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Metal- and halide-free solid-type multifunctional alkanolamines as catalysts for cycloaddition of CO2

  • Hyeon-Gook Kim
  • Hye Jeong Son
  • Choong-Sun Lim
Article
  • 15 Downloads

Abstract

Although the production of cyclic carbonates from CO2 and epoxides can be promoted by eco-friendly halogen- and metal-free organic catalysts, its homogeneity complicates the catalyst reuse. Herein, we synthesized solid multifunctional alkanolamines using simple epoxy and amine reactions, and analyzed their structures by IR and 13CNMR. Then, we employed these as catalysts for CO2 cycloaddition with propylene oxide, obtaining propylene carbonate in 98% yield after 3 h at 120 °C. Moreover, at 60 °C, the reaction was successfully repeated five times and a product yield of 50% was maintained throughout.

Keywords

Alkanolamine Carbon Dioxide Fixation Metal- and Halide-free Solid Catalyst Propylene Carbonate 

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Metal- and halide-free solid-type multifunctional alkanolamines as catalysts for cycloaddition of CO2

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Copyright information

© Korean Institute of Chemical Engineers, Seoul, Korea 2018

Authors and Affiliations

  • Hyeon-Gook Kim
    • 1
  • Hye Jeong Son
    • 1
  • Choong-Sun Lim
    • 1
  1. 1.Advanced Industrial Chemistry Research Center, Advanced Convergent Chemistry DivisionKorea Research Institute of Chemical TechnologyUlsanKorea

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