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Synthesis and investigation of structural, optical, dielectric and electronic properties of a new hybrid: [C13H21N2O2](Cd(SCN)3)

  • Rahma Jabbar
  • Francois Michaud
  • Slaheddine KamounEmail author
Original Paper
  • 23 Downloads

Abstract

A new ferroelectric relaxor: [C13H21N2O2](Cd(SCN)3) procainium tris(thiocyanato) cadmiate(II) was synthesized and studied by single-crystal XRD. This compound crystallizes in the orthorhombic system with acentric space group Pna21. The crystal structure is formed of discrete ionic entities (C13H21N2O2)+ and [Cd(SCN)3]. The cadmium atom has 3N3S hexa coordinated octahedral geometry. The sulfur atoms and the nitrogen atoms are in facial mode (fac). Each pair of cadmium atoms is triply bridged by μ-1,3-SCN–bridge. Consequently, a linear polymeric chain is formed. The procainium cations are bonded to these chains by hydrogen-bonding contacts and π–ring interaction. DSC measurement shows that this compound exhibits a diffuse ferro–paraelectric phase transition around 356 K. Dielectric study exhibits a relaxor behavior characterized by the transition temperature shifts toward higher temperature with the rise of frequency. This behavior was validated by the Vogel–Fulcher relationship and the modified Curie–Weiss law. The diffuseness parameter was γ = 1.96. The optical band gap Eg = 2.20 eV was estimated by diffuse reflection spectroscopy (DRS) investigation.

Keywords

Structure Ferroelectric relaxor Vogel–Fulcher model Modulus Conductivity 

Notes

Acknowledgements

The authors gratefully acknowledge the support of the Tunisian Ministry of Higher Education and Scientific Research for LR11ES46.

Compliance with ethical standards

Conflict of interest

On behalf of all authors, the corresponding author states that there is no conflict of interest.

Supplementary material

11696_2019_691_MOESM1_ESM.docx (20.9 mb)
Supplementary material 1 (DOCX 21402 kb)

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Copyright information

© Institute of Chemistry, Slovak Academy of Sciences 2019

Authors and Affiliations

  1. 1.Laboratoire de Génie des Matériaux et Environnement, Ecole Nationale d’Ingénieurs de SfaxUniversite´ de SfaxSfaxTunisia
  2. 2.Service commun d’analyse par diffraction des rayons XUniversité de BrestBrest Cedex 3France

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