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Dimethyl Ether Production from Sugarcane Vinasse: Modeling and Simulation for a Techno-economic Assessment

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Abstract

Industrialization and energy demand increase are highlighted as consequences of world population growth for decades. Thereby, aiming to contribute to sustainable processes capable of mitigating the effects resulting from this process, biofuels have been intensively researched, produced and used in recent years. Among the possibilities, dimethyl ether (DME) stands out with great prospects replacing liquefied petroleum gas and diesel due to its potential as clean fuel. This work aims to conjoin the production of DME, a biofuel with great prospects for technical performance, safety, and economy, with a favorable destination for vinasse, the most worrying residue of ethanol production, due to its high polluting potential and large production volume in several countries. A rigorous and robust simulation of direct synthesis of DME from vinasse-derived syngas is performed using Aspen Hysys and its supplements, evaluating the technical and economic aspects of its production in ethanol distilleries. Results of the proposed scenario point that the process is technically feasible, reaching a purity of 99.9%, respecting the minimum required by standard norms. In addition, the designed process achieved yields of 1 kg of DME for each 1.6 kg of syngas. The simulated process presented a total capital cost of 47.1 millions of dollars, operating costs of 14.1 millions of dollars per year, and utilities cost of 11.2 millions of dollars per year. Considering energy cogeneration, an economy of 9.2% was reached, resulting in a production cost of simulated stage of 98.36 US$/tonne of DME and, considering a complete scenario, an accumulated cost of 233.48 US$/tonne of DME. It demonstrates an economic competitiveness for the DME price and ensures a considerable profit margin for the process. Consequently, the investigated DME production scenario emerges as a promising diesel substitute in a realistic scenario.

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Abbreviations

CF:

capital annualized costs (US$/year)

C R :

capital costs (US$)

crf:

capital recovery factor

DME:

dimethyl ether

i :

interest rate

IEA:

International Energy Agency

IRR:

internal rate of return

IT:

income tax

LP steam generation:

low-pressure steam generation

MP steam generation:

medium-pressure steam generation

NRTK – RK:

non-random two liquid model – Redlick-Kwog

OC:

operating costs (US$/year)

P:

pressure (kPa)

Q DME :

mass flow of dimethyl ether produced per year (tonnes/year)

Syngas:

synthesis gas

t :

plant lifetime (year)

T:

temperature (K)

TAC:

total annualized cost (US$/year)

UNCTAD:

United Nations Conference on Trade and Development

UN DESA:

United Nations Department of Economic and Social Affairs

wt:

mass fraction

References

  1. 1.

    United Nations Department of Economic and Social Affairs (2017) World population prospects: the 2017 revision. https://esa.un.org/unpd/wpp/publications/files/wpp2017_keyfindings.pdf. Accessed 22 August 2018

  2. 2.

    International Energy Agency (2017) World energy outlook 2017. https://www.iea.org/weo2017/. Accessed 2 August 2018

  3. 3.

    Statista (2018) Primary energy consumption worldwide from 2005 to 2017, by fuel type (in million tons oil equivalent). https://www.statista.com/statistics/265619/primary-energy-consumption-worldwide-by-fuel/. Accessed 22 September 2018

  4. 4.

    Moradi GR, Parvizian F (2011) An expert model for estimation of the performance of direct dimethyl ether synthesis from synthesis gas. Can J Chem Eng 89:1266–1273. https://doi.org/10.1002/cjce.20558

  5. 5.

    Guo M, Song W, Buhain J (2015) Bioenergy and biofuels: history, status, and perspective. Renew Sust Energ Rev 42:712–725. https://doi.org/10.1016/j.rser.2014.10.013

  6. 6.

    Pascall A, Adams TA (2013) Semicontinuous separation of dimethyl ether (DME) produced from biomass. Can J Chem Eng 91:1001–1021. https://doi.org/10.1002/cjce.21813

  7. 7.

    United Nations Conference on Trade and Development (UNCTAD) (2009) The biofuels market: current situation and alternative scenarios. Geneva and New York

  8. 8.

