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Waste and Biomass Valorization

, Volume 10, Issue 5, pp 1343–1353 | Cite as

Catalytic Performances of Various Solid Catalysts and Metal Halides for Microwave-Assisted Hydrothermal Conversion of Xylose, Xylan, and Straw to Furfural

  • Oktay YemişEmail author
  • Giuseppe Mazza
Original Paper

Abstract

Purpose

Furfural is a multifunctional green chemical and a precursor for many furan-based chemicals. The drawbacks of the current furfural production on industrial scale are the processes with low yields, and the corrosive and non-environmental catalysts are being used in the processes. Here, the one pot catalytic conversion of xylose, xylan, and straw biomass (i.e., wheat straw, triticale straw and flax shives) to furfural was investigated in the only single-phase aqueous system using various solid catalysts and metal halides under microwave irradiation.

Methods

Four different solid catalysts (i.e., Amberlyst®-15 dry, Amberlyst®-36, Nafion®-NR50, and DOWEX 50WX8-200) were tested at selected ranges of temperatures (120–180 °C). Catalytic performance of 14 metal halides (i.e., FeCl3, LaCl3, CrCl3, AlCl3, NiCl2, MnCl2, MgCl2, CaCl2, LiCl, NaCl, KCl, LiBr, LiI, and NaBr) was evaluated at 180 °C. A substrate:liquid ratio of 1:15, a catalyst loading of 10% (w/w), a residence time of 20 min were employed as the fixed microwave process conditions.

Results

The Amberlyst-36 wet was the most efficient heterogeneous catalyst for the conversion of xylose at 180 °C, which resulted in a furfural yield of 25.34%. However, for the conversion of xylan under same reaction conditions, only ~ 1% furfural yield was observed. Among metal halides, FeCl3 was the best catalyst for the microwave-assisted hydrothermal conversion of wheat straw, triticale straw and flax shives to furfural with yields of 35.3, 41.6, and 65.3%, respectively.

Conclusions

Microwave-assisted hydrothermal treatment in the presence of FeCl3 can be applied for both the saccharification of straw biomass and production of furfural from straw biomass.

Graphical Abstract

Keywords

Biomass conversion Microwave-assisted process Furfural Xylose Solid catalyst Metal halides 

Notes

Acknowledgements

The technical aid of Lana Fukumoto and David Godfrey is gratefully acknowledged. The authors would also like to thank the anonymous reviewers for their constructive criticisms and suggestions. Oktay Yemis thanks the Scientific and Technological and Research Council of Turkey (TUBITAK) for the scholarship (BIDEB-2219, Postdoctoral Research Scholarship).

Compliance with Ethical Standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

12649_2017_144_MOESM1_ESM.docx (321 kb)
Supplementary material 1 (DOCX 320 KB)

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Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2017

Authors and Affiliations

  1. 1.Summerland Research and Development CentreAgriculture and Agri-Food CanadaSummerlandCanada
  2. 2.Department of Food Engineering, Faculty of EngineeringSakarya UniversitySerdivanTurkey
  3. 3.Mazza Innovation Ltd.DeltaCanada

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