Direct observation of epitaxial alignment of Au on MoS2 at atomic resolution
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The morphology and structural stability of metal/2D semiconductor interfaces strongly affect the performance of 2D electronic devices and synergistic catalysis. However, the structural evolution at the interfaces has not been well explored particularly at atomic resolution. In this work, we study the structural evolution of Au nanoparticles (NPs) on few-layer MoS2 by high resolution transmission electron microscope (HRTEM) and quantitative high-angle annular dark field scanning TEM. It is found that in the transition of Au from nanoparticles to dendrites, a dynamically epitaxial alignment between Au and MoS2 lattices is formed, and Moiré patterns can be directly observed in HRTEM images due to the mismatch between Au and MoS2 lattices. This epitaxial alignment can occur in ambient conditions, and can also be accelerated by the irradiation of high-energy electron beam. In situ observation clearly reveals the rotation of Au NPs, the atom migration inside Au NPs, and the transfer of Au atoms between neighboring Au NPs, finally leading to the formation of epitaxially aligned Au dendrites on MoS2. The structural evolution of metal/2D semiconductor interfaces at atomic scale can provide valuable information for the design and fabrication of the metal/2D semiconductor nano-devices with desired physical and chemical performances.
Keywordsatom migration MoS2 in situ TEM metal-semiconductor interface Moiré patterns
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The authors thank Fangtao Li, Hongsheng Fan, and Sibin Duan for helpful discussions. This work was supported by the National Natural Science Foundation of China (Nos. 11604010 and 11674023), 111 Project (No. B170003), and the Fundamental Research Funds for the Central Universities (No. FRF-BD-18-004A).
- Voiry, D.; Fullon, R.; Yang, J.; de Carvalho Castro e Silva, C.; Kappera, R.; Bozkurt, I.; Kaplan, D.; Lagos, M. J.; Batson, P. E.; Gupta, G. et al. The role of electronic coupling between substrate and 2D MoS2 nanosheets in electrocatalytic production of hydrogen. Nat. Mater. 2016, 15, 1003–1009.CrossRefGoogle Scholar
- Seel, S. C. Stress and structure evolution during Volmer-Weber growth of thin films. Ph.D. Dissertation, MIT, Cambridge, 2002.Google Scholar
- Yuan, W. T.; Zhang, D. W.; Ou, Y.; Fang, K.; Zhu, B. E.; Yang, H. S.; Hansen, T. W.; Wagner, J. B.; Zhang, Z.; Gao, Y. et al. Direct in situ TEM visualization and insight into the facet-dependent sintering behaviors of gold on TiO2. Angew. Chem., Int. Ed. 2018, 57, 16827–16831.CrossRefGoogle Scholar