Sources, deposition flux and carcinogenic potential of PM2.5-bound polycyclic aromatic hydrocarbons in the coastal zone of the Baltic Sea (Gdynia, Poland)
Concentrations of 16 PAHs of different molecular weight and carcinogenic potency were measured in PM2.5 aerosols collected in the coastal zone of southern Baltic Sea (Gdynia, Poland) during the end of the heating and beginning of the non-heating season of 2012. Obtained results showed that coal combustion (pyrogenic source) contributed to the highest emission of PAHs during the heating season. However, similar concentrations of highly carcinogenic PAHs were detected in the non-heating period. The analysis of prevailing wind directions, air mass trajectories and diagnostic PAH ratios revealed that in addition to land transport emission (mainly from diesel vehicles), the increase in sea shipping traffic during the non-heating season contributed to the high concentrations of detected carcinogenic PAHs. We conclude that the increasing maritime activity in the southern Baltic Sea region might have an adverse effect on both environmental and human health. Therefore, it should receive more attention by the Polish government as a pollutant source.
KeywordsPM2.5 PAHs Diagnostic ratios Deposition flux BaP-TEQ
Polycyclic Aromatic Hydrocarbons (PAHs) are a group of organic compounds composed of more than one aromatic ring. They are typically classified according to their mass, with the division into low (2-3 benzene rings), medium (4 benzene rings) and high (5-6 benzene rings) molecular weight compounds being the most common (Ravindra et al. 2008). PAHs’ molecular weight and chemical structure determine their characteristics. Lighter compounds are volatile and primarily present in gaseous phase. Hence, they are widely dispersed in the atmosphere and can be washed out by rain (Karali et al. 2018). Heavier compounds, on the other hand, are characterised by a higher affinity towards solid phase and can get readily adsorbed on particulate matter, which increases their persistence in the environment. The latter have been of major scientific interest due to their well-documented carcinogenicity, genotoxicity and potential for DNA damage (Błaszczyk and Mielżyńska-Švach 2016). It has been reported that over 95% of particle-phase PAHs are associated with particulate matter of less than 3 μm in diameter. Such aerosols can easily penetrate the human respiratory tract, and, in the case of sub-micron particulates, enter the blood stream. That, in turn, leads to PAH-initiated carcinogenesis via the formation of PAH-DNA adducts (Liu et al. 2015).
Although PAHs are often associated with anthropogenic emission (e.g. burning of coal or gas), they can also originate from natural sources, such as forest fires or volcanic eruptions. Anthropogenic sources include combustion processes (pyrogenic PAHs) and maturation of crude oil (petrogenic PAHs) (Ravindra et al. 2008). Because these processes result in an emission of specific PAHs, individual sources can be distinguished using the diagnostic ratio method (Tobiszewski and Namiesnik 2012). Irrelevant of the source, PAHs are always emitted as a mixture rather than individual compounds (Ravindra et al. 2008). The diagnostic ratio method uses the relative concentrations of PAH pairs of the same molecular weight and properties (isomers), which are thought to represent specific emission sources (e.g. petroleum combustion or fuel burning). A total of 16 priority PAH species, nevertheless, the isomer ratio method has been widely used to determine sources of PAHs in a range of different matrices, e.g. air, water, soil or marine organisms (Tobiszewski and Namiesnik 2012).
