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Even-carbon predominance of Monomethyl branched alkanes in Humic coal from Junggar Basin, NW China

  • Qingsong Cheng
  • Min ZhangEmail author
  • Guanghui Huang
Original Article
  • 13 Downloads

Abstract

A series of Monomethyl branched alkanes compounds were detected between nC14–nC36, in immature and low maturity Jurassic humic coal, Junggar basin. 2-methyl alkanes and 3-methyl alkanes accounted for the vast majority of the compounds. It is worth noting that the 2-methyl alkanes in the humic coal samples show an obvious distribution of even carbon predominances rarely reported in the literature. The results show that with the increase of Pr/Ph (pristane/phytane), the even carbon dominance of 2-methyl alkanes is more obvious, while the odd carbon number distribution of 3-methyl alkanes is weakened. As Pr/Ph increases in the humic coal, the relative content of the hopanes increased, while the relative content of 2-methyl alkanes and 3-methyl alkanes increases first and then decreases.

Keywords

Junggar basin Humic coal Even carbon predominance 2-methyl alkanes 3-methyl alkanes 

Notes

Acknowledgements

This research was financially supported by the National Natural Science Foundation of China (No. 41772124) and National Science and Technology Major Project (No. 2016ZX05007001-002).

References

  1. Alexander R, Kagi RI, Noble R, Volkman JK (1984) Identification of some bicyclic alkanes in petroleum. Org Geochem 6:63–72Google Scholar
  2. Arouri K, Conaghan PJ, Walter MR et al (2000) Reconnaissance sedimentology and hydrocarbon biomarkers of Ediacarian microbial mats and acritarchs, Lower Ungoolya Group, Officer Basin. Precambr Res 100(1/3):235–280.  https://doi.org/10.1016/S0301-9268(99)00076-5 Google Scholar
  3. ASTM D7708-14 (2014) Standard test method for microscopical determination of the reflectance of vitrinite dispersed in sedimentary rocks, ASTM International, West Conshohocken, PA, www.astm.org
  4. Audino M, Grice K, Alexander R et al (2001) Unusual distribution of mono-methyl alkanes in Botryococcus braunii-rich samples: origin and siginificance. Geochim Cosmochim Acta 65(12):1995–2006.  https://doi.org/10.1016/S0016-7037(01)00568-3 Google Scholar
  5. Cheng Q-S, Zhang M, Huang G-H, Zhang W-J (2019a) The contribution of bacteria to organic matter in coal-measure source rocks. Acta Geochimica 38(3):364–375.  https://doi.org/10.1007/s11631-018-0304-5 Google Scholar
  6. Cheng Q-S, Huang G-H, Zhang M, Zhang W-J, Liu X (2019b) Distribution and source significance of 2-methylalkanes in coal-measure source rocks, northwest china. J Petrol Sci Eng 174:257–267.  https://doi.org/10.1016/j.petrol.2018.11.014 Google Scholar
  7. Connan J, Bouroullec J, Dessort D et al (1986) The microbial input in carbonate-anhydrite facies of a sabkha palaeoenvironment from Guatemala: a molecular approach. Org Geochem 10(1):29–50.  https://doi.org/10.1016/0146-6380(86)90007-0 Google Scholar
  8. Fowler MG, Douglas AG (1987) Saturated hydrocarbon biomarkers in oils of Late Precambrian age from Eastern Siberia. Org Geochem 11(3):201–213.  https://doi.org/10.1016/0146-6380(87)90023-4 Google Scholar
  9. Gelin JK, Volkman C, Largeau S et al (1999) Distribution of aliphatic, nonhydrolyzable biopolymers in marine microalgae. Org Geochem 30(147):159.  https://doi.org/10.1016/S0146-6380(98)00206-X Google Scholar