    Moradi GR, Ahmadpour J, Yaripour F, Wang J (2011) Equilibrium calculations for direct synthesis of dimethyl ether from syngas. Can J Chem Eng 89:108–115. https://doi.org/10.1002/cjce.20373

  9. 9.

    Chen WH, Hsu CL, Wang XD (2016) Thermodynamic approach and comparison of two-step and single step DME (dimethyl ether) syntheses with carbon dioxide utilization. Energy 109:326–340. https://doi.org/10.1016/j.energy.2016.04.097

  10. 10.

    Azizi Z, Rezaeimanesh M, Tohidian T, Rahimpour MR (2014) Dimethyl ether: a review of technologies and production challenges. Chem Eng Process Process Intensif 82:150–172. https://doi.org/10.1016/j.cep.2014.06.007

  11. 11.

    Bakhtyari A, Rahimpour MR (2018) Methanol to dimethyl ether. In: Basile A, Dalena F (eds) Methanol, 1st edn. Elsevier, Cambridge, pp 281–311

  12. 12.

    Boundy B, Diegel S, Wright L, Davis SC (2011) Biomass energy data book, 4th edn. Oak Ridge National Laboratory, Tennessee

  13. 13.

    CEIC (2018) China CN: market price: monthly avg: organic chemical material: dimethyl ether: 99.0% or above. https://www.ceicdata.com/en/china/china-petroleum%2D%2Dchemical-industry-association-petrochemical-price-organic-chemical-material/cn-market-price-monthly-avg-organic-chemical-material-dimethyl-ether-990-or-above. Accessed 15 August 2018

  14. 14.

    Global Petrol Prices (2018) Diesel prices. https://www.globalpetrolprices.com/diesel_prices/. Accessed 20 August 2018

  15. 15.

    Global Petrol Prices (2019) Gasoline prices. https://www.globalpetrolprices.com/gasoline_prices/. Accessed 16 Oct 2019

  16. 16.

    Global Safety Management (2015). Safety data sheet: methanol, lab grade, 4L. https://beta-static.fishersci.com/content/dam/fishersci/en_US/documents/programs/education/regulatory-documents/sds/chemicals/chemicals-m/S25426A.pdf. Accessed [16 Oct 2019]

  17. 17.

    GPC Química (2011) Ficha de Informações de Segurança de Protuto Químico - FISPQ: Metanol (In portuguese). http://www.gpcquimica.com.br/portal/produtos/pdf/metanol/fispq_metanol.pdf/. Accessed 16 Oct 2019

  18. 18.

    Holly Frontier (2017) Safety data sheet: gasoline (all grades). HollyFrontier Refining & Marketing LLC, Dallas https://s2.q4cdn.com/255514451/files/doc_downloads/safety/2017/Gasoline-(All-Grades)-RSD-HollyFrontier-ISS-SDS-GHS-United-States-(US)-HCS-2012-V4.3.1English.pdf. Accessed 16 Oct 2019

  19. 19.

    Kapus P, Ofner H (1995) Development of fuel injection equipment and combustion system for DI diesels operated on dimethyl ether. SAE Techn Pap 950062:18

  20. 20.

    Methanol Institute (2019) Methanol price and supply/demand. https://www.methanol.org/methanol-price-supply-demand//. Accessed 16 October 2018

  21. 21.

    Park SH, Lee CS (2014) Applicability of dimethyl ether (DME) in a compression ignition engine as an alternative fuel. Energy Convers Manag 86:848–863. https://doi.org/10.1016/j.enconman.2014.06.051

  22. 22.

    Petrobras Distribuidora (2018) Ficha de Informações de Segurança de Produto Químico - FISPQ: Óleo Diesel B S500 (In portuguese). Rio de Janeiro

  23. 23.

    Seddon D (2011) Methanol and dimethyl ether (DME) production from synthesis gas. In: Khan MR (ed) Advances in clean hydrocarbon fuel processing: science and technology, 1st edn. Woodhead Publishing Limited, pp 363–386

  24. 24.