High concentrations of PAHs are commonly noted in urban regions, where they originate from burning fossil fuels, vehicle combustion engines, as well as from the industrial sector. Whereas west European countries are converting to green energy sources, eastern nations (i.e. Bulgaria, Poland, Czech Republic, Slovakia) still rely on fossil fuel combustion to generate electricity and heat (Garrido et al. 2014). As a consequence, PAH levels in well-developed western European countries rarely exceed the set threshold values, while their elevated concentrations are frequently noted in Eastern Europe (EEA 2018). Of all European countries, Poland is often referred to as ‘Europe’s capital of smog’. With air contamination showing no signs of improvement and the current government’s ongoing investments in coal mining, it remains one of the most polluted countries in Europe. According to European Environment Agency, Poland currently has the highest levels of BaP relative to other European countries, with 87% of the total PAH emission resulting from domestic coal and wood burning (EEA 2018). High concentrations of BaP (in PM10) are routinely detected all over Poland; however, its highest levels (as high as 22.7 ng m3 in 2017) are often noted in central and southern parts of the country (Iwanek et al. 2016), partially due to the local topography. Southern Poland is dominated by mountainous terrains, which results in the trapping of contaminants in adjacent air. Its northern part, on the other hand, is located near the Baltic Sea, which facilitates an effective dispersal of air pollutants (Lewandowska et al. 2018a). Air pollution is often associated with rural areas, as a result of using low-quality coal and outdated furnaces for heat generation in individual households. The practice of burning garbage (e.g. plastic bottles or car tires) instead of coal in efforts to save money is also well-documented (Lewandowska et al. 2018b). Due to domestic heating being a large contributor to air pollution, seasonal variability in PAHs concentration has been reported by several authors in Poland, with elevated levels of contaminants in the autumn/winter period (e.g. Ćwiklak et al. 2009; Iwanek et al. 2016; Lewandowska et al. 2018b). Another potential source of PAHs is the emission of exhaust gases and particulates from diesel engines. It is well-acknowledged that diesel engines contribute to the emission of both semi-volatile and particle-bound hydrocarbons (Yilmaz and Davis 2016). An average Polish car has been reported to be 13 years old, suggesting that Poland has the oldest vehicles in European Union (ACEA 2017).
With that many sources significantly contributing to the problem of air pollution, it is vital to monitor the levels of PAHs in the air and recognise their sources of origin to drive measures to reduce their emission. This is especially important for contaminants associated with smaller particles, which have been found to be hazardous to human health (Liu et al. 2015). Therefore, the purpose of this study was to assess the variability of PM2.5-bound PAHs concentration in the late heating and the early non-heating period (April-May of 2012) in Gdynia, located in the coastal zone of the southern Baltic Sea. Thorough analysis of air mass trajectories and quantification of PAH diagnostic ratios allowed identification of potential sources of PAHs in the collected aerosol samples. Moreover, an effort was made to estimate the deposition fluxes and the overall carcinogenic potential of 16 priority PAHs emitted over the analysed period.
Materials and methods
Sample processing and chemical analysis of PAHs
PM2.5 samples were collected throughout April and May 2012 (April 16, 2012–May 15, 2012) using FAI Hydra Dual Sampler operating at a flow rate of 2.3 m3 h−1. Particulate matter was collected on QMA Whatman quartz filters (φ = 47 mm). Prior to aerosol sampling, all filters were pre-combusted in a muffle furnace for at least 6 h at 550 °C and weighed (10−5 g precision, T = 23 ± 2 °C and air humidity of 40 ± 5%). After sample collection, filters were weighed again and kept in a desiccator under the same conditions as before sampling. The mass of collected particulate matter was determined by subtracting the pre-sampling mass of the filter from its post-sampling total weight. This value was later divided by the volume of air that passed through the sampling device, enabling a precise quantification of PM2.5 concentration in a parcel of air. The limit of detection was estimated at 0.17 μg m−3, and the estimated error quantified for 28 blank samples (p = 0.99) was around 4.1% (Witkowska and Lewandowska 2016; Lewandowska et al. 2018a).
