Stationary and transient acoustically induced birefringence of methyl acetate molecules dissolved in ethanol

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A detailed study of the acoustically induced birefringence has been performed in methyl acetate molecules in solutions with ethanol to evaluate the relative variations of the acoustic intensity. Static and dynamic birefringence signals are ascribed to the orientation of the molecules along the direction of the applied ultrasonic field. The birefringence in dilute and concentrated solutions was investigated as a function of frequency, ultrasonic intensity and concentration. The transient behavior of the birefringence is indicative of a single exponential function implying a single relaxation mechanism. Systematic analysis of the experimental results is performed in the context of the presence of two distinct types of MA molecules in the solutions, namely the molecules that are similar to those existing in bulk material and the “solution”-type molecules that are distorted after the interaction with the ethanol/solvent molecules. The estimated relatively slow relaxation times, obtained from the transient birefringence measurements, imply that the acoustically induced birefringence is affected by the collective motion over the short-to-medium range order. Relaxation times exhibit a characteristic change below and above ~ 0.6 volume fraction of MA, which is related to the presence of the two discrete types of methyl acetate molecules in the solutions.

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  1. Agarwal L, Pavani V, Rao DP, Kaistha N (2010) Process intensification in HiGee absorption and distillation: design procedure and applications. Ind Eng Chem Res 49:10046–10058.

  2. De Gennes PG, Prost J (1993) The physics of liquid crystals. Claredron, Oxford

  3. Fair MC, Anderson JL (1989) Electrophoresis of nonuniformly charged ellipsoidal particles. J Colloid Interface Sci 127:388–400.

  4. Fan S, Chapline M, Franklin N, Tombler T, Cassell A, Dai H (1999) Self-oriented regular arrays of carbon nanotubes and their emission field emission properties. Sience 283:512–514.

  5. Frohlich H (1949) Theory of dielectrics; dielectric constant and dielectric loss. Oxford Clarendon Press, London

  6. Harmsen GJ (2007) Reactive distillation: the front-runner of industrial process intensification. A full review of commercial applications, research, scale-up, design and operation. Chem Eng Proc Proc Int 46:774–780.

  7. Hilyard NC, Jerrard HG (1962) Theories of birefringence induced in liquids by ultrasonic waves. J Appl Phys 33:3470–3479.

  8. Hiwale RS, Bhate NV, Mahajani YS, Mahajani SM (2004) Industrial applications of reactive distillation: recent trends. Int J Chem React Eng 2:1–52.

  9. Hurtado-Aviles EA, Torres JA, Trejo-Valdez M, Romero-Ángeles B, Villalpando I, Torres-Torres C (2018) Amplitude-modulated acoustic waves by nonlinear optical signals in bimetallic Au-Pt nanoparticles and ethanol based nanofluids. J Mol Liq 263:288–293.

  10. Hurtado-Aviles EA, Torres JA, Trejo-Valdez M, Torres-SanMiguel CR, Villalpando I, Torres-Torres C (2019) Ultrasonic influence on plasmonic effects exhibited by photoactive bimetallic Au-Pt nanoparticles suspended in ethanol. Materials 12:1791.

  11. Jerrard HG (1964) Birefringence induced in liquids and solutions by ultrasonic waves. Ultrasonics 2:74–81.

  12. Kalampounias AG (2012a) Picosecond dynamics from lanthanide chloride melts. J Mol Struct 1030:125–130.

  13. Kalampounias AG (2012b) Manifestation of thermodynamic glass transition by structure and picosecond dynamics in alkali tellurite glasses. J Non-Cryst Solids 358:2796–2802.

  14. Kalampounias AG, Tsilomelekis G, Boghosian S (2015) Vibrational dephasing and frequency shifts of hydrogen-bonded pyridine–water complexes. Spectrochim Acta A 135:31–38.

  15. Kumbharkhane AC, Puranik SM, Mehrotra SC (1993) Dielectric relaxation studies of aqueous N, N-dimethylformamide using a picosecond time domain technique. J Solut Chem 22:219–229.

  16. Li J, Ng HT, Cassell A, Fan W, Chen H, Ye Q, Koehne J, Han J, Meyyappan M (2003) Carbon nanotube nanoelectrode array for ultrasensitive DNA detection. Nano Lett 3:597–602.

  17. Li L, Liu Y, Zhang F, Sun Z (2017) Several explanations on the theoretical formula of Helmholtz resonator. Adv Eng Softw 114:361–371.

  18. Lipeles R, Kivelson D (1980) Experimental studies of acoustically induced birefringence. J Chem Phys 72:6199–6208.

  19. Love AEH (1888) The small free vibrations and deformation of a thin elastic shell. Philos Trans R Soc A Math Phys Eng Sci 179:491–546.

  20. Martinoty P, Bader M (1981) Measurement of the birefringence induced in liquids by ultrasonic waves: application to the study of the isotropic phase of PAA near the transition point. J Phys 42:1097–1102.