    SHELL (2014) Safety data sheet: dimethyl ether. Shell Deutschland Oil GmbH, Hamburg https://www.shell.com/business-customers/shell-liquefied-petroleum-gas-lpg/shell-dimethylether-dme/about-shell-lpg/_jcr_content/par/textimage_754410638.stream/1447283677172/20cb44175f13a7c75c92a41e9d5e42d056bbced7/dme-english-2014.pdf. Accessed 16 Oct 2019

  25. 25.

    Delparish A, Avci AK (2016) Intensified catalytic reactors for Fischer-Tropsch synthesis and for reforming of renewable fuels to hydrogen and synthesis gas. Fuel Process Technol 151:72–100. https://doi.org/10.1016/j.fuproc.2016.05.021

  26. 26.

    Yousefi A, Eslamloueyan R, Kazerooni NM (2017) Optimal conditions in direct dimethyl ether synthesis from syngas utilizing a dual-type fluidized bed reactor. Energy 125:275–286. https://doi.org/10.1016/j.energy.2017.02.085

  27. 27.

    Kurzina IA, Reshetnikov SI, Karakchieva NI, Kurina LN (2017) Direct synthesis of dimethyl ether from synthesis gas: experimental study and mathematical modeling. Chem Eng J 329:135–141. https://doi.org/10.1016/j.cej.2017.04.132

  28. 28.

    Bhatia SC (2014) Biodiesel. In: Advanced renewable energy systems. Woodhead Publishing India, Nova York, pp 573–626. https://doi.org/10.1016/B978-1-78242-269-3.50022-X

  29. 29.

    Farsi M, Sani AH, Riasatian P (2016) Modeling and operability of DME production from syngas in a dual membrane reactor. Chem Eng Res Des 112:190–198. https://doi.org/10.1016/j.cherd.2016.06.019

  30. 30.

    Luu MT, Milani D, Wake M, Abbas A (2016) Analysis of di-methyl ether production routes: process performance evaluations at various syngas compositions. Chem Eng Sci 149:143–155. https://doi.org/10.1016/j.ces.2016.04.019

  31. 31.

    Leonzio G (2018) State of art and perspectives about the production of methanol, dimethyl ether and syngas by carbon dioxide hydrogenation. J CO2 Util 27:326–354. https://doi.org/10.1016/j.jcou.2018.08.005

  32. 32.

    Leme RM, Seabra JEA (2017) Technical-economic assessment of different biogas upgrading routes from vinasse anaerobic digestion in the Brazilian bioethanol industry. Energy 119:754–766. https://doi.org/10.1016/j.energy.2016.11.029

  33. 33.

    de Souza Dias MO, Maciel Filho R, Mantelatto PE et al (2015) Sugarcane processing for ethanol and sugar in Brazil. Environ Dev 15:35–51. https://doi.org/10.1016/j.envdev.2015.03.004

  34. 34.

    Parsaee M, Kiani MKD, Karimi K (2019) A review of biogas production from sugarcane vinasse. Biomass Bioenergy 122:117–125. https://doi.org/10.1016/j.biombioe.2019.01.034

  35. 35.

    Fuess LT, Araújo Júnior MM, Garcia ML, Zaiat M (2017) Designing full-scale biodigestion plants for thetreatment of vinasse in sugarcane biorefineries: how phase separation and alkalinization impactbiogas and electricity production costs? Chem Eng Res Des 119:209–220

  36. 36.

    Fuess LT, Garcia ML, Zaiat M, Fuess LT (2018) Seasonal characterization of sugarcane vinasse: assessing environmental impacts from fertirrigation and the bioenergy recovery potential through biodigestion. Sci Total Environ 634:29–40

  37. 37.

    Molina FB, Salina FH, Palacios-Bereche R, Ensinas AV (2018) Supercritical water gasification route for methane production from sugarcane vinasse. In: 31st International Conference on efficiency, cost, optimization, simulation and environmental impact of energy systems ECOS. p 1–13

  38. 38.