Prior to the analysis, a portion (φ = 2.5 cm) of the filter was cut out. Sixteen priority PAHs were extracted using the Soxhlet apparatus and a 1:1 mixture of toluene and methanol (250 cm3) as solvent. The extraction was conducted over 8 h, with a frequency of 6–8 cycles per hour. Solvents were later evaporated from the extracts using a rotary evaporator, and the obtained liquid was purified by solid-phase extraction using Florisil magnesium silica cartridges (ThermoScientificHyperSep). At this stage, the 1:1 mixture of toluene and methanol was used as eluent. The obtained eluate was concentrated to 1 cm3 using a nitrogen evaporative concentrator. All of the samples were analysed using the Agilent 1200 Series HPLC System with a diode array detector. A solution of acetonitrile and Merck MilliQ water (8:2) was used as liquid phase, and the analytes were subsequently separated using Hypersil Green columns. A total of 16 priority PAH species were analysed (identified according to the obtained spectra and retention time): naphthalene (NAP), acenaphthylene (ACY), acenaphthene (ACE), fluorene (FLU), phenanthrene (PHE), anthracene (ANT), fluoranthene (FLA), pyrene (PYR), benzo(a)anthracene (BaA), chrysene (CHR), benzo(b)fluoranthene (BbF), benzo(k)fluoranthene (BkF), benzo(a)pyrene (BaP), indeno(1,2,3-c,d)pyrene (IcdP), dibenzo(a,h)anthracene (DahA) and benzo(g,h,i)perylene (BghiP). The limit of detection was quantified at 0.001 pg cm−3 (FLA) to 0.05 pg cm−3 (NAP), whereas the average recovery was estimated to be between 87 and 93%.
Weather conditions and air-mass back trajectories
Meteorological data obtained in Gdynia throughout 16/04/2012-15/05/2012
Additionally, 48-h air mass back trajectories were computed using the NOAA HYSPLIT Model (Stein et al. 2015) for each day, using 6-h intervals and arrival heights of 500, 1000 and 1500 m. Where trajectories were found to differ significantly, additional maps were created using the arrival height of the sampling location and 3-h time intervals. The method used was described in detail by Witkowska and Lewandowska (2016).
Statistical calculations of average, maximum and minimum values as well as standard deviations were made using the STATISTICA®, R and EXCEL® software, which was also used for the determination of linear regression coefficients, the standardisation of data and the graphic presentation of results. In order to determine statistically significant differences in more than two sets of independent and nonparametric data, the Kruskal-Wallis test was used. For all dependencies presented in the publication, the level of significance (p) was established at less than 0.05.
Quantification of dry deposition flux
Quantification of BaP-equivalent
Results and discussion
Variations of PM2.5 concentrations in the atmosphere over Gdynia
Mass concentrations of PM2.5 [μg m−3] and PAHs [ng m−3] obtained in Gdynia throughout April 16–May 15, 2012
Heating period (April 16–April 29, 2012)
Non-heating period (April 30–May 15, 2012)
34.85 ± 6.91
41.7 ± 7.40
3.89 ± 3.71
0.24 ± 0.12
5.96 ± 4.23
2.42 ± 1.31
0.53 ± 0.42
0.30 ± 0.19
0.26 ± 0.21
0.06 ± 0.1
0.08 ± 0.05
0.04 ± 0.03
1.05 ± 1.43
1.26 ± 0.68
7.94 ± 6.64
2.83 ± 1.92
0.45 ± 0.26
0.23 ± 0.15
0.19 ± 0.18
0.04 ± 0.04
0.15 ± 0.14
0.18 ± 0.19
0.22 ± 0.19
0.65 ± 0.50
0.42 ± 0.33
0.40 ± 0.59
0.12 ± 0.10
0.39 ± 0.49
0.33 ± 0.48
0.23 ± 0.13
0.87 ± 0.87
8.25 ± 7.90
3.27 ± 2.15
5.09 ± 1.78
3.97 ± 5.76
6.16 ± 4.27
12.56 ± 7.88
9.40 ± 4.64
Changes in PAHs concentration in PM2.5 in the atmosphere over Gdynia
It is well-established that particulate-bound PAHs display strong seasonal variations due to the presence or absence of combustion sources. Indeed, the mean ∑PAH16 concentration obtained in the non-heating season (9.40 ng m−3) was slightly lower than that quantified for the heating period (12.56 ng m−3) (Table 2). These values are comparable to these reported by Martellini and co-authors (Martellini et al. 2012), who found PM2.5-bound ∑PAH16 concentrations to range between 0.76 and 17 (winter) to 0.46 and 10 ng m−3 (summer) at an urban location in Italy (Florence, Tuscany). Much lower concentrations are reported for warmer regions of Europe that rely on coal and biomass combustion to a much lower extent (e.g. ∑PAH27 levels of less than 5 ngm−3 were measured in winter months in Athens by Alves et al. 2017). At the same time, concentrations found in Gdynia were significantly lower than in highly urbanised polluted areas, where PAH levels can be higher even by an order of magnitude. Mikuska and co-authors (Mikuska et al. 2015) reported ∑PAH16 concentrations in the range of 435–2316 ng m−3 during a 6-day winter smog episode in Ostrava (Czech Republic).
