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Sulfonic Acid-Functionalized Silica-Coated Magnetic Nanoparticles as a Reusable Catalyst for the Preparation of Pyrrolidinone Derivatives Under Eco-Friendly Conditions

  • Zahra Hosseinzadeh
  • Ali RamazaniEmail author
  • Hamideh Ahankar
  • Katarzyna Ślepokura
  • Tadeusz Lis
Original Paper
  • 4 Downloads

Abstract

The surface of silica-coated CoFe2O4 magnetic nanoparticles (CoFe2O4@SiO2), which is resistant to the oxidation due to silicone coating, was functionalized using chlorosulfonic acid and used as an efficient and recyclable catalyst for the preparation of 3-pyrrolin-2-ones from diethyl acetylenedicarboxylate, an aldehyde and aniline in ethanol solvent at 60 °C. In the presented study, some fascinating chracteritics of such catalyst, such as magnetically separable, simple workup and obtaining a high purity of products by simple recrystallization, have been successfully obtained. The structural features of CoFe2O4@SiO2-SO3H catalyst were elucidated by X-ray powder diffraction (XRPD), thermo-gravimetric studying (TGA), scanning electron microscopy (SEM) and FT-IR spectra.

Graphical Abstract

Sulfnic acid-functionalized silica-coated magnetic nanoparticles as a reusable catalyst for the preparation of pyrrolidinone derivatives under eco-friendly conditions

Keywords

Cobalt ferrite Silica-coated Sulfonic acid-functionalized Reusable catalyst Magnetic nanoparticles 3-pyrrolin-2-ones 

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Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.Department of ChemistryUniversity of ZanjanZanjanIran
  2. 2.Department of ChemistryAbhar Branch, Islamic Azad UniversityAbharIran
  3. 3.Faculty of ChemistryUniversity of WrocławWrocławPoland

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