Rheological properties and anticorrosion performance of graphene oxide- and reduced graphene oxide-based nanocomposites

  • Kerim YapiciEmail author
  • Secil Peker


In this study, the effect of graphene oxide (GO) and reduced graphene oxide (rGO) nanoparticles on the corrosion protection performance of nanocomposite coatings containing particle mass concentration ranging from 0.25% to 1% in epoxy matrix was investigated in detail. In addition, the effect of the distribution of GO and rGO nanoparticles in epoxy matrix on the corrosion performance and rheology of the coatings was studied by mixing the nanocomposites with the ball milling for 24 and 48 h. The surface morphology of coatings was analyzed by field-emission scanning microscope. It was observed that oxygen groups in the graphene structure, the effective distribution of nanoparticles in the matrix and the amount of nanoparticle doped affected the corrosion protection performance. The best corrosion protection performance among all nanocomposite coatings was 0.75 wt% rGO/epoxy nanocomposite, which was milled for 48 h. GO/epoxy nanocomposite coatings exhibit hydrophilic properties in all mass fractions and mixing times. However, adding 0.5 and 0.75 wt% of rGO and milling 48 h resulted in hydrophobic nanocomposites. rGO nanoparticles had the best dispersion performance at 0.75 wt% concentration in the epoxy. The nonlinear rheological measurements revealed that rGO/epoxy nanocomposites exhibit non-Newtonian shear thinning behavior at the studied mass concentrations and milling times as opposed to the nanocomposites containing GO particles.


Graphene oxide Reduced graphene oxide Rheology Anticorrosion performance Nanocomposite coating 