The dominant PAHs detected over the study period were BghiP (mean of 8.25 and 3.27 ngm−3 for the heating and non-heating season, respectively) and ACE (mean of 5.96 and 2.42 ngm−3 for the heating and non-heating season, respectively). Both compounds displayed a pronounced seasonality. Slightly lower were the levels of IcdP and NAP. The lowest average concentrations were noted for PHE (mean of 0.08 and 0.04 ngm−3 for the heating and non-heating season, respectively), which is consistent with its partitioning behaviour: due to its characteristics, PHE is mostly found in vapour phase (Ravindra et al. 2008). Average concentrations of DahA and BaP, compounds characterised by the high carcinogenicity, were relatively low and exhibited a similar pattern of elevated concentrations in the heating season (e.g. mean BaP concentrations of 0.23 and 0.08 ng m−3 were obtained for the heating and non-heating season).
Although seasonality in particle-bound PAH concentrations is well described for urbanised regions (Liu et al. 2015; Akyuz and Cabuk 2009), a small number of studies focus on medium-sized coastal cities like Gdynia and aerosols of less than 2.5 μm in diameter. Results obtained in Gdynia revealed that the average concentration of BaP (widely recognised as the representative PAH) was approximately three times higher during the heating period relative to the non-heating period (0.23 and 0.08 ng m−3, respectively). This was most likely due to the increased coal consumption in the investigated region (Ravindra et al. 2008; Lewandowska et al. 2018b). A pronounced summer-winter variation in PAH concentrations detected in PM2.5 in the coastal zone (Hong Kong) was previously reported by Guo and co-authors (Guo et al. 2003). The mean ∑PAH16 concentration obtained in the summer (4.87 ng m−3) was one order of magnitude lower than that noted in the winter months (41.75 ng m−3). The winter concentrations of PAHs were much higher in Hong Kong compared to those in Gdynia, which can be explained by the much larger population of Hong Kong combined with extensive maritime activity. Moreover, Guo et al. (2003) accounted for the entire winter season. At the same time, they observed BaP seasonality similar to the one seen in our data (winter levels approximately three times higher than summer; a mean of 2.06 and 0.73 ng m−3 in winter and summer, respectively). Comparable values were later reported by Villar-Vidal and co-authors (Villar-Vidal et al. 2014), who found PM2.5-bound BaP concentrations in Spanish coastal cities to range between 0.05 and 0.88 ng m−3. Other PAHs detected in PM2.5 in Gdynia revealed a similar trend with much higher concentrations noted during the heating period (Table 2), further supporting the hypothesis about the negative impact of domestic energy consumption on air quality. This phenomenon has previously been observed by several authors (Tobiszewski and Namiesnik 2012; Garrido et al. 2014; Lewandowska et al. 2018b).
The sampling location was situated near an industrial part of the city and was heavily influenced by residential heating. However, the trajectory analysis suggested that the highly contaminated air masses were transported from the Silesian Voivodeship in Southern Poland. Meteorological conditions largely determine the behaviour of atmospheric pollutants, and it is likely that the relatively low concentrations of PAHs detected in samples collected in coastal zones are a result of the highly efficient dispersal of contaminants (Lewandowska et al. 2018b).
Sources of PAHs
Major PAH source types can be differentiated by their species composition profile (i.e., ‘fingerprint’), permitting initial source type identification based on the ratio of individual compounds within diagnostic pairs. It is important that species paired for diagnostic ratio analysis have the same molecular mass and properties and are subject to similar transport and reaction processes in the atmosphere (Galarneau 2008; Tobiszewski and Namiesnik 2012). In general, petrogenic sources typically release lighter hydrocarbons, whereas compounds of pyrogenic origin are characterised by a higher molecular mass (Ravindra et al. 2008).
