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Synthesis and structure of Anderson cluster based organic–inorganic hybrid solid, \([\{\hbox {Cu}(2\hbox {-}pzc)(\hbox {H}_{2}\hbox {O})_{2}\}_{2}\{\hbox {H}_{7}\hbox {AlMo}_{6}\hbox {O}_{24}\}]\cdot 17\hbox {H}_{2}\hbox {O}\) and its dye adsorption properties

  • Arti Joshi
  • Sonalika Vaidya
  • Monika SinghEmail author
Regular Article
  • 54 Downloads

Abstract

An inorganic–organic hybrid compound, namely \([\{\hbox {Cu}(2\hbox {-}pzc)(\hbox {H}_{2}\hbox {O})_{2}\}_{2}\{\hbox {H}_{7}\hbox {AlMo}_{6}\hbox {O}_{24}\}]{\cdot }17\hbox {H}_{2}\hbox {O}\) was synthesized based on Anderson–Evans cluster by the normal stirring process at room temperature. Its structure consists of metal coordination polymer covalently linked with Anderson–Evans cluster forming a 2D-sheet with void space containing water chains as determined by Single-Crystal X-ray Diffraction technique. This material owing to its void space of approx. 13 Å was utilized for adsorption of organic dyes like Methylene Blue (MB), Basic Violet 1 (BV1) and shows ultra-high uptake (more than 90%) within 5 min.

Graphical abstract:

Anderson-Evans cluster based organic-inorganic hybrid solid is reported which shows remarkable activity in adsorbtion of basic dyes namely Methylene Blue and Basic Violet 1 from their aqueous solution.

Keywords

Polyoxomolybdates Anderson–Evans cluster dye adsorption 

Notes

Acknowledgements

MS acknowledges Prof. Ramanan for Single Crystal X-Ray facility at IIT Delhi. AJ thanks INST for PhD fellowship. MS appreciates the financial support from the Department of Science and Technology (DST) SB/FT/CS-091/2014 Project, and instrumental facility and infrastructural support from INST. SV thanks INST (25(1)/2015-INST) for financial support.

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Copyright information

© Indian Academy of Sciences 2019

Authors and Affiliations

  1. 1.Institute of Nano Science and TechnologyMohaliIndia

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