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Nano Research

, Volume 12, Issue 11, pp 2808–2814 | Cite as

Butterfly-wing hierarchical metallic glassy nanostructure for surface enhanced Raman scattering

  • Hongyu Jiang
  • Jing Li
  • Chengrong Cao
  • Xiaozhi Liu
  • Ming Liu
  • Yutian Shen
  • Yanhui Liu
  • Qinghua Zhang
  • Weihua Wang
  • Lin GuEmail author
  • Baoan SunEmail author
Research Article
  • 99 Downloads

Abstract

The surface-enhanced Raman spectroscopy (SERS) is a technique for the detection of analytes on the surface with an ultrahigh sensitivity down to the atomic-scale, yet the fabrication of SERS materials such as nanoparticles or arrays of coinage metals often involve multiple complex steps with the high cost and pollution, largely limiting the application of SERS. Here, we report a complex hierarchical metallic glassy (MG) nanostructure by simply replicating the surface microstructure of butterfly wings through vapor deposition technique. The MG nanostructure displays an excellent SERS effect and moreover, a superhydrophobicity and self-cleaning behavior. The SERS effect of the MG nanostructure is attributed to the intrinsic nanoscale structural heterogeneities on the MG surface, which provides a large number of hotspots for the localized electromagnetic field enhancement affirmed by the finite-difference time-domain (FDTD) simulation. Our works show that the MG could be a new potential SERS material with low cost and good durability, well extending the functional application of this kind of material.

Keywords

metallic glassy structural heterogeneities surface enhanced Raman scattering superhydrophobicity butterfly wing 

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Notes

Acknowledgements

The authors would like to thank the support of the National Natural Science Foundation of China (Nos. 51822107, 51671121, 51761135125, and 61888102), the National Key Research and Development Program (No. 2018YFA0703603) and the Strategic Priority Research Program of the Chinese Academy of Sciences (Nos. XDB07030200 and XDB30000000). We appreciate Professor Di Zhang’s deep discussions on the usage of bio-templates. The authors also thank Ruhao Pan and Xianzhong Yang for discussions on collecting Raman spectra, Mo Han Wang for the measurement of UV–vis absorption spectra and Kun Chen for the dielectric coefficient measurement.

Supplementary material

12274_2019_2517_MOESM1_ESM.pdf (1.6 mb)
Butterfly-wing hierarchical metallic glassy nanostructure for surface enhanced Raman scattering

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Copyright information

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Hongyu Jiang
    • 1
    • 2
  • Jing Li
    • 3
  • Chengrong Cao
    • 1
  • Xiaozhi Liu
    • 1
    • 2
  • Ming Liu
    • 1
    • 2
  • Yutian Shen
    • 1
    • 2
  • Yanhui Liu
    • 1
    • 4
  • Qinghua Zhang
    • 1
    • 4
  • Weihua Wang
    • 1
    • 2
    • 4
  • Lin Gu
    • 1
    • 2
    • 4
    Email author
  • Baoan Sun
    • 1
    • 2
    • 4
    Email author
  1. 1.Institute of PhysicsChinese Academy of SciencesBeijingChina
  2. 2.School of Physical SciencesUniversity of Chinese Academy of SciencesBeijingChina
  3. 3.Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijingChina
  4. 4.Songshan Lake Materials LaboratoryDongguanChina

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