  10. Han J, Calvin M (1970) Branched alkanes from blue-green algae. J Chem Soc D Chem Commun 22:1490–1491.  https://doi.org/10.1039/c29700001490 Google Scholar
  11. He Q, Liu J, Xu Z-H et al (2009) Origin and biosynthetic effects on the stable carbon isotopic compositions of 3-methyl and 2-methyl alkanes in tobacco leaves. Geochimica 38(3):282–288.  https://doi.org/10.1016/S1874-8651(10)60080-4 Google Scholar
  12. Heemann V, Brummer U, Paulsen C, Seehofer F (1983) Composition of the leaf surface gum of some Nicotiana species and Nicoyiana tabacum cultivars. Phytochemistry 22(1):133–135.  https://doi.org/10.1016/S0031-9422(00)80073-4 Google Scholar
  13. Hou D-J, Wang P-R, Lin R-Z, Li Z-S (1992) Distribution of some diterpenoid hydrocarbons in Huangxian brown coal and their thermal evolution. Acta Petrolel Sinica 13(3):27–35.  https://doi.org/10.1007/bf02677081 Google Scholar
  14. Hou D-J, Wang T-G, Huang G-H, et al (1994) Distribution patterns of pentacyclic triterpenoid hydrocarbons in source rocks. J Oil Gas Technol 16(4):39-45.http://www.en.cnki.com.cn/Article_en/CJFDTOTAL-JHSX404.007.htm
  15. Huang D-F, Li J-C, Zhang D-J et al (1991) Maturation sequence of tertiary crude oils in the qaidam basin and its significance in petroleum resource assessment. J SE Asian Earth Sci 5(1–4):359–366.  https://doi.org/10.1016/0743-9547(91)90049-4 Google Scholar
  16. Huang G-H, Wang T-G, Zhong N-N, Xiong B (1993) Compositional Characteristics of the Jurassic Crude oil and oil- source Correlation in BeiPiao Basin. J Oil Gas Technol 15(1):21–27.http://en.cnki.com.cn/Article_en/CJFDTOTAL-JHSX199301004.htm
  17. Huang H-P, Zheng Y-B, Zhang Z-W et al (2003) Lower aquatic organisms: an important source of high waxy oil formation. Chin Sci Bull 48(10):1092–1098.  https://doi.org/10.3321/j.issn:0023-074X.2003.10.021 Google Scholar
  18. Huang X, Meyers PA, Wu W et al (2011) Significance of long chain iso, and anteiso, monomethyl alkanes in the Lamiaceae (mint family). Org Geochem 42(2):156–165.  https://doi.org/10.1016/j.orggeochem.2010.11.008 Google Scholar
  19. ISO 7404-2. Methods for the petrographic analysis of coals—Part 2: Method of preparing coal samples. International Organization for Standardization, ISO 7404-2:2009(en). www.iso.org/standard/42832.html
  20. ISO 7404-5. Methods for the petrographic analysis of coals—Part 5: Methods of preparing coal samples. International Organization for Standardization, ISO 7404-5:2009(en). www.iso.org/standard/42798.html
  21. Ji L-M, Li J-F, Song Z-G (2009) Petroleum geological significance of Botryococcus in TriassicYanchang Formation, Ordos Basin. Petrol Explor Dev 36(2):156–165.  https://doi.org/10.3321/j.issn:1000-0747.2009.02.004 Google Scholar
  22. Johns RB, Belsky T, McCarthy ED et al (1966) The organic geochemistry of ancient sediments—Part III. Geochim Cosmochim Acta 30(12):1191–1222.  https://doi.org/10.1016/0016-7037(66)90120-7 Google Scholar
  23. Kenig F (2000) C16–C29 homologous series of monomethyl alkanes in the pyrolysis products of a Holocene microbial mat. Org Geochem 31(2/3):237–241.  https://doi.org/10.1016/S0146-6380(99)00158-8 Google Scholar
  24. Kenig F, Damsté JSS, de Leeuw JW et al (1994) Molecular palaeonto-logical evidence for food-web relationships? Naturwissen-schaften 81(3):128–130.  https://doi.org/10.1007/BF01131768 Google Scholar
  25. Killops SD, Carlson RMK, Peters KE (2000) High-temperature GC evidence for the early formation of C40 + n-alkanes in coals. Org Geochem 31(6):589–597.  https://doi.org/10.1016/s0140-6701(02)85010-x Google Scholar
