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Journal of Phase Equilibria and Diffusion

, Volume 40, Issue 6, pp 787–796 | Cite as

Phase Relations in the FeSe–FeGa2Se4–FeIn2Se4 System: Refinement of the Crystal Structures of FeIn2Se4 and FeGaInSe4

  • Faik Mammadagha Mammadov
  • Imamaddin Rajabali Amiraslanov
  • Samira Zakir Imamaliyeva
  • Mahammad Baba BabanlyEmail author
Article
  • 12 Downloads

Abstract

The phase equilibria in the FeSe–FeGa2Se4–FeIn2Se4 system were studied using the differential thermal analysis (DTA) and x-ray diffraction (XRD) methods. An isothermal section at 700 K, some isopleths sections of the phase diagram, and the projection of the liquidus surface were constructed. The results show that the 2FeSe–FeGaInSe4 section is quasibinary and of eutectic type. The crystal structure of FeGaInSe4 was refined by the Rietveld method, revealing that this compound cannot be regarded as an ordinary substitutional solid solution but as an ordered phase that differs qualitatively from FeIn2Se4 in the occupancy of crystallographic positions.

Keywords

crystal structure FeSe–FeGa2Se4–FeIn2Se4 system FeGaInSe4 phase diagram Rietveld refinement solid solutions 

Notes

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Copyright information

© ASM International 2019

Authors and Affiliations

  1. 1.Institute of Catalysis and Inorganic Chemistry Named After Acad. M. NagiyevAzerbaijan National Academy of SciencesBakuAzerbaijan
  2. 2.Institute of PhysicsAzerbaijan National Academy of SciencesBakuAzerbaijan

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