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Development of N-doped carbons from zeolite-templating route as potential electrode materials for symmetric supercapacitors

  • Meng Ren
  • Cheng-yun Zhang
  • Yue-lin Wang
  • Jin-jun Cai
Article
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Abstract

N-doped carbons were fabricated from zeolite-templated carbon via modification with melamine and mild KOH activation. The N-doping treatment and KOH activation slightly lowered the surface areas of pristine zeolite-templated carbon; nonetheless, N-doped carbons with a lower surface area exhibited much higher capacitance and cycling stability as fabricated into symmetric supercapacitor. Significantly, N-doped carbon obtained at 700°C showed a capacitance of 45.7 F/g at 0.1 A/g and 42.0 F/g at 10 A/g for the fabricated supercapacitor with 6 M KOH electrolyte, with 92% retention of initial capacitance as current density increased up to 100-fold. This performance was attributed to the dual contribution of electric double-layer capacitance and pseudo-capacitance. The assembled supercapacitor also exhibited excellent cycling stability, with 91% capacitance retention at 10 A/g after 10000 cycles.

Keywords

zeolite template porous carbon nitrogen-doping chemical activation supercapacitor 

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Notes

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (No. 21506184), Hunan 2011 Collaborative Center of Chemical Technologies for Environmental Benignity & Efficient Resource Utilization, and State Key Laboratory of Powder Metallurgy of Central South University. Dr. Cai also give his special thanks to Prof. Titirici worked at Queen Mary University of London for her kind help on the measurements and discussions for the electrochemical performance.

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Copyright information

© University of Science and Technology Beijing and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Meng Ren
    • 1
    • 2
  • Cheng-yun Zhang
    • 1
  • Yue-lin Wang
    • 1
  • Jin-jun Cai
    • 1
    • 3
  1. 1.Hunan Key Laboratory of Environment Friendly Chemical Process Technology, School of Chemical EngineeringXiangtan UniversityXiangtanChina
  2. 2.State Key Laboratory of Powder MetallurgyCentral South UniversityChangshaChina
  3. 3.School of Engineering Materials & ScienceQueen Mary University of LondonLondonUK

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