  26. Kissin YV (1987) Catagenesis and composition of petroleum: origin of n-alkanes and isoalkanes in petroleum crudes. Geochim Cosmochim Acta 51(9):2445–2457.  https://doi.org/10.1016/0016-7037(87)90296-1 Google Scholar
  27. Klomp UC (1986) The chemical structure of a pronounced series of 2-methy alkanes in South Oman crudes. Org Geochem 10(4/6):807–814.  https://doi.org/10.1016/0016-7037(87)90296-1 Google Scholar
  28. Kolattukudy PE (1969) Plant waxes. Lipids 5(2):259–275.  https://doi.org/10.1007/BF02532477 Google Scholar
  29. Krkošová Ž, Kubinec R, Addová G et al (2007) Gas chromatographic-mass spectrometric characterization of monomethyl alkanes from fuel diesel. Pet Coal 49(3):51–62Google Scholar
  30. Logan GA, Calver CR, Gorjan P et al (1999) Terminal Proterozoic mid-shelf benthic microbial mats in the Centralian Superbasin and their environmental significance. Geochim Cosmochim Acta 63(9):1345–1358.  https://doi.org/10.1016/S0016-7037(99)00033-2 Google Scholar
  31. Logan GA, Hinman MC, Walter MR et al (2001) Biogeochemistry of the 1640 Ma McArthur River (HYC) lead-zinc ore and host sediments, Northern Territory, Australia. Geochim Cosmochim Acta 65(14):2317–2336.  https://doi.org/10.1016/S0016-7037(01)00599-3 Google Scholar
  32. Love GD, Stalvies C, Grosjean E et al (2008) Analysis of molecular biomarkers covalently bound within Neoproterozoic sedimentary kerogen. In: Kelley PH, Bambach RK (eds) From evolution to geobiology: research questions driving paleontology at the start of a new century, Paleontological Society Short Course, October 4, pp 67–93Google Scholar
  33. Lu H, Peng P-A, Sun Y-G (2003) Molecular and stable carbon isotopic composition of monomethylalkanes from one oil sand sample: source implications. Org Geochem 34(6):745–754.  https://doi.org/10.1016/S0146-6380(03)00039-1 Google Scholar
  34. Luo B-J, Wang G-Y, Li X-Y et al (1986) Identification of a novel species of hexacylic a romatic hopanoids and discussion of their geochemical significance. Acta Sedimentol Sin 4(02):128–132.  https://doi.org/10.14027/j.cnki.cjxb.1986.02.015 Google Scholar
  35. Ly TTB, Schifrin A, Nguyen BD, Bernhardt R (2017) Improvement of a p450-based recombinant escherichia coli whole-cell system for the production of oxygenated sesquiterpene derivatives. J Agric Food Chem.  https://doi.org/10.1021/acs.jafc.7b00792 Google Scholar
  36. Mc Carthy ED, Han J, Calvin M (1968) Hydrogen atom transfer in mass spectrometric fragmentaion patterns of saturated aliphatic hydrocarbons. Analyt Chem 40:1475–1480.  https://doi.org/10.1021/ac60266a021 Google Scholar
  37. Peters KE, Moldowan JM (1991) Effects of source, thermal maturity, and biodegradation on the distribution and isomerization of homohopanes in petroleum. Org Geochem 17(1):47–61.  https://doi.org/10.1016/0146-6380(91)90039-M Google Scholar
  38. Philp RP (1983) Correlation of crude oils from the san jorges basin, argentina. Geochim Cosmochim Acta 47(2):267–275.  https://doi.org/10.1016/0016-7037(83)90139-4 Google Scholar
  39. Philp RP (1987) Fossil Fuel biomarkers: applications and spectra, Fu Jiamo, Sheng Guoying, trans. Science Press, Beijing, pp 44–48Google Scholar
  40. Pickel W, Kus J, Flores D, Kalaitzidis S, Christanis K, Cardott BJ, Misz-Kennan M, Rodrigues S, Hentschel A, Hamor-Vido M, Crosdale P, Wagner N, ICCP (2017) Classification of liptinite–ICCP System 1994. Int J Coal Geol 169:40–61.  https://doi.org/10.1016/j.coal.2016.11.004 Google Scholar
