Journal of Electronic Materials

, Volume 48, Issue 4, pp 1840–1845 | Cite as

ZnO-Nanoparticle-Dispersed Cu11.5Ni0.5Sb4S13−δ Tetrahedrite Composites with Enhanced Thermoelectric Performance

  • Fu-Hua Sun
  • Jinfeng Dong
  • Huaichao Tang
  • Hua-Lu Zhuang
  • Jing-Feng LiEmail author
Topical Collection: International Conference on Thermoelectrics 2018
Part of the following topical collections:
  1. International Conference on Thermoelectrics 2018


Cu12Sb4S13 tetrahedrite is an abundant natural that is also environmentally friendly. There have been efforts made to reach a unity of ZT value through optimizing the interdependence of electrical and thermal performance. In this study, we reported on ZnO nanoparticles-dispersed Cu11.5Ni0.5Sb4S13−δ composites that were synthesized by the mechanical alloying and spark plasma sintering method. The structural characterizations were conducted via scanning electron microscopy, electronic probe microscopic analysis and transmission electron microscopy. The ZnO-nanoparticles were uniformly distributed in the Cu12Sb4S13 grains. ZnO was used as a heterogeneous nucleation site to reveal the effectiveness of reducing thermal conductivity, likely derived from the strong low/mid-frequency phonon scattering. The lowest lattice thermal conductivity, 0.33 W m−1 K−1, was obtained at 673 K in 0.5 vol.% of ZnO sample. A small quantity of ZnO addition led to a high ZT ∼ 1.0 at 723 K, which increased by ∼ 42% in the pure-phased Cu12Sb4S13−δ sample.


Thermoelectric tetrahedrite ZnO mechanical alloying 


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This work was supported by National Key R&D Program of China (Grant No. 2018YFB0703603) and the National Natural Science Foundation of China (Grant No. 11474176).


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Copyright information

© The Minerals, Metals & Materials Society 2018

Authors and Affiliations

  1. 1.State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and EngineeringTsinghua UniversityBeijingPeople’s Republic of China

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