Based on PAHs values obtained in Gdynia in the study period (April 16, 2012–May 15, 2012) the FLA/(FLA + PYR) diagnostic ratio was calculated, revealing that detected PAHs originated from coal or wood combustion during both the heating and non-heating season (0.76 and 0.77, respectively) (De La Torre-Roche et al. 2009). The high mean IcdP/(IcdP+BghiP) ratio in the heating period (0.97) also pointed at the prevalence of pyrogenic sources in the studied region (Yunker et al. 2002; Ravindra et al. 2008). This further supports the previously stated hypothesis about domestic heating being the dominant PAH source in the first half of the study.
In the non-heating season, the mean IcdP/(IcdP+BghiP) ratio decreased twofold (0.40), which might suggest that the dominant source of PAHs changed from coal combustion to a petrogenic origin (Yunker et al. 2002; Hanedar et al. 2014). This was likely caused by the sampler’s proximity to several busy roads. The prevailing PAHs in the study period included ACE, NAP, BghiP and IcdP (Table 2), the first two typically emitted as a result of coal combustion (Tasdemir and Esen 2007), which could explain their elevated levels in the heating season. Concentrations of both decreased in the beginning of the non-heating period, whereas the dominant PAHs changed to BghiP and IcdP, commonly used as proxies for diesel engine emission (Yilmaz and Davis 2016). The lowest IcdP/(IcdP+BghiP) ratio noted over the analysed period was 0.14 (April 30, 2012) and could have been associated with the emission of PAHs from diesel engines (Yunker et al. 2002). Furthermore, hydrocarbons composed of three benzene rings were dominant throughout the entire sampling period (40.7%), with the percentage of highly carcinogenic 6-ring substances being slightly lower (30%). Such elevated abundances of 3- and 6-ring hydrocarbons have been found to be representative of diesel engine emissions (Yunker et al. 2002), which might suggest that the busy street located near the sampling device might have been a source of PAHs during the entire study, or that the prevalent winds blowing from the west carried contaminants from the adjacent bypass (Witkowska and Lewandowska 2016). Notably, a high (31%) percentage of vehicles registered in Gdynia are equipped with diesel engines that reportedly contribute to PAH pollution (https://bdl.stat.gov.pl). The mean BaA/(BaA+Chr) value (0.55) seems to further confirm the contribution of this source to the overall air pollution in Gdynia (Akyuz and Cabuk 2009).
It is also likely that the change of dominant source from pyrogenic into petrogenic was caused by maritime transport. The Baltic Sea is characterised by a high marine traffic, with 80% of cruise ships being able to accommodate more than 3,000 people. Most cruises take up to 20 h and are especially popular during warmer months. In this study, high concentrations of IcdP and BghiP seem to have been associated with an intensification of maritime activity in the port of Gdynia (Stankiewicz et al. 2010). For example, low IcdP/(IcdP+BghiP) ratios were noted for May 01–02, 2012 and May 06–09, 2012 (0.47 and 0.36, respectively). Such a pronounced trend was not obtained for ANT/(ANT+PHE), which did not display weekday/weekend variations and remained low (mean = 0.03) throughout the entire non-heating period, suggesting a petrogenic origin of PAHs. In addition to passenger vessels, the local port serves cargo and tank ships that, back in 2012, used heavy fuel oil and possibly emitted large amounts of HMW PAHs without a clear weekend schedule (Adams et al. 2014). Starting 2015, the Baltic Sea has become an Emissions Control Area and vessels now have to comply with strict SOx emission limits (Jonson et al. 2019). Nevertheless, it has been suggested that sea shipping might still be a significant source of airborne pollutants in Gdynia (Lewandowska et al. 2018a, b). Despite the new regulations, the increasing shipping in the port of Gdynia can cause an adverse effect on the environmental health of the particularly vulnerable, landlocked Baltic Sea (Stankiewicz et al. 2010).
