic surfactant adsorption on mica: 1. Mono-and bilayer adsorption of CTAB. J Colloid Interface Sci 181:476–489CrossRefGoogle Scholar
  7. Foo KY, Hameed BH (2010) Insights into the modeling of adsorption isotherm systems. Chem Eng J 156:2–10.  https://doi.org/10.1016/j.cej.2009.09.013 CrossRefGoogle Scholar
  8. Gheju M, Balcu I, Enache A, Flueras A (2017) A kinetic approach on hexavalent chromium removal with metallic iron. J Environ Manag 203:937–941Google Scholar
  9. Jorfi S, Soltani RDC, Ahmadi M, Khataee A, Safari M (2017) Sono-assisted adsorption of a textile dye on milk vetch-derived charcoal supported by silica nanopowder. J Environ Manag 187:111–121CrossRefGoogle Scholar
  10. Li D, Ding Y, Li L, Chang Z, Rao Z, Lu L (2015) Removal of hexavalent chromium by using red mud activated with cetyltrimethylammonium bromide. Environ Technol 36:1084–1090.  https://doi.org/10.1080/09593330.2014.975286 CrossRefGoogle Scholar
  11. Liang W, Couperthwaite SJ, Kaur G, Yan C, Johnstone DW, Millar GJ (2014) Effect of strong acids on red mud structural and fluoride adsorption properties. J Colloid Interface Sci 423:158–165.  https://doi.org/10.1016/j.jcis.2014.02.019 CrossRefGoogle Scholar
  12. Lin S-H, Juang R-S (2009) Adsorption of phenol and its derivatives from water using synthetic resins and low-cost natural adsorbents: a review. J Environ Manag 90:1336–1349CrossRefGoogle Scholar
  13. Luo Y-Y, Du Z-P, Lu Y-H, Liu B-X (2009) Adsorption of CTAB on zeolite a detected by surfactant ion-selective electrode. Tenside Surf Deterg 46:175–178CrossRefGoogle Scholar
  14. Nadeem M, Mahmood A, Shahid S, Shah S, Khalid A, McKay G (2006) Sorption of lead from aqueous solution by chemically modified carbon adsorbents. J Hazard Mater 138:604–613CrossRefGoogle Scholar
  15. Ntemi AM (2013) An evaluation of the current situation of cyanide waste disposal and treatment methods. Freie Universität, BerlinGoogle Scholar
  16. Orlov SN, Burkov KA, Skripkin MYu (2013) Adsorption of phosphate ions from water solutions on a red mud. Water Chem Ecol 12:117–122Google Scholar
  17. Pan J, Guan B (2010) Adsorption of nitrobenzene from aqueous solution on activated sludge modified by cetyltrimethylammonium bromide. J Hazard Mater 183:341–346CrossRefGoogle Scholar
  18. Paria S, Khilar KC (2004) A review on experimental studies of surfactant adsorption at the hydrophilic solid-water interface. Adv Colloid Interface Sci 110:75–95.  https://doi.org/10.1016/j.cis.2004.03.001 CrossRefGoogle Scholar
  19. Pichinelli BC, da Silva MSG, da Conceição FT, Menegário AA, Antunes MLP, Navarro GRB, Moruzzi RB (2017) Adsorption of Ni (II), Pb (II) and Zn (II) on Ca (NO3) 2-neutralised red mud water. Air Soil Pollut 228:24CrossRefGoogle Scholar
  20. Rubinos DA, Barral MT (2013) Fractionation and mobility of metals in bauxite red mud. Environ Sci Pollut Res Int 20:7787–7802.  https://doi.org/10.1007/s11356-013-1477-4 CrossRefGoogle Scholar
  21. Saadi R, Saadi Z, Fazaeli R, Fard NE (2015) Monolayer and multilayer adsorption isotherm models for sorption from aqueous media Korean. J Chem Eng 32:787–799.  https://doi.org/10.1007/s11814-015-0053-7 CrossRefGoogle Scholar
  22. Sadeghalvad B, Azadmehr A, Hezarkhani A (2016) Enhancing adsorptive removal of sulfate by metal layered double hydroxide functionalized quartz-albitophire iron ore waste: preparation, characterization and properties. RSC Adv 6:67630–67642.  https://doi.org/10.1039/c6ra10573d CrossRefGoogle Scholar
  23. Sahu MK (2017) Studies on the utilization of red mud for environmental application. Doctoral dissertationGoogle Scholar
  24. Schwarz M, Lalík V (2012) Possibilities of exploitation of bauxite residue from alumina production. In: Recent researches in metallurgical engineering—from extraction to forming. IntechOpen, pp 1–22Google Scholar
  25. Stavropoulos GG, Papadopoulou M, Papadimitriou K (2015) A kinetic and thermodynamic study of cyanide adsorption in activated carbon. Desal Water Treat 57:21939–21943.  https://doi.org/10.1080/19443994.2015.1127777 CrossRefGoogle Scholar
  26. Taffarel SR, Rubio J (2010) Adsorption of sodium dodecyl benzene sulfonate from aqueous solution using a modified natural zeolite with CTAB. Miner Eng 23:771–779CrossRefGoogle Scholar
  27. Tuzen M, Sarı A, Saleh TA (2018) Response surface optimization, kinetic and thermodynamic studies for effective removal of rhodamine B by magnetic AC/CeO2 nanocomposite. J Environ Manag 206:170–177CrossRefGoogle Scholar
  28. Uppal H et al (2017) Study of cyanide removal from contaminated water using zinc peroxide nanomaterial. J Environ Sci 55:76–85CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Department of Mining and Metallurgical EngineeringAmirkabir University of TechnologyTehranIran

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