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Fibers and Polymers

, Volume 20, Issue 11, pp 2289–2296 | Cite as

Synthesis and Application of Benzotriazole UV Absorbers to Improve the UV Resistance of Polyester Fabrics

  • Chunli Li
  • Wei Ma
  • Xuehong RenEmail author
Article
  • 5 Downloads

Abstract

In this study, 2-(2-hydroxy-4-acryloyl)-2H-benzotriazole (BTHA), a benzotriazole ultraviolet absorber monomer, was synthesized from 2-(2,4-dihydroxyphenyl)-benzotriazole (BTDP) and acryloyl chloride. The synthesized BTHA was characterized by 1H-NMR, FTIR, and ultraviolet spectroscopy, and grafted onto polyester fabrics by the traditional pad-dry-cure (PDC) process. The effects of monomer concentration and initiator concentration on the UPF values of the grafted PET fabrics were studied. The grafted fabrics were characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA). The breaking strength of the grafted PET fabrics was comparable with the original PET fabrics in warp and weft directions. The UV protection factors improved significantly after grafting. The modified PET fabrics exhibited good durability to washing. The grafting of BTHA onto PET fabrics protected the damage of UV light to PET fabrics and decreased the strength loss of PET fabrics after UVA light exposure.

Keywords

Polyester Benzotriazoles UV stability Pad-dry-cure process UV resistant 

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Notes

Acknowledgments

This work was supported by national first-class discipline program of Light Industry Technology and Engineering (LITE2018-21), the Project of Jiangsu Science and Technological Innovation Team, and 111 Projects (B17021).

