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Magnetic Aluminosilicate Nanoclay: a Natural and Efficient Nanocatalyst for the Green Synthesis of 4H-Pyran Derivatives

  • Ali Maleki
  • Zoleikha Hajizadeh
Original Paper
  • 7 Downloads

Abstract

In this study, the magnetic nanoparticles have been loaded on the halloysite nanotubes (HNTs) as an aluminosilicate clay mineral. Fe3O4/HNTs nanocomposite was fully characterized by Fourier transform infrared (FT-IR) spectroscopy, energy dispersive X-ray (EDX) analysis, thermogravimetric analysis (TGA), field-emission scanning electron microscopy (FE-SEM) image, transmission electron microscope (TEM) image, inductively coupled plasma (ICP) analysis, X-ray diffraction (XRD) pattern and vibrating sample magnetometer (VSM) curve. The performance of the Fe3O4/HNTs as a heterogeneous catalyst was investigated in the synthesis of 4H-pyran derivatives. The high efficiently, mild reaction condition, green solvents and using the eco-friendly and recoverable catalyst are the most advantages of the present work. Moreover, the simple separation and reuse of the Fe3O4/HNTs nanocatalyst were confirmed stability and efficiency of the catalyst after 7 runs.

Keywords

Aluminosilicate nanoclay Green magnetic nanocomposite Halloysite Fe3O4 nanoparticles 4H-Pyran 

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Notes

Acknowledgements

The authors gratefully acknowledge the partial support from the Research Council of the Iran University of Science and Technology.

Supplementary material

12633_2019_69_MOESM1_ESM.doc (242 kb)
ESM 1 (DOC 242 kb)

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Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.Catalysts and Organic Synthesis Research Laboratory, Department of ChemistryIran University of Science and TechnologyTehranIran

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