Deposition flux of PM2.5 and associated PAHs
Once emitted, PAHs can be removed from the atmosphere via two major pathways: (i) photodegradation or (ii) wet and dry deposition. The latter have been found to be the most effective for particulate-bound PAHs. As a consequence, PAHs tend to accumulate in soil, as well as aquatic sediments (Ravindra et al. 2008). This is especially important in the case of heavy PAHs that bind to aerosols and undergo slow biodegradation in the natural environment. Their deposition velocity depends on the particle size and a range of meteorological parameters (e.g. air temperature or humidity) (Fang et al. 2004). Because of their high carcinogenic and mutagenic potential and the apparent tendency to accumulate in animal and plant tissues, it is crucial to assess the flux of PM 2.5-bound PAHs.
Conversely, temporal variations were much more pronounced for PAHs of low and high molecular weight. The average dry deposition flux was estimated at 528 ng m−2 day−1. In general, the highest values were obtained for HMW PAHs, followed by slightly lower numbers quantified for LMW PAHs (792 and 698 ng m−2 day−1, respectively). The mean total daily flux of PAHs was estimated at 4923 ng m−2 day−1, which is comparable to the value reported by Terzi and Samara (2005) for a coastal sampling point located in Greece (3917 ng m−2 day−1). Much higher values are often noted for highly urbanised and industrial regions. For example, Fang and co-authors (Fang et al. 2004) estimated dry deposition fluxes of total PAHs to be as high as 58,500 ng m−2 day−1 in the industrial area in Taiwan.
The highest total flux of ∑PAHs16 was noted in the heating period, on April 17–18, 2012. The FLA/(FLA + PYR) ratio of 0.78 suggested an existing pyrogenic source of airborne pollutants (De La Torre-Roche et al. 2009). In this case, the analysis of air trajectories revealed that air masses were advected from the local bypass, as well as the Kashubian region (W-SW, Fig. 4b). This observation further confirmed the relatively high contribution of domestic heating and road traffic to the air quality of Gdynia.
The carcinogenic potential of PAHs based on the BaP equivalent method
Over the analysed period, the average BaP equivalent concentration was estimated at 0.9 ng m−3. Similar values have previously been found in Florence, Italy (0.79 ng m−3) (Martellini et al. 2012) and Hamilton, Canada (0.84 ng m−3) (Anastasopoulos et al. 2012). At the same time, much higher values have been reported in industrial, densely populated and polluted regions such as Guangzhou, China (max = 22.46 ng m−3) (Liu et al. 2015).
The mean BaPE was significantly higher during the heating period relative to the non-heating season (0.81 and 0.48 ng m−3), again pointing at domestic heating sources of PAHs contributing to the overall air quality of Gdynia over the analysed period. On April 22, 2012 (Sunday) the carcinogenic potential reached 1.4 ng m−3 as a result of elevated concentrations of highly mutagenic DahA and BF detected in PM2.5 aerosols. This peak was most likely to the prevailing southerly winds, which could have caused an advection of contaminants from the highly polluted Kashubian region or the local bypass during weekend road traffic.
The average concentrations of PAHs detected in PM2.5 aerosols in Gdynia were found to be relatively low throughout the whole study. PAH levels were generally higher during the heating season. That was likely due to PAH emission associated with fossil fuel combustion for domestic heating (pyrogenic sources). However, concentrations of highly carcinogenic heavy hydrocarbons increased during the non-heating season as a result of sea shipping in the Gulf of Gdansk (petrogenic source). At the same time, it is possible that a large portion of PAHs originated from diesel engine emissions. Levels of hazardous compounds associated with small aerosols should be carefully monitored throughout the upcoming years, so appropriate measures can be taken. Although domestic heating and vehicle emission remain the main contributors to air pollution in Poland, it is important to account for all of the possible PAH sources. Obtained results suggest that in coastal locations, maritime emission might be underestimated and should receive more attention. This is especially crucial given the ongoing rapid expansion of sea shipping on the global scale and its increasing effect on air quality.
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