In situ non-invasive characterization of pigments and alteration products on the masonry altar of S. Maria ad Undas (Idro, Italy)
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Abstract
A non-invasive characterization study has been performed and here presented for the first time on the masonry altar of S. Maria ad Undas, a parish medieval church on the Idro (Brescia, Italy) lakeshore. The determination of painting materials and of alteration products represent the one of the first steps, together with art history studies, of a wider project aimed to the valorization of the site. Images collected under UV light in fluorescence and reflectance mode provided useful information about the presence of organic residual materials attributable to the application of lost gilding details, while the readability of some particulars was greatly improved with respect to what observable in visible light. Moreover, near infrared (NIR) images led to hypothesize the presence of green earths in green painted areas. Raman and reflectance spectroscopy allowed the identification of the pigments and of several alteration products, such as plattnerite, which derived by the degradation of the lead-based ones, hydromagnesite, gypsum, and niter, as well as of carbon-based depositions.
Keywords
Raman spectroscopy Multispectral imaging Medieval pigments Wall paintingsNotes
Acknowledgements
Authors are grateful to Mgr. F. Pellegrini (Diocese of Brescia) for allowing access and carrying out the investigation and to Dr. M. Vallotti (Catholic University of Brescia). Authors are also indebted to Prof. P.P. Lottici (Department of Mathematical, Physical and Computer Sciences, University of Parma, Italy) for providing the Plattnerite standard.
Funding information
Authors gratefully acknowledge the financial support of Madatec srl (Pessano con Bornago, MI, Italy) in the present investigation.
Supplementary material
S. Maria ad Undas, Idro: a West and South sides; b East side: semicircular apse and bell tower. (GIF 261 kb)
S. Maria ad Undas Altar and Saints attributed names. (GIF 333 kb)
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