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Promoting Si-graphite composite anodes with SWCNT additives for half and NCM811 full lithium ion batteries and assessment criteria from an industrial perspective

  • Jingning ShanEmail author
  • Xiaofang Yang
  • Chao Yan
  • Lin Chen
  • Fang Zhao
  • Yiguang JuEmail author
Research Article

Abstract

Single wall carbon nanotube (SWCNT) additives were formulated into µm-Si-graphite composite electrodes and tested in both half cells and full cells with high nickel cathodes. The critical role of small amount of SWCNT addition (0.2 wt%) was found for significantly improving delithiation capacity, first cycle coulombic efficiency (FCE), and capacity retention. Particularly, Si (10 wt%)-graphite electrode exhibits 560 mAh/g delithiation capacity and 92% FCE at 0.2 C during the first charge-discharge cycle, and 91% capacity retention after 50 cycles (0.5 C) in a half cell. Scanning electron microscope (SEM) was used to illustrate the electrode morphology, compositions and promoting function of the SWCNT additives. In addition, full cells assembled with high nickel-NCM811 cathodes and µm-Si-graphite composite anodes were evaluated for the consistence between half and full cell performance, and the consideration for potential commercial application. Finally, criteria to assess Si-containing anodes are proposed and discussed from an industrial perspective.

Keywords

lithium-ion battery Si anode Si-graphite composite single wall carbon nanotube (SWCNT) NCM811 

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Notes

Acknowledgements

The authors thank HiT Nano Inc, ACEE and the grant from DOE SBIR Project. Yiguang Ju would like to thank the support from NSF CMMI-1449314 and the grant of electrification of transportation from the Andlinger Center for Energy and the Environment at Princeton University.

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Copyright information

© Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Department of Mechanical and Aerospace EngineeringPrinceton UniversityPrincetonUSA
  2. 2.HiT Nano, IncPrincetonUSA
  3. 3.Department of Mechatronics Engineering, College of Mechanical EngineeringGuangxi UniversityNanningChina
  4. 4.Department of PhysicsPrinceton UniversityPrincetonUSA

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