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Development of solid polymer electrolytes based on sodium-carboxymethylcellulose (NaCMC)-polysulphide for quantum dot-sensitized solar cells (QDSSCs)

  • N. N. S. Baharun
  • M. A. Mingsukang
  • M. H. BuraidahEmail author
  • H. J. Woo
  • L. P. Teo
  • A. K. Arof
