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Fibers and Polymers

, Volume 20, Issue 1, pp 165–176 | Cite as

Influence of Crosslinking Density on Antioxidant Nanocellulose in Bio-degradation and Mechanical Properties of Nitrile Rubber Composites

  • Mohamad Nurul Azman Mohammad Taib
  • Wageeh A. Yehye
  • Nurhidayatullaili Muhd JulkapliEmail author
Article
  • 56 Downloads

Abstract

Nanocellulose antioxidant (Aox-NCC) was used as reinforcement and crosslinking agent in nitrile butadiene rubber (NBR) composites. The crosslinking density and volume of rubber bonded in the matrix were increased up to 3 phr and no significant improvement between 4 phr and 5 phr was recorded. The interactions of gallic acid and NCC was found to occur between the -OH and -COOH groups, as revealed by Fourier Transform Infra-Red (FTIR) and Nuclear Magnetic Resonance (NMR) analysis. Crystallinity index of Aox-NCC was increased more than 11 %, recorded by X-ray diffraction (XRD) analysis. Meanwhile, the thermal stability of Aox-NCC was increased 30°C, analyzed by thermogravimetry (TG). With the addition of 3 phr Aox-NCC, tensile strength and modulus at 500 % for NBR composites were increased significantly up to 20 %. There was no significant improvement on modulus at 100 %, modulus at 300 %, elongation at break and tear strength. The degradability of NBR composites within 6 months period was improved significantly at 5 phr of Aox- NCC. Increase in carbonyl group after soil burial test with the existence of cracks, voids and degradable parts of NBR composites were revealed. This demonstrated that, Aox-NCC plays a secure function to reinforce NBR composites.

Keywords

Cellulose Nanocrystals Biodegradable Composites Morphology 

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Copyright information

© The Korean Fiber Society 2019

Authors and Affiliations

  • Mohamad Nurul Azman Mohammad Taib
    • 1
  • Wageeh A. Yehye
    • 1
  • Nurhidayatullaili Muhd Julkapli
    • 1
    Email author
  1. 1.Nanotechnology & Catalysis Research Centre (NANOCAT), Institute of Postgraduate Studies (IPS)University of MalayaKuala LumpurMalaysia

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