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Food Analytical Methods

, Volume 12, Issue 1, pp 217–228 | Cite as

Metal Organic Framework-Molecularly Imprinted Polymer as Adsorbent in Matrix Solid Phase Dispersion for Pyrethroids Residue Extraction from Wheat

  • Ting Liang
  • Shangshu Wang
  • Ligang Chen
  • Na Niu
Article

Abstract

Metal organic frameworks-molecular imprinting polymers (MOFs-MIPs) were applied as dispersants of matrix solid phase dispersion (MSPD) followed by gas chromatography-tandem mass spectrometry (GC-MS/MS) to selectively analyze pyrethroids in wheat. MOFs-MIPs characterized by a series of instrumental techniques and the adsorption properties researched by isothermal, kinetics, thermodynamics, and selective binding experiments. The results revealed that the MOFs-MIPs had a larger adsorption capacity (474.56 mg g−1) and fast adsorption time (20 min). What is more, MOFs-MIPs-MSPD procedure clearly increased extraction efficiency and decreased the consumption of organic solvent. The better recoveries of pyrethroids were reached by optimizing MSPD conditions. Under the excellent conditions, the linearity ranges of pyrethroids in wheat samples were obtained varying from 10 to 1000 ng g−1; the limits of detection were in the range of 1.8–2.8 ng g−1 and the precisions were lower than 6.3%. At the same time, the method was successfully applied for detection of three pyrethroids residue in six kinds of wheat samples and cyhalothrin residue detected in one wheat was 23.96 ng g−1, which is lower than the maximum residue limits allowed by the Ministry of Agriculture of the People’s Republic of China. The developed MOFs-MIPs-MSPD-GC-MS/MS method displayed high selectivity, absorbability, simplicity, rapidity, sensitivity, and excellent practical food control applicability.

Keywords

Matrix solid phase dispersion Pyrethroids Metal organic framework Gas chromatography-tandem mass spectrometry Molecularly imprinted polymer Wheat 

Notes

Funding

This study was funded by the Fundamental Research Funds for the Central Universities (No. 2572017EB08), Natural Science Foundation of Heilongjiang Province (JJ2018ZR0081, B20170001), Harbin science and technology innovation talent research special funds (2016RAQXJ151), National Natural Science Foundation of China (NSFC 201401019), Heilongjiang Postdoctoral Fund (LBH-Z16009), and China Postdoctoral Science Foundation (2016M591501, 332017T100218).

Compliance with Ethical Standards

Conflict of Interest

Ting Liang declares that she has no conflict of interest. Shangshu Wang declares that he has no conflict of interest. Ligang Chen declares that he has no conflict of interest. Na Niu declares that she has no conflict of interest.

Ethical Approval

This article does not contain any studies with human participants or animals performed by any of the authors.

Informed Consent

Not applicable.

Supplementary material

12161_2018_1353_MOESM1_ESM.docx (108 kb)
ESM 1 (DOCX 108 kb)

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of Chemistry, College of ScienceNortheast Forestry UniversityHarbinChina

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