    Nogueira CEC, Souza SNM, Micuanski VC, Azevedo RL (2015) Exploring possibilities of energy insertion from vinasse biogas in the energy matrix of Parana State, Brazil. Renew Sust Energ Rev 48:300–305. https://doi.org/10.1016/j.rser.2015.04.023

  39. 39.

    Pinto LS, Neto DP, Domingues EG (2018) Investment risk analysis of electricity generation from vinasse biodigestion in the free contracting environment. In: IEEE International Conference on Environment and Electrical Engineering and IEEE Industrial and Commercial Power Systems Europe. p 1–6

  40. 40.

    Salomon KR, Lora EES (2009) Estimate of the electric energy generating potential for different sources of biogas in Brazil. Biomass Bioenergy 33:1101–1107

  41. 41.

    Clausen RL, Elmegaard B, Houbak N (2010) Techno economic analysis of a low CO2 emission dimethyl ether (DME) plant based on gasification of torrefied biomass. Energy 35:4831–4842. https://doi.org/10.1016/j.energy.2010.09.004

  42. 42.

    Inayat A, Ghenai C, Naqvi M, Ammar M, Ayoub M, Hussin MNB (2017) Parametric study for production of dimethyl ether (DME) as a fuel from palm wastes. Energy Procedia 105:1242–1249. https://doi.org/10.1016/j.egypro.2017.03.431

  43. 43.

    Ju F, Chen H, Ding X, Yang H, Wang X, Zhang S, Dai Z (2009) Process simulation of single-step dimethyl ether production via biomass gasification. Biotechnol Adv 27:599–605. https://doi.org/10.1016/j.biotechadv.2009.04.015

  44. 44.

    Nakyai T, Saebea D (2019) Exergoeconomic comparison of syngas production from biomass, coal, and natural gas for dimethyl ether synthesis in single-step and two-step processes. J Clean Prod 241:118334. https://doi.org/10.1016/j.jclepro.2019.118334

  45. 45.

    Parvez AM, Wu T, Li S, Miles N, Mujtaba IM (2018) Bio-DME production based on conventional and CO2-enhanced gasification of biomass: a comparative study on exergy and environmental impacts. Biomass Bioenergy 110:105–113. https://doi.org/10.1016/j.biombioe.2018.01.016

  46. 46.

    Espana-Gamboa EI, Mijangos-Cortés JO, Hernández-Zárate G, Maldonado JAD, Alzate-Gaviria LM (2012) Methane production by treating vinasses from hydrous ethanol using a modified UASB reactor. Biotechnol Biofuels 82:1–9

  47. 47.

    Fuess LT, Garcia ML (2014) Implications of stillage land disposal: a critical review on the impacts of fertigation. J Environ Manag 145:210–229. https://doi.org/10.1016/j.jenvman.2014.07.003

  48. 48.

    Salomon K, Lora EES, Rocha MH, Olmo OA (2011) Cost calculations for biogas from vinasse biodigestion and its energy utilization. Sugar Ind 136:217–223

  49. 49.

    Labriet M, Simbolotti G, Tosato G (2013) Biogas and bio-syngas production. In: Energy Technology Systems Analysis Program (ETSAP) technology brief P11: International Energy Agency (IEA). https://iea-etsap.org/E-TechDS/PDF/P11_BiogasProd_ML_Dec2013_GSOK.pdf. Accessed 22 September 2019

  50. 50.

    Moraes BS, Zaiat M, Bonomi A (2015) Anaerobic digestion of vinasse from sugarcane ethanol production in Brazil : challenges and perspectives. Renew Sust Energy Rev 44:888–903. https://doi.org/10.1016/j.rser.2015.01.023

  51. 51.

    Chen X, Jiang J, Li K, Tian S, Yan F (2017) Energy-efficient biogas reforming process to produce syngas: the enhanced methane conversion by O2. Appl Energy 185:687–697. https://doi.org/10.1016/j.apenergy.2016.10.114

  52. 52.

