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Journal of Chemical Sciences

, 130:139 | Cite as

In search of stable visible light absorbing photocatalysts: gold nanoclusters\(^{\S }\)

  • Barnali Mondal
  • Mohan Raj Anthony Raj
  • V Ramamurthy
Regular Article
  • 33 Downloads

Abstract

Abstract

Photochemical reactions are beginning to play an important role in the synthesis of complex organic molecules. The impetus to employ light initiated photoreactions as a synthetic tool derives from the fact that these reactions require no reagents except light. The abundance of sunlight has prompted the chemists to search for the visible light absorbing sensitizers (catalysts) to initiate the desired reactions. Our goal in this context is to develop stable and readily available catalysts that would function under sunlight. In this manuscript, we present the results of our experiments with gold nanoclusters (AuNCs) as a visible light absorbing catalysts. AuNCs absorb and emit in the visible region, soluble in water and transfers electron to suitable acceptors. Employing a series of acceptors we found that excited AuNC can transfer one electron to any acceptor whose reduction potential is above −1.1 eV. In the excited state, AuNC does not accept electrons. Also, it did not serve as an energy transfer sensitizer even with molecular oxygen. We are optimistic that AuNP and AuNC could be developed into a stable and water-soluble visible light absorbing photocatalysts to perform useful photoreactions.

Graphical Abstract

SYNOPSIS In the context of visible light photocatalysis gold nanoclusters upon light, absorption was found to transfer electron to acceptors whose reduction potential is above −1.1 eV. AuNC has limited value as electron transfer sensitizers in photochemical reactions.

Keywords

Nanoclusters photocatalysis electron transfer emission quenching visible light photocatalysis 

Notes

Acknowledgements

V.R. is thankful to the National Science Foundation (CHE-1807729), USA for financial support.

Supplementary material

12039_2018_1553_MOESM1_ESM.pdf (2.4 mb)
Supplementary material 1 (pdf 2407 KB)

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Copyright information

© Indian Academy of Sciences 2018

Authors and Affiliations

  1. 1.Department of ChemistryUniversity of MiamiCoral Cables, MiamiUSA

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