  21. Matsuoka T, Yasuda K, Koda S, Nomura H (1999) On the frequency dependence of ultrasonically induced birefringence in isotropic phase of liquid crystal: 5CB (p-n-pentyl p’-cyanobiphenyl). J Chem Phys 111:1580–1586.

  22. Matsuoka T, Koda S, Nomura H (2000) Linear and nonlinear ultrasonically induced birefringence in polymer solutions. Jpn J Appl Phys 39:2902–2905.

  23. Matsuoka T, Yasuda K, Yamamoto K, Koda S, Nomura H (2007) Dynamics of ultrasonically induced birefringence of in rod-like colloidal solutions. Colloids Surf B Biointerfaces 56:72–79.

  24. Mendonça CR, Neves UM, Guedes I, Zilio SC, Misoguti L (2006) Coherent control of optically induced birefringence in azoaromatic molecules. Phys Rev A 74:025401-1–025401-4.

  25. Mpourazanis P, Stogiannidis G, Tsigoias S, Kalampounias AG (2019a) Transverse phonons and intermediate-range order in Sr-Mg fluorophosphate glasses. Spectrochim Acta A 212:363–370.

  26. Mpourazanis P, Stogiannidis G, Tsigoias S, Papatheodorou GN, Kalampounias AG (2019b) Ionic to covalent glass network transition: effects on elastic and vibrational properties according to ultrasonic echography and Raman spectroscopy. J Phys Chem Solids 125:43–50.

  27. Natansohn A, Rochon P, Gosselin J, Xie S (1992) Azo polymers for reversible optical storage. 1. Poly[4′-[[2-(acryloyloxy)ethyl]ethylamino]-4-nitroazobenzene]. Macromolecules 25:2268–2273.

  28. Nomura H, Matsuoka T, Koda S (2002) Translational-orientational coupling motion of molecules in liquids and solutions. J Mol Liq 96–97:135–151.

  29. Nomura H, Matsuoka T, Koda S (2004) Ultrasonically induced birefringence in liquids and solutions. In: Samios J, Durov VA (eds) Novel approaches to the structure and dynamics of liquids: experiments, theories and simulations. Kluwer Academic Publishers, Dordrecht, pp 167–192.

  30. Oka S (1939) Zur Theorie der Doppelbrechung bei nicht-kugelförmigen Kolloiden im Ultraschallfelde. Kolloid Z 87:37–43.

  31. Oka S (1940) Zur Theorie der akustischen Doppelbrechung von kolloidalen Lösungen. Z Phys 116:632–651.

  32. Ou-Yang HD, MacPhail RA, Kivelson D (1986) Nonlinear ultrasonically induced birefringence in gold sols: frequency-dependent diffusion. Phys Rev A 33:611–619.

  33. Scruby CB, Drain LE (1990) Laser ultrasonics. Adam Higler, Bristol

  34. Shirke RM, Chaudhari A, More NM, Patil PB (2000) Dielectric measurements on methyl acetate + alcohol mixtures at (288, 298, 308, and 318) K using the time domain technique. J Chem Eng Data 45:917–919.

  35. Stogiannidis G, Tsigoias S, Mpourazanis P, Boghosian S, Kaziannis S, Kalampounias AG (2019) Dynamics and vibrational coupling of methyl acetate dissolved in ethanol. Chem Phys 522:1–9.

  36. Yasuda K, Matsuoka T, Koda S, Nomura H (1994) Linear and nonlinear ultrasonically induced birefringence in polymer solutions. Jpn J Appl Phys 33:2901–2905.

  37. Yasuda K, Matsuoka T, Koda S, Nomura H (1996) Frequency dependence of ultrasonically induced birefringence of rodlike particles. J Phys Chem 100:5892–5897.

  38. Yasuda K, Matsuoka T, Koda S, Nomura H (1997) Dynamics of entanglement networks of rodlike micelles studied by measurements of ultrasonically induced birefringence. J Phys Chem B 101:1138–1141.

  39. Yesilkoy F, Terborg RA, Pello J, Belushkin AA, Jahani Y, Pruneri V, Altug H (2018) Phase-sensitive plasmonic biosensor using a portable and large field-of-view interferometric microarray imager. Light Sci Appl 7:17152.

  40. Zhang L, Deng L, Zhou Y, Liu C, Fan S (2016) Photodetection and photoswitch based on polarized optical response of macroscopically aligned carbon nanotubes. Nano Lett 16:6378–6382.

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The authors gratefully acknowledge financial support from the University of Ioannina. Furthermore, we would like to express our thanks to Professor Dr. C. Kosmidis and the personnel of the Central Laser Facility of Ioannina University for access on their facilities and their help.

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Correspondence to A. G. Kalampounias.

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Stogiannidis, G., Tsigoias, S., Kaziannis, S. et al. Stationary and transient acoustically induced birefringence of methyl acetate molecules dissolved in ethanol. Chem. Pap. (2020).

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  • Acoustically induced birefringence
  • Stationary birefringence
  • Transient birefringence
  • Reorientational relaxation
  • Collective motion