  1. 1.
    Di, H, Yu, Z, Ma, Y, “Corrosion-Resistant Hybrid Coatings Based on Graphene Oxide-Zirconia Dioxide/Epoxy System.” J. Taiwan Inst. Chem. Eng., 67 (12) 511–520 (2016)CrossRefGoogle Scholar
  2. 2.
    Ramezanzadeha, B, Niroumandrad, S, Ahmadib, A, Mahdaviana, M, “Enhancement of Barrier and Corrosion Protection Performance of an Epoxy Coating Through Wet Transfer of Amino Functionalized Graphene Oxide.” Corros. Sci., 103 283–304 (2016)CrossRefGoogle Scholar
  3. 3.
    Blustein, G, Romagnoli, R, “Zinc Basic Benzoate as Eco-Friendly Steel Corrosion Inhibitor Pigment for Anticorrosive Epoxy-Coatings.” Colloids Surf. A: Physicochem. Eng. Asp., 290 (1–3) 7–18 (2006)CrossRefGoogle Scholar
  4. 4.
    Joseph, R, Corrosion: Understanding the Basics. Materials Park, Ohio (2000)Google Scholar
  5. 5.
    Zaki, A, Principles of Corrosion Engineering and Corrosion Control. Elsevier, Amsterdam (2006)Google Scholar
  6. 6.
    Sanyal, B, Organics Compounds as Corrosion Inhitiors in Different Environments. Elsevier, Amsterdam (1981)Google Scholar
  7. 7.
    Chi-Hao, C, Tsao-Cheng, H, Chih-Wei, P, Tzu-Chun, Y, Hsin-I, L, Wei-I, H, Chang-Jian, W, “Novel Anticorrosion Coatings Prepared from Polyaniline/Graphene Composites.” Carbon, 50 5044–5051 (2012)CrossRefGoogle Scholar
  8. 8.
    Singh, R, Chakraborty, B, Derrek, EL, Gullapalli, H, Sumandasa, M, Kumar, A, “Protecting Copper from Electrochemical Degradation by Graphene Coating.” Carbon, 50 (11) 4040–4045 (2012)CrossRefGoogle Scholar
  9. 9.
    Wan, Y, Gong, L, Tang, L, Wu, J, “Mechanical Properties of Epoxy Composites Filled with Silane-Functionalized Graphene Oxide.” Compos. Part A. App. Sci. Manuf., 64 79–89 (2014)CrossRefGoogle Scholar
  10. 10.
    Ghanbari, A, Attar, M, “A Study on the Anticorrosion Performance of Epoxy Nanocomposite Coatings Containing Epoxy—Silane Treated Nano-Silica on Mild Steel Substrate.” J. Ind. Eng. Chem. Res., 23 145–153 (2014)CrossRefGoogle Scholar
  11. 11.
    Hongpeng, Z, Yawei, S, Yanqiu, W, Guozhe, M, Bin, L, “Reinforcing the Corrosion Protection Property of Epoxy Coating by Using Graphene Oxide Poly(urea–formaldehyde) Composites.” Corros. Sci., 123 267–277 (2017)CrossRefGoogle Scholar
  12. 12.
    Jafari, Y, Ghoreishi, S, Shabani, M, “Polyaniline/Graphene Nanocomposite Coatings on Copper: Electropolymerization, Characterization, and Evaluation of Corrosion Protection Performance.” Synth. Met., 217 220–230 (2016)CrossRefGoogle Scholar
  13. 13.
    Abdel, A, EntesarAl-Hetlani, N, Amin, M, “A Poly(butyl methacrylate)/Graphene Oxide/TiO2 Nanocomposite Coating with Superior Corrosion Protection for AZ31 Alloy in Chloride Solution.” Chem. Eng. J., 361 485–498 (2019)CrossRefGoogle Scholar
  14. 14.
    Ramezanzadeh, B, Haeri, Z, Ramezanzadeh, M, “A Facile Route of Making Silica Nanoparticles-Covered Graphene Oxide Nanohybrids (SiO2-GO); Fabrication of SiO2-GO/Epoxy Composite Coating with Superior Barrier and Corrosion Protection Performance.” Chem. Eng. J., 303 511–528 (2016)CrossRefGoogle Scholar
  15. 15.
    Haihui, D, Zongxue, Y, Yu, M, Chunli, Z, “Corrosion-Resistant Hybrid Coatings Based on Graphene Oxide–Zirconia Dioxide/Epoxy System.” J. Taiwan Inst. Chem. Eng., 67 511–520 (2016)CrossRefGoogle Scholar
  16. 16.
    Zhang, J, Lıu, Z, Feng, T, Wen, S, Chen, R, “Effect of Carbon Nanotube on Properties of Epoxy Coating.” J. Chin. Soc. Corros. Prot., 37 (3) 254–260 (2017)Google Scholar
  17. 17.
    Anwar, Z, Kausar, A, Rafique, I, Muhammad, B, “Advances in Epoxy/Graphene Nanoplatelet Composite with Enhanced Physical Properties: A Review.” Poly.-Plast. Tech. Eng., 55 (6) 643–662 (2016)CrossRefGoogle Scholar
  18. 18.
    Monetta, T, Acquesta, A, Bellucci, F, “Graphene/Epoxy Coating as Multifunctional Material for Aircraft Structures.” J. Aerosp., 2 423–434 (2015)CrossRefGoogle Scholar
  19. 19.
    Shah, R, Kausar, A, Muhammad, B, Shah, S, “Progression from Graphene and Graphene Oxide to High Performance Polymer-Based Nanocomposite: A Review.” Poly.-Plast. Tech. Eng., 54 (2) 173–183 (2015)CrossRefGoogle Scholar
  20. 20.
    Moosa, A, Kubba, F, Raad, M, Ramazani, A, “Mechanical and Thermal Properties of Graphene Nanoplates and Functionalized Carbon-Nanotues Hybrid Epoxy Nanocomposites.” Am. J. Mater. Sci., 6 (5) 125–134 (2016)Google Scholar
  21. 21.
    Wang, X, Li, Z, Zhang, Y, “Enhancing the Corrosion Resistance of Epoxy Coatings by Impregnation with a Reduced Graphene Oxide-Hydrophobic Ionic Liquid Composite.” ChemElectroChem, 5 (21) 3300–3306 (2018)CrossRefGoogle Scholar
  22. 22.
    Ghauri, F, Raza, M, Baig, M, “Corrosion Study of the Graphene Oxide and Reduced Graphene Oxide-Based Epoxy Coatings.” Mater. Res. Exp., 4 (12) 324–326 (2017)Google Scholar
  23. 23.
    Yu, Z, Ma, Y, Di, H, “Preparation of Graphene Oxide Modified by Titanium Dioxide to Enhance the Anti-corrosion Performance of Epoxy Coatings.” Surf. Coat. Tech., 276 471–478 (2015)CrossRefGoogle Scholar
  24. 24.
    Zhang, Z, Li, D, Sun, Y, “Mechanical and Anticorrosive Properties of Graphene/Epoxy Resin Composites Coating Prepared by In-Situ Method.” Int. J. Mol. Sci., 16 (1) 2239–2251 (2015)CrossRefGoogle Scholar
  25. 25.
    Chang, K, Hsu, M, Lu, H, Lai, M, “Room-Temperature Cured Hydrophobic Epoxy/Graphene Composites as Corrosion Inhibitor for Cold-Rolled Steel.” Carbon, 66 144–153 (2014)CrossRefGoogle Scholar
  26. 26.
    Jin, T, Han, Y, Bai, R, Liu, X, “Corrosion Protection Properties of Nano NH2-Reduced Graphene Oxide/Epoxy Composite Coatings Formed by Self-Curing on Magnesium Alloy.” J. Nanosci. Nanotech., 18 (7) 4971–4981 (2018)CrossRefGoogle Scholar
  27. 27.
    Hayatgheib, Y, Ramezanzadeh, B, Kardar, P, Mahdavian, M, “A Comparative Study on Fabrication of a Highly Effective Corrosion Protective System Based on Graphene Oxide-Polyaniline Nanofibers/Epoxy Composite.” Corros. Sci., 133 358–373 (2018)CrossRefGoogle Scholar
  28. 28.
    Marcano, D, Kosynkin, V, Berlin, M, Sinitskii, A, Sun, Z, Slesarev, A, Alemany, B, Lu, W, Tour, M, “Improved Synthesis of Graphene Oxide.” ACS Nano, 4 4806–4814 (2010)CrossRefGoogle Scholar
  29. 29.
    Zhou, S, Wu, Y, Zhao, W, Yu, S, Ma, L, “Comparative Corrosion Resistance of Graphene Sheets with Different Structures in Waterbone Epoxy Coatings.” Colloids Surf., 556 273–283 (2018)CrossRefGoogle Scholar
  30. 30.
    Jiang, M, Wu, L, Hu, J, Zhang, J, “Silane-Incorporated Epoxy Coatings on Alumium Alloy (AA2024).” Corros. Sci., 92 118–126 (2015)CrossRefGoogle Scholar
  31. 31.
    Wu, L, Zhang, J, Hu, J, Zhang, J, “Improved Corrosion Performance of Electrophoretic Coatings by Silane Addition.” Corros. Sci., 56 58–66 (2015)CrossRefGoogle Scholar

Copyright information

© American Coatings Association 2019

Authors and Affiliations

  1. 1.Department of Chemical EngineeringSüleyman Demirel UniversityIspartaTurkey

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