    Salomon KR (2007) Technical-economic and environmental assessment of the use of biogas from vinasse biodigestion in technologies for electricity generation. Dissertation. Federal University of Itajubá

  53. 53.

    International DME Association (2019) About DME. https://www.aboutdme.org/index.asp?sid=48. Accessed 25 March 2018

  54. 54.

    Gopaul SG, Dutta A (2015) Dry reforming of multiple biogas types for syngas production simulated using Aspen Plus: the use of partial oxidation and hydrogen combustion to achieve thermo-neutrality. Int J Hydrog Energy. https://doi.org/10.1016/j.ijhydene.2015.03.079

  55. 55.

    Silva RO, Yoshi HCMH, Rocha LB, Lima OCM, Jiménez L, Jorge LMM (2017) Synthesis of a new route for methanol production by syngas arising from sugarcane vinasse. Comput Aided Chem Eng 40:811–816. https://doi.org/10.1016/B978-0-444-63965-3.50137-9

  56. 56.

    Al-Lagtah N, Al-Habsi S, Onaizi SA (2015) Optimization and performance improvement of Lekhwair natural gas sweetening plant using Aspen Hysys. J Nat Gas Sci Eng 26:367–381

  57. 57.

    Alnili F, Barifcani A (2018) Simulation study of sweetening and dehydration of natural gas stream using MEG solution. Can J Chem Eng 96:2000–2006. https://doi.org/10.1002/cjce.23132

  58. 58.

    Gangadharan P, Kanchi KC, Lou HH (2012) Chemical Engineering Research and Design Evaluation of the economic and environmental impact of combining dry reforming with steam reforming of methane. Chem Eng Res Des 90:1956–1968. https://doi.org/10.1016/j.cherd.2012.04.008

  59. 59.

    Matzen M, Demirel Y (2016) Methanol and dimethyl ether from renewable hydrogen and carbon dioxide: alternative fuels production and life-cycle assessment. J Clean Prod 139:1068–1077. https://doi.org/10.1016/j.jclepro.2016.08.163

  60. 60.

    Luyben WL (2011) Compressor heuristics for conceptual process design. Ind Eng Chem Res 50:13984–13989. https://doi.org/10.1021/ie202027h

  61. 61.

    Abu-Dahrieh J, Rooney D, Goguet A, Saih Y (2012) Activity and deactivation studies for direct dimethyl ether synthesis using CuO-ZnO-Al2O3 with NH(4)ZSM-5, HZSM-5 or gamma-Al2O3. Chem Eng J 203:201–211. https://doi.org/10.1016/j.cej.2012.07.011

  62. 62.

    Falco M, Capocelli M, Centi G (2016) Dimethyl ether production from CO2 rich feedstocks in a one-step process: thermodynamic evaluation and reactor simulation. Chem Eng J 294:400–409. https://doi.org/10.1016/j.cej.2016.03.009

  63. 63.

    Aguayo T, Eren J, Mier D, Arandes JM, Olazar M, Bilbao J (2007) Kinetic modeling of dimethyl ether synthesis in a single step on a CuO−ZnO−Al2O3/γ-Al2O3 catalyst. Ind Eng Chem Res 46:5522–5530

  64. 64.

    Stolov MA, Zaitseva KV, Varfolomeev MA, Acree WE (2017) Thermochimica Acta enthalpies of solution and enthalpies of solvation of organic solutes in ethylene glycol at 298.15 K: prediction and analysis of intermolecular interaction contributions. Thermochim Acta 648:91–99. https://doi.org/10.1016/j.tca.2016.12.015

  65. 65.

    Urut GO, Bayramin D, Alp S (2017) Synthesis and spectral properties of new ethylene glycol bridged oxazol-5-ones: high stokes’ shift fluorophores sensitive to solvent polarity. J Mol Liq 247:109–115

  66. 66.

    MEGlobal (2008) Ethylene Glycol Product Guide. https://www.meglobal.biz/wp-content/uploads/2019/01/Monoethylene-Glycol-MEG-Technical-Product-Brochure-PDF.pdf. Accessed 15 August 2018

  67. 67.

