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Nano Research

, Volume 12, Issue 4, pp 733–740 | Cite as

Polychromic carbon black: Laser galvanized multicolour fluorescence display

  • Sharon Xiaodai Lim
  • Kae Lin Wong
  • Zheng Zhang
  • Antonio H. Castro Neto
  • Chorng-Haur SowEmail author
Research Article

Abstract

Recovered carbon black (rCB), a very economical and abundance source of material, is transformed into dazzling multicolour fluorescence and visual display for the first time by way of a scanning focused laser treatment. This laser-initiated process is both straightforward and versatile, catering to both micro- and macro-scopic patterning with the sample in ambient or helium environment. The observed phenomenon is attributed to both chemical and structural induced colouration of rCB powder. Chemically, carbon infusion of oxidised metal occurs when photothermal reaction takes place in ambient. After laser modification with the sample in helium environment, the powder not only fluoresces due to sulphur impurities, control annealing of these powders results in formation of periodic arrangements of carbon nanoparticles. The periodicity of these arrangement falls within the range of visible wavelength, hence contributing to the visually observable rainbow coloured rCB flakes. The patterned sample is also transferrable using PDMS stamps. This in turn broadens the application of this material in flexible electronic devices/displays. Photocurrent measurements show most significant enhancement under yellow light illumination. Furthermore, in the presence of an applied potential, the fluorescence detected from the sample can easily be switched off. All in all, we present a simple process to add multiple functionalities to a material that is both inexpensive and sustainable.

Keywords

recovered carbon black laser modification fluorescence emission photocurrent flexible 

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Notes

Acknowledgements

The authors acknowledge the kind assistance from Dr. Wu Jing in creating the cover design submitted with this work.

Supplementary material

Supplementary material, approximately 37.3 MB.

12274_2018_2239_MOESM2_ESM.pdf (2.9 mb)
Polychromic carbon black: Laser galvanized multicolour fluorescence display

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Copyright information

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Sharon Xiaodai Lim
    • 1
  • Kae Lin Wong
    • 2
  • Zheng Zhang
    • 3
  • Antonio H. Castro Neto
    • 1
    • 4
  • Chorng-Haur Sow
    • 1
    • 4
    Email author
  1. 1.Department of PhysicsNational University of SingaporeSingaporeSingapore
  2. 2.Department of Electrical and Electronic EngineeringUniversiti Tunku Abdul Rahman, Sungai Long CampusKajangMalaysia
  3. 3.Institute of Materials Research EngineeringA*Star (Agency for Science, Technology and Research)SingaporeSingapore
  4. 4.Center for Advanced 2D Materials and Graphene Research CenterNational University of SingaporeSingaporeSingapore

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