References

  1. 1.
    M. Ichihashi, M. Ueda, A. Budiyanto, T. Bito, M. Oka, M. Fukunaga, K. Tsuru, and T. Horikawa, Toxicology, 189, 21 (2003).CrossRefGoogle Scholar
  2. 2.
    D. M. Wilmouth, T. F. Hanisco, R. M. Stimpfle, and J. G. Anderson, J. Phys. Chem. A, 113, 14099 (2009).CrossRefGoogle Scholar
  3. 3.
    J. Mamnicka and W. Czajkowski, Cellulose, 19, 1781 (2012).CrossRefGoogle Scholar
  4. 4.
    X. He, M. Wang, C. Zhang, and L. Liu, J. Nanopart. Res., 19, 229 (2017).CrossRefGoogle Scholar
  5. 5.
    J. Cadet and T. Douki, Photochem. Photobiol. Sci., 17, 1816 (2018).CrossRefGoogle Scholar
  6. 6.
    N. A. Ibrahim, B. M. Eid, M. A. Youssef, H. A. Ameen, and A. M. Salah, J. Ind. Text., 42, 353 (2012).CrossRefGoogle Scholar
  7. 7.
    K. Qi, J. H. Xin, W. A. Daoud, and C. L. Mak, Int. J. Appl. Ceram. Technol., 4, 554 (2007).CrossRefGoogle Scholar
  8. 8.
    A. Bozzi, T. Yuranova, I. Guasaquillo, D. Laub, and J. Kiwi, J. Photochem. Photobiol., A, 174, 156 (2005).CrossRefGoogle Scholar
  9. 9.
    Y. W. H. Wong, C. W. M. Yuen, M. Y. S. Leung, S. K. A. Ku, and H. L. I. Lam, AUTEX Res. J., 6, 177 (2006).Google Scholar
  10. 10.
    S. Li, B. Hu, and F. Zhang, J. Nanoelectron. Optoelectron., 12, 1056 (2017).Google Scholar
  11. 11.
    M. Day and D. M. Wiles, J. Appl. Polym. Sci., 16, 175 (1972).Google Scholar
  12. 12.
    S. K. Malik and T. Arora, Man-Made Text. India, 46, 164 (2003).Google Scholar
  13. 13.
    H. Y. Wang, H. U. Guo-Liang, Z. Ying, and X. D. Pan, Mater. Sci. Technol., 16, 582 (2008).Google Scholar
  14. 14.
    K. H. Chung, Y. C. Lin, and A. Y. Lin, Environ. Sci. Pollut. Res. Int., 25, 5911 (2018).CrossRefGoogle Scholar
  15. 15.
    B. A. M. C. Santos, A. C. P. da Silva, M. L. Bello, A. S. Gonçalves, T. A. Gouvêa, R. F. Rodrigues, L. M. Cabral, and C. R. Rodrigues, J. Photochem. Photobiol., A, 356, 219 (2018).CrossRefGoogle Scholar
  16. 16.
    M. Á. Bonet-Aracil, P. Díaz-García, E. Bou-Belda, N. Sebastiá, A. Montoro, and R. Rodrigo, Dyes Pigm., 134, 448 (2016).CrossRefGoogle Scholar
  17. 17.
    C. Liu and X. Ren, J. Polym. Res., 25, 97 (2018).CrossRefGoogle Scholar
  18. 18.
    P. Sundell and F. Sundholm, J. Appl. Polym. Sci., 92, 1413 (2004).CrossRefGoogle Scholar
  19. 19.
    A. R. Katritzky and S. Rachwal, Chem. Rev., 110, 1564 (2010).CrossRefGoogle Scholar
  20. 20.
    D. E. Aultz, Speciality Chemicals, 16, 71 (1996).Google Scholar
  21. 21.
    E. G. Tsatsaroni and I. C. Eleftheriadis, Dyes Pigm., 61, 141 (2004).CrossRefGoogle Scholar
  22. 22.
    W. Ma, X. Jiang, Y. Liu, B. T. Tang, and S. F. Zhang, Chinese Chem. Lett., 22, 1489 (2011).CrossRefGoogle Scholar
  23. 23.
    E. G. Tsatsaroni and A. H. Kehayoglou, Dyes Pigm., 28, 123 (1995).CrossRefGoogle Scholar
  24. 24.
    Z. Cui, X. Li, X. Wang, K. Pei, and W. Chen, J. Mol. Struct., 1054–1055, 94 (2013).CrossRefGoogle Scholar
  25. 25.
    S. Cohen, M. Kolitz-Domb, H. Haham, C. Gelber, and S. Margel, Polym. Adv. Technol., 28, 897 (2017).CrossRefGoogle Scholar
  26. 26.
    M. J. Shin, Y. J. Shin, Y. U. Moon, and J. S. Shin, J. Elastomers Plast., 46, 569 (2013).CrossRefGoogle Scholar
  27. 27.
    R. Li, B. Lv, J. Li, X. Chen, S. Yan, X. Shao, X. Ren, and J. Liang, Fiber. Polym., 16, 1876 (2015).CrossRefGoogle Scholar
  28. 28.
    X. Lin, M. Yin, Y. Liu, L. Li, X. Ren, Y. Sun, and T.-S. Huang, J. Ind. Eng. Chem., 63, 303 (2018).Google Scholar
  29. 29.
    S. Zhang, R. Li, D. Huang, X. Ren, and T. S. Huang, Mater. Sci. Eng., C, 85, 123 (2018).CrossRefGoogle Scholar
  30. 30.
    R. Bail, J. Y. Hong, and B. D. Chin, J. Ind. Eng. Chem., 38, 141 (2016).CrossRefGoogle Scholar
  31. 31.
    R. Li, P. Hu, X. Ren, S. D. Worley, and T. S. Huang, Carbohydr. Polym., 92, 534 (2013).CrossRefGoogle Scholar
  32. 32.
    A. Salisu, M. M. Sanagi, A. Abu Naim, K. J. Abd Karim, W. A. W. Ibrahim, and U. Abdulganiyu, Polym. Bull., 73, 519 (2016).CrossRefGoogle Scholar
  33. 33.
    A. Alberti, S. Bertini, G. Gastaldi, N. Iannaccone, D. Macciantelli, G. Torri, and E. Vismara, Eur. Polym. J., 41, 1787 (2005).CrossRefGoogle Scholar
  34. 34.
    T. Xing, J. Liu, and S. Li, Text. Res. J., 83, 363 (2012).CrossRefGoogle Scholar
  35. 35.
    D. A. Beattie, A. Arcifa, I. Delcheva, B. A. Le Cerf, S. V. MacWilliams, A. Rossi, and M. Krasowska, Colloids Surf., A, 544, 78 (2018).CrossRefGoogle Scholar
  36. 36.
    J. Ding, S. Tang, X. Chen, M. Ding, J. Kang, R. Wu, Z. Fu, Y. Jin, L. Li, X. Feng, R. Wang, and C. Xia, Chem. Eng. J., 344, 594 (2018).CrossRefGoogle Scholar
  37. 37.
    K. Dutt and R. K. Soni, Iran. Polym. J., 22, 481 (2013).CrossRefGoogle Scholar
  38. 38.
    S. Amrollahi, M. Mohseni, and B. Ramezanzadeh, Prog. Org. Coat., 105, 132 (2017).CrossRefGoogle Scholar

Copyright information

© The Korean Fiber Society 2019

Authors and Affiliations

  1. 1.Key Laboratory of Eco-Textiles of Ministry of Education, College of Textiles and ClothingJiangnan UniversityWuxi, JiangsuChina

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