  41. Qian Y, Wang Z-D, Tuo J-C et al (2017) Origin and significance of monomethyl alkanes from Yanchang Formation source rocks in Ordos Basin. Petrol Geol Exp 39(1):86–93.  https://doi.org/10.11781/sysydz201701086 Google Scholar
  42. Shiea J, Brassell SC, Ward DM (1990) Mid-chain branched mono-and dimethylakanes in hot spring cyanbacterial mats: a direct biogenic source for branched alkanes in ancient sediments? Org Geochem 15(3):223–231.  https://doi.org/10.1016/0146-6380(90)90001-G Google Scholar
  43. Summons RE (1987) Branched alkanes from ancient and modern sediments: isomer discrimination by GC/MS with multiple reaction monitoring. Org Geochem 11(4):281–289.  https://doi.org/10.1016/0146-6380(87)90039-8 Google Scholar
  44. Summons RE, Powell TG, Boreham CJ (1988) Petroleum geology and geochemistry of the Middle Proterozoic Mcarthur Basin, Northern Australia: III Composition of extractable hydrocarbons. Geochimica Cosmochimica Acta 52(7):1747–1763.  https://doi.org/10.1016/0016-7037(88)90001-4 Google Scholar
  45. Sun L-N, Zhang Z-N, Wu Y-D et al (2015) Evolution patterns and their significances of biomarker maturity parameters—a case study on liquid hydrocarbons from type III source rock under HTHP hydrous pyrolysis. Oil Gas Geol 36(4):573–580.  https://doi.org/10.11743/ogg20150406 Google Scholar
  46. Tegelaar EW, Matthezing RM, Jansen JBH et al (1989) Possible origin of n-alkanes in high-wax crude oils. Nature 342(6249):529–531.  https://doi.org/10.1038/342529a0 Google Scholar
  47. Thiel V, Jenisch A, Wörheide G et al (1999) Mid-chain branched alkanoicacids from “living fossil” demosponges: a link to ancient sedimentary lipids? Org Geochem 30(1):1–14.  https://doi.org/10.1016/S0146-6380(98)00200-9 Google Scholar
  48. Tissot BP, Welte DH (1984) Petroleum formation and occurrence. Springer, BerlinGoogle Scholar
  49. Wang C-J, Xia Y-Q, Zhang Z-N et al (1997) Chemical structures of Branched alkanes identified in Jurassic Coals and Coal-related mudstones from the Turpan-Hami basin and their geochemical significance. Geochimica 26(1):72–84.  https://doi.org/10.1016/S0140-6701(97)84394-9 Google Scholar
  50. Wang T-G, Sheng G-Y, Chen J-H, Fu J-M (1995a) Biomarker assemblage of algal coal in Shuicheng, Western Guizhou, China. Sci China 25(11):1219–1225Google Scholar
  51. Wang T-G, Zhong N-N, Hou D-J, Huang G-H et al (1995b) On bacterial role in hydrocarbon generation mechanism, banqiao sag. Sci China 9:1123–1134.  https://doi.org/10.1007/bf01151314 Google Scholar
  52. Yang H-B, Chen L, Kong Y-H (2004) A novel classification of structural units in Junggar Basin. XinJiang Petrol Geol 25(6):686–688.  https://doi.org/10.3969/j.issn.1001-3873.2004.06.034 Google Scholar
  53. Zhang Z-R, Xiaoying S, Qu Z (2008) GC-MS quantitative analysis of biomarkers. Petrol Geol Exp 30(4):405–407.  https://doi.org/10.11781/sysydz200804405 Google Scholar
  54. Zhu C-S (2012) Instrumental analysis teaching guidance materials, Yangtze University, Wuhan, pp 49–51 (in Chinese)Google Scholar

Copyright information

© Science Press and Institute of Geochemistry, CAS and Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.College of Resources and EnvironmentYangtze UniversityWuhanChina
  2. 2.Key Laboratory of Exploration Technology for Oil & Gas Research (Yangtze University)Ministry of EducationWuhanChina

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