    Spath P, Aden A, Eggeman T, Ringer M, Wallace B, Jechura J (2005) Biomass to hydrogen production detailed design and economics utilizing the Battelle Columbus Laboratory indirectly - heated gasifier. Golden

  68. 68.

    Turton R, Bailie RC, Whiting WB, Shaeiwitz JA, Battacharyya D (2012) Analysis, synthesis, and design of chemical processes, 4th edn. Prentice Hall, Upper Saddle River

  69. 69.

    Silva RO, Torres CM, Bonfim-Rocha L, Lima OCM, Coutu A, Jiménez L, Jorge LMM (2018) Multi-objective optimization of an industrial ethanol distillation system for vinasse reduction – a case study. J Clean Prod 183:956–963. https://doi.org/10.1016/j.jclepro.2018.02.179

  70. 70.

    Plastic Insight (2018) Mono-ethylene glycol (MEG): production, Market, Price and its Properties. https://www.plasticsinsight.com/resin-intelligence/resin-prices/mono-ethylene-glycol-meg/. Accessed 5 June 2018

  71. 71.

    Hofsetz K, Silva MA (2012) Brazilian sugarcane bagasse: energy and non-energy consumption. Biomass Bioenergy 46:564–573. https://doi.org/10.1016/j.biombioe.2012.06.038

  72. 72.

    Arshad M, Ahmed S (2016) Cogeneration through bagasse : a renewable strategy to meet the future energy needs. Renew Sust Energ Rev 54:732–737. https://doi.org/10.1016/j.rser.2015.10.145

  73. 73.

    Bonfim-Rocha L, Gimenes ML, Faria SHB, Silva RO, Jiménez L (2018) Multi-objective design of a new sustainable scenario for bio-methanol production in Brazil. J Clean Prod 187:1043–1056. https://doi.org/10.1016/j.jclepro.2018.03.267

  74. 74.

    Bollon F (2011) DME standardization , regulation and safety recommendations. In: 7th Asian DME Conference. International DME Association, Niigata p 1–27

  75. 75.

    Dantas GA, Legey LFL, Mazzone A (2013) Energy from sugarcane bagasse in Brazil: an assessment of the productivity and cost of different technological routes. Renew Sust Energ Rev 21:356–364. https://doi.org/10.1016/j.rser.2012.11.080

  76. 76.

    Brazilian Central Bank (2017) Interest rate history. https://www.bcb.gov.br/Pec/Copom/Port/taxaSelic.asp. Accessed 20 August 2018

  77. 77.

    Ballinger SE, Adams TA II (2017) Space-constrained purification of dimethyl ether through process intensification using semicontinuous dividing wall columns. Comput Chem Eng 105:197–211. https://doi.org/10.1016/j.compchemeng.2017.01.037

  78. 78.

    Exchange-Rates (2019) Conversão de Dólares Americanos (USD) para Reais Brasileiros (BRL) - Taxas de Câmbio. https://pt.exchange-rates.org/Rate/USD/BRL. Accessed 5 February 2019

  79. 79.

    Petrobrás (2019) Composição de Preços do Diesel - Petrobras (In portuguese). http://www.petrobras.com.br/pt/produtos-e-servicos/composicao-de-precos-de-venda-ao-consumidor/diesel/. Accessed 5 February 2019

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Correspondence to Gabriela de França Lopes.

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Appendix. Equipment data

Appendix. Equipment data

Table 15 Equipment data exported from simulation

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de França Lopes, G., Bonfim-Rocha, L., de Matos Jorge, L.M. et al. Dimethyl Ether Production from Sugarcane Vinasse: Modeling and Simulation for a Techno-economic Assessment. Bioenerg. Res. (2020) doi:10.1007/s12155-020-10089-9

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Keywords

  • Vinasse
  • Biogas
  • Syngas
  • Industrial scale
  • Renewable processes
  • Dimethyl ether