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Synthesis, Characterization, and Properties of N- Heteroaryl Formamide Derivatives in the Presence of the Al-MCM-41-Nanocatalyst

  • Kianoosh Ahmadi Meleh Amiri
  • Zohreh SaadatiEmail author
  • Zahra Vafayi Bagheri
Original Paper
  • 1 Downloads

Abstract

This study aims to find out an efficient and simple method for N-formylation of different kinds of heteroaryl amines. The method is based on presence of formic acid and use of aluminum nanoparticles, loaded on a regular porous silica MCM-41 (Al-MCM-41), as the catalyst (at 60 °C in a solvent-free condition). The synthesized Al-MCM-41 nanocatalyst with average size 25–35 nm was characterized by FT-IR, SEM and TEM. The results show that the Al-MCM-41 nanocatalyst can provide yields of up 91% between 15 and 30 min for the N-formylation of different aromatic amines. The use of Al-MCM-41 nanocatalysts for the synthesis of N-heteroaryl formamide is reported for the first time in this article.

Graphical Abstract

Keywords

Al-MCM-41 nanocatalyst Heteroaryl amine N-heteroaryl formamide Solvent- free 

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Notes

Acknowledgements

We acknowledge the Islamic Azad University of Omidiyeh. We would also like to thank Mrs. Saedeh Kamalifar for her contribution to this manuscript.

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Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.Department of ChemistryIslamic Azad UniversityOmidiyehIran
  2. 2.Department of ChemistryBirjand UniversityBirjandIran

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