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Curable hybrid materials for corrosion protection of steel: development and application of UV-cured 3-methacryloxypropyltrimethoxysilane-derived coating

Abstract

A UV-crosslinkable two-component organically modified silicate (ORMOSIL) sol–gel coating was made using 3-methacryloxypropyltrimethoxysilane (MaPTMS) and tetraethoxysilane (TEOS) in two stages. In the first stage, key synthetic parameters, such as use of co-solvents, reaction temperature, reaction time, and catalyst, were optimized for the rapid hydrolysis and condensation of the ORMOSIL. The ORMOSIL material was made using isopropanol as the solvent and HNO3 as the acid catalyst. This resulted in a sol–gel that underwent rapid hydrolysis in 35 s. The ORMOSIL demonstrated extensive condensation after 10 min of stirring at room temperature followed by 10 min of heating at 60°C as monitored by 29Si-NMR. In the second stage, the ORMOSIL was successfully crosslinked with up to 70% consumption of the acryl functionality within 5 min under UV light exposure in the presence of photoinitiator. The UV-crosslinked coating exhibited high adhesion to low-carbon steel and impeded substrate corrosion from 17 to 25 h under an accelerated corrosive environment.

Graphic abstract

Schematic representation of the hydrolysis and condensation of 3-methacryloxypropyltrimethoxysilane (MaPTMS) and tetraethoxysilane (TEOS) system and the 2D gHMBC 29Si NMR of the system.

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References

  1. 1.

    Velázquez, JC, Van Der Weide, JAM, Hernández, E, Hernández, HH, “Statistical Modelling of Pitting Corrosion: Extrapolation of the Maximum Pit Depth-Growth.” Int. J. Electrochem. Sci., 9 4129–4143 (2014)

  2. 2.

    Shetranjiwalla, S, Vreugdenhil, A, Stotesbury, T, “Waterborne Epoxy-Thiol Decorated Silica Sol–Gel Coatings: Impact of Crosslinking on Corrosion Prevention.” J. Sol-Gel Sci. Technol., 87 504–513 (2018). https://doi.org/10.1007/s10971-018-4739-2

  3. 3.

    Akid, R, Gobara, M, Wang, H, “Corrosion Protection Performance of Novel Hybrid Polyaniline/Sol–Gel Coatings on an Aluminium 2024 Alloy in Neutral, Alkaline and Acidic Solutions.” Electrochim. Acta, 56 2483–2492 (2010). https://doi.org/10.1016/j.electacta.2010.12.032

  4. 4.

    Wang, H, Akid, R, “Encapsulated Cerium Nitrate Inhibitors to Provide High-Performance Anti-Corrosion Sol–Gel Coatings on Mild Steel.” Corros. Sci., 1 2 (2007). https://doi.org/10.1016/j.corsci.2007.11.019

  5. 5.

    Sarmento, VHV, Schiavetto, MG, Hammer, P, et al., “Corrosion Protection of Stainless Steel by Polysiloxane Hybrid Coatings Prepared Using the Sol–Gel Process.” Surf. Coat. Technol., 204 2689–2701 (2010). https://doi.org/10.1016/j.surfcoat.2010.02.022

  6. 6.

    Baruthio, F, “Toxic Effects of Chromium and its Compounds.” Biol. Trace Elem. Res., 32 145–153 (1992). https://doi.org/10.1007/BF02784599

  7. 7.

    Nazeer, AA, Madkour, M, “Potential Use of Smart Coatings for Corrosion Protection of Metals and Alloys: A Review.” J. Mol. Liq., 253 11–22 (2018). https://doi.org/10.1016/j.molliq.2018.01.027

  8. 8.

    Twite, RL, Bierwagen, GP, “Review of Alternatives to Chromate for Corrosion Protection of Aluminum Aerospace Alloys.” Prog. Org. Coat., 33 91–100 (1998)

  9. 9.

    Rosero-Navarro, NC, Pellice, SA, Castro, Y, et al., “Improved Corrosion Resistance of AA2024 Alloys Through Hybrid Organic–Inorganic Sol–Gel Coatings Produced from Sols with Controlled Polymerisation.” Surf. Coat. Technol., 203 1897–1903 (2009). https://doi.org/10.1016/j.surfcoat.2009.01.019

  10. 10.

    Croes, KJ, Vreugdenhil, AJ, Yan, M, et al., “An Electrochemical Study of Corrosion Protection by In Situ Oxidative Polymerization in Phenylenediamine Crosslinked Sol–Gel Hybrid Coatings.” Electrochim. Acta, 56 7796–7804 (2011). https://doi.org/10.1016/j.electacta.2011.06.046

  11. 11.

    Hench LL, West JONK (1990) The Sol–Gel Process. 33–72. https://doi.org/10.1021/cr00099a003

  12. 12.

    Wang, D, Bierwagen, GP, “Sol–Gel Coatings for Corrosion Protection.” Prog. Org. Coat., 64 327–338 (2009)

  13. 13.

    Vreugdenhil, AJ, Gelling, VJ, Woods, ME, et al., “The Role of Crosslinkers in Epoxy-Amine Crosslinked Silicon Sol–Gel Barrier Protection Coatings.” Thin Solid Films, 517 538–543 (2008). https://doi.org/10.1016/j.tsf.2008.06.073

  14. 14.

    Vreugdenhil, AJ, Horton, JH, Woods, ME, “Fabrication, Characterization and Modification of Nanodimensional Silica Hybrid Multilayered Materials.” J. Non Cryst. Solids, 355 1206–1211 (2009). https://doi.org/10.1016/j.jnoncrysol.2009.05.010

  15. 15.

