Advertisement

Fibers and Polymers

, Volume 20, Issue 10, pp 2070–2077 | Cite as

Electrospinning Synthesis of ZIF-67/PAN Fibrous Membrane with High-capacity Adsorption for Malachite Green

  • Lina Jin
  • Jian Ye
  • Yin Wang
  • Xinye QianEmail author
  • Mingdong Dong
Article
  • 5 Downloads

Abstract

Metal-organic frameworks (MOFs) exhibit great potential for dye adsorption. However, MOF powder is difficult to remove from aqueous solution, which hinders the practical application of MOFs. Integration of MOFs on polymeric fibrous membrane provides a new strategy to reach the achievements that not only keep the adsorption ability of MOFs for dyes, but also easily remove the MOF/dye complex from water. Here, we successfully synthesize zeolitic imidazole framework-67/polyacrylonitrile (ZIF-67/PAN) fibrous membrane with ZIF-67 loading ratio of 54 % by electrospinning method. The average diameters of ZIF-67 nanoparticles and ZIF-67/PAN fibers are about 200 nm and 0.72 µm, respectively. The adsorption process of MG on ZIF-67 nanoparticles or ZIF-67/PAN fibers followed a pseudo-second-order kinetic model and fitted Langmuir isotherm. The maximum adsorption capacities of ZIF-67 nanoparticles and ZIF-67/PAN fibers are 2545 and 1305 mg·g−1, respectively. After four regeneration cycles, the ZIF-67/PAN fibers membrane still exhibit over 92 % of the original capacity of ZIF-67/PAN fibers. In addition, ZIF-67/PAN fibers also show good adsorption abilities for Congo red (849 mg·g−1) and Basic fuschin (730 mg·g−1). Therefore, ZIF-67/PAN fibers would be as a promising adsorbent for the removal of dye in industrial application because of its simple preparation method, excellent adsorption property, ease of separation and favorable reusability.

Keywords

ZIF-67 Electrospinning Nanofibers Malachite green Adsorption 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 21401081) and the Senior Intellectuals Fund of Jiangsu University (No. 14JDG058).

References

  1. 1.
    S. Nethaji, A. Sivasamy, G. Thennarasu, and S. Saravanan, J. Hazard. Mater., 181, 271 (2010).PubMedCrossRefPubMedCentralGoogle Scholar
  2. 2.
    E. S. Baeissa, J. Alloys Compd., 672, 564 (2016).CrossRefGoogle Scholar
  3. 3.
    D. J. Alderman and R. S. Clifton-Hadley, J. Fish. Dis., 16, 297 (1993).CrossRefGoogle Scholar
  4. 4.
    S. Shanmugam, P. S. Ulaganathan, K. Waminathan, S. Sadhasivam, and Y. R. Wu, Inter. Biodeter. Biodegr., 125, 258 (2017).CrossRefGoogle Scholar
  5. 5.
    Y. Panahian and N. Arsalani, J. Phys. Chem. A, 121, 5614 (2017).PubMedCrossRefPubMedCentralGoogle Scholar
  6. 6.
    B. H. Hameed and T. W. Lee, J. Hazard. Mater., 164, 468 (2009).PubMedCrossRefPubMedCentralGoogle Scholar
  7. 7.
    L. Jin, X. Zhao, X. Qian, and M. Dong, J. Colloid. Interf. Sci., 509, 245 (2018).CrossRefGoogle Scholar
  8. 8.
    N. P. Raval, P. U. Shah, and N. K. Shah, Appl. Clay. Sci., 7, 3407 (2017).Google Scholar
  9. 9.
    J. R. Li, J. Sculley, and H. C. Zhou, Chem. Soc. Rev., 112, 869 (2011).CrossRefGoogle Scholar
  10. 10.
    S. H. Huo and X. P. Yan, J. Mater. Chem., 22, 7449 (2012).CrossRefGoogle Scholar
  11. 11.
    X. Y. Xu, J. Zhang, X. Zhao, H. Fu, C. Chu, P. Wang, and C. C. Wang, ACS Appl. Nano Mater., 2, 418 (2019).CrossRefGoogle Scholar
  12. 12.
    X. Y. Xu, C. Chu, H. Fu, X. D. Du, P. Wang, W. Zheng, and C. C. Wang, Chem. Eng. J., 350, 436 (2018).CrossRefGoogle Scholar
  13. 13.
    J. J. Li, C. C. Wang, H. F. Fu, J. R. Cui P. Xu, J. Guo, and J. R. Li, Dalton Trans., 46, 10197 (2017).PubMedCrossRefPubMedCentralGoogle Scholar
  14. 14.
    Y. Yan, Y. Luo, J. Ma, B. Li, H. Xue, and H. Pang, Small, 14, 1801815 (2018).CrossRefGoogle Scholar
  15. 15.
    Y. Yan, B. Li, W. Guo, H. Pang, and H. Xue, J. Power Sources, 329, 148 (2016).CrossRefGoogle Scholar
  16. 16.
    Y. Yan, H. Xu, W. Guo, Q. Huang, M. Zheng, H. Pang, and H. Xue, Inorg. Chem. Front., 3, 791 (2016).CrossRefGoogle Scholar
  17. 17.
    Y. Yan, T. Wang, X. Li, H. Pang, and H. Xue, Inorg. Chem. Front., 4, 33 (2017).CrossRefGoogle Scholar
  18. 18.
    K. Gupta, D. Gupta, and O. P. Khatri, Appl. Surf. Sci., 476, 647 (2019).CrossRefGoogle Scholar
  19. 19.
    J. J. Li, C. C. Wang, J. Guo, J. R. Cui, P. Wang, and C. Zhao, Polyhedron, 139, 89 (2018).CrossRefGoogle Scholar
  20. 20.
    A. Liu, C. C. Wang, C. Z. Wang, H. F. Fu, W. Peng, Y. L. Cao, H. Y. Chu, and A. F. Du, J. Colloid. Interf. Sci., 730, 512 (2018).Google Scholar
  21. 21.
    Y. Yan, P. Gu, S. Zheng, M. Zheng, H. Pang, and H. Xue, J. Mater. Chem. A, 4, 19078 (2016).CrossRefGoogle Scholar
  22. 22.
    K. Y. A. Lin and H. A. Chang, Chemosphere, 139, 624 (2015).PubMedCrossRefPubMedCentralGoogle Scholar
  23. 23.
    K. Y. A. Lin and W. D. Lee, Appl. Surf. Sci., 361, 114 (2016).CrossRefGoogle Scholar
  24. 24.
    L. Fan, M. Xue, Z. Kang, H. Li, and S. Qiu, J. Mater. Chem., 22, 25272 (2012).CrossRefGoogle Scholar
  25. 25.
    Y. N. Wu, F. Li, H. Liu, W. Zhu, M. Teng, Y. Jiang, and G. Li, J. Mater. Chem., 22, 16971 (2012).CrossRefGoogle Scholar
  26. 26.
    Y. Chen, X. Li, K. Park, W. Lu, C. Wang, W. Xue, F. Yang, J. Zhou, L. Suo, T. Lin, H. Huang, J. Li, and J. B. Goodenough, Chem., 3, 152 (2017).CrossRefGoogle Scholar
  27. 27.
    Q. Niu, J. Guo, B. Chen, J. Nie, X. Guo, and G. Ma, Carbon, 114, 250 (2017).CrossRefGoogle Scholar
  28. 28.
    R. Ostermann, J. Cravillon, C. Weidmann, M. Wiebcke, and B. M. Smarsly, Chem. Commun., 47, 442 (2011).CrossRefGoogle Scholar
  29. 29.
    M. R. Armstrong, K. Y. Y. Arredondo, C. Y. Liu, J. E. Stevens, A. Mayhob, B. Shan, and B. Mu, Ind. Eng. Chem. Res., 54, 12386 (2015).CrossRefGoogle Scholar
  30. 30.
    M. Gao, L. Zeng, J. Nie, and G. Ma, RSC Adv., 6, 7078 (2016).CrossRefGoogle Scholar
  31. 31.
    N. D. Shooto, C. W. Dikio, D. Wankasi, L. M. Sikhwivhilu, F. M. Mtunzi, and E. D. Dikio, Nanoscale Res. Lett., 11, 414 (2016).PubMedPubMedCentralCrossRefGoogle Scholar
  32. 32.
    G. Wang, H. Zhang, J. Wang, Z. Ling, and J. Qiu, Sep. Purif. Technol., 177, 257 (2017).CrossRefGoogle Scholar
  33. 33.
    L. E. Lange, F. O. Ochanda, S. K. Obendorf, and J. P. Hinestroza, Fiber. Polym., 15, 200 (2014).CrossRefGoogle Scholar
  34. 34.
    C. Liu, Y. N. Wu, C. Morlay, Y. Gu, B. Gebremariam, X. Yuan and F. Li, ACS Appl. Mater. Inter., 8, 2552 (2016).CrossRefGoogle Scholar
  35. 35.
    A. F. Gross, E. Sherman, and J. J. Vajo, Dalton T., 41, 5458 (2012).CrossRefGoogle Scholar
  36. 36.
    H. T. Kwon, H. K. Jeong, A. S. Lee, H. S. An, and J. S. Lee, J. Am. Chem. Soc., 137, 12304 (2015).PubMedCrossRefPubMedCentralGoogle Scholar
  37. 37.
    C. Wang, C. Liu, J. Li, X. Sun, J. Shen, W. Han, and L. Wang, Chem. Comm., 53, 1751 (2017).PubMedCrossRefPubMedCentralGoogle Scholar
  38. 38.
    L. N. Jin, X. Y. Qian, J. G. Wang, H. Aslan, and M. Dong, J. Colloid. Interf. Sci., 453, 270 (2015).CrossRefGoogle Scholar
  39. 39.
    X. X. Huang, L. G. Qiu, W. Zhang, Y. P. Yuan, X. Jiang, A. J. Xie, and J. F. Zhu, CrystEngComm, 14, 1613 (2012).CrossRefGoogle Scholar
  40. 40.
    S. Patel and G. Hota, Fiber. Polym., 15, 2272 (2014).CrossRefGoogle Scholar
  41. 41.
    Z. Li, G. Zhou, H. Dai, M. Yang, Y. Fu, Y. Ying, and Y. Li, J. Mater. Chem. A, 6, 3402 (2018).CrossRefGoogle Scholar
  42. 42.
    R. Xu, M. Jia, Y. Zhang, and F. Li, Micropor. Mesopor. Mat., 149, 111 (2012).CrossRefGoogle Scholar
  43. 43.
    X. P. Luo, S. Y. Fu, Y. M. Du, J. Z. Guo, and B. Li, Micropor. Mesopor. Mat., 237, 268 (2017).CrossRefGoogle Scholar
  44. 44.
    H. Liu, L. Chen, and J. Ding, Rsc. Adv., 6, 48884 (2016).CrossRefGoogle Scholar
  45. 45.
    R. U. A. N. Chang-Ping, A. I. Ke-Long, and L. U. Le-Hui, Chinese J. Anal. Chem., 44, 224 (2016).CrossRefGoogle Scholar
  46. 46.
    F. Jiang, D. M. Dinh, and Y. L. Hsieh, Carbohyd. Polym., 173, 286 (2017).CrossRefGoogle Scholar
  47. 47.
    H. Liu, Z. Mo, L. Li, F. Chen, Q. Wu, and L. Qi, J. Chem. Eng. Data, 62, 3036 (2017).CrossRefGoogle Scholar
  48. 48.
    X. Feng, T. Wu, and M. A. Carreon, J. Cryst. Growth, 455, 152 (2016).CrossRefGoogle Scholar
  49. 49.
    X. D. Du, C. C. Wang, J. G. Liu, X. D. Zhao, J. Zhong, Y. X. Li, J. Li, and P. Wang, J. Colloid. Interf. Sci., 506, 437 (2017).CrossRefGoogle Scholar

Copyright information

© The Korean Fiber Society 2019

Authors and Affiliations

  • Lina Jin
    • 1
  • Jian Ye
    • 1
  • Yin Wang
    • 2
  • Xinye Qian
    • 1
    Email author
  • Mingdong Dong
    • 2
  1. 1.Institute for Advanced Materials, and School of Materials Science and EngineeringJiangsu UniversityZhenjiangChina
  2. 2.Center for DNA Nanotechnology (CDNA), Interdisciplinary Nanoscience Center (iNANO)Aarhus UniversityAarhusDenmark

Personalised recommendations