    Vreugdenhil, AJ, Balbyshev, VN, Donley, MS, “Nanostructured Silicon Sol–Gel Surface Treatments for Al 2024-T3 Protection.” J. Coat. Technol., 73 35–43 (2001). https://doi.org/10.1007/bf02730029

  16. 16.

    Schottner, G, “Hybrid Sol–Gel-Derived Polymers: Applications of Multifunctional Materials.” Chem. Mater., 13 3422–3435 (2001). https://doi.org/10.1021/cm011060m

  17. 17.

    Zheludkevich, ML, Salvado, IM, Ferreira, MGS, “Sol-Gel Coatings for Corrosion Protection of Metals.” J. Mater. Chem., 15 5099–5111 (2005). https://doi.org/10.1039/b419153f

  18. 18.

    Delattre, L, Dupuy, C, Babonneau, F, “Characterization of the Hydrolysis and Polymerization of Methacryloxypropyltrimethoxysilane.” J. Sol-Gel Sci. Technol., 2 185–188 (1994)

  19. 19.

    Wouters, MEL, Wolfs, DP, Van Der Linde, MC, et al., “Transparent UV Curable Antistatic Hybrid Coatings on Polycarbonate Prepared by the Sol-Gel Method.” Prog. Org. Coat., 51 312–320 (2004). https://doi.org/10.1016/j.porgcoat.2004.07.020

  20. 20.

    Soppera, O, Croutxe, C, “Real-Time Fourier Transform Infrared Study of the Free-Radical Ultraviolet-Induced Polymerization of a Hybrid Sol–Gel. II. The Effect of Physicochemical Parameters on the Photopolymerization Kinetics.” J. Polym. Sci. Part A Polym. Chem., 41 831–840 (2003)

  21. 21.

    Sangermano, M, Amerio, E, Epicoco, P, et al., “Preparation and Characterization of Hybrid Nanocomposite Coatings by Cationic UV-Curing and the Sol–Gel Process of a Vinyl Ether Based System.” Macromol. Mater. Eng., 292 634–640 (2007). https://doi.org/10.1002/mame.200600507

  22. 22.

    Abe, Y, Honda, Y, Gunji, T, “Preparation and Properties of Silicon-Containing Polymer Hybrids from 3-Methacryloxypropyltrimethoxysilane.” Appl. Organomet. Chem., 12 749–753 (1998). https://doi.org/10.1002/(SICI)1099-0739(199810/11)12:10/11<749::AID-AOC782>3.0.CO;2-2

  23. 23.

    Garcia-Heras, M, Jimenez-Morales, A, Casal, B, et al., “Preparation and Electrochemical Study of Cerium-Silica Sol–Gel Thin Films.” J. Alloys Compd., 380 219–224 (2004). https://doi.org/10.1016/j.jallcom.2004.03.047

  24. 24.

    Deflorian, F, Fedel, M, Dirè, S, et al., “Study of the Effect of Organically Functionalized Silica Nanoparticles on the Properties of UV Curable Acrylic Coatings.” Prog. Org. Coat., 72 44–51 (2011). https://doi.org/10.1016/j.porgcoat.2011.01.002

  25. 25.

    Hench, LL, West, JK, “The Sol–Gel Process.” Chem. Rev., 90 33–72 (1990)

  26. 26.

    Esposito, S, ““Traditional” Sol–Gel Chemistry as a Powerful Tool for the Preparation of Supported Metal and Metal Oxide Catalysts.” Mater. (Basel), 12 1–25 (2019). https://doi.org/10.3390/ma12040668

  27. 27.

    Zheludkevich, ML, Salvado, IM, Ferreira, MGS, “Sol–Gel Coatings for Corrosion Protection of Metals.” J. Mater. Chem., 15 5099 (2005). https://doi.org/10.1039/b419153f

  28. 28.

    Criado, M, Sobrados, I, Sanz, J, “Polymerization of Hybrid Organic–Inorganic Materials from Several Silicon Compounds Followed by TGA/DTA, FTIR and NMR Techniques.” Prog. Org. Coat., 77 880–891 (2014). https://doi.org/10.1016/j.porgcoat.2014.01.019

  29. 29.

    Iwamoto, T, Morita, K, Mackenzie, JD, “Liquid State 29Si NMR Study on the Sol–Gel Reaction Mechanisms of Ormosils.” J. Non Cryst. Solids, 159 65–72 (1993). https://doi.org/10.1016/0022-3093(93)91282-8

  30. 30.

    Oubaha, M, Dubois, M, Murphy, B, Etienne, P, “Structural Characterisation of a Sol–Gel Copolymer Synthesised from Aliphatic and Aromatic Alkoxysilanes Using 29Si-NMR Spectroscopy.” J. Sol-Gel Sci. Technol., 38 111–119 (2006). https://doi.org/10.1007/s10971-006-7114-7

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Correspondence to Andrew J. Vreugdenhil.

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Scotland, K.M., Shetranjiwalla, S. & Vreugdenhil, A.J. Curable hybrid materials for corrosion protection of steel: development and application of UV-cured 3-methacryloxypropyltrimethoxysilane-derived coating. J Coat Technol Res (2020). https://doi.org/10.1007/s11998-019-00317-z

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Keywords

  • Sol–gel coatings
  • 3-Methacryloxypropyltrimethoxysilane
  • MaPTMS
  • UV crosslinking
  • Corrosion prevention
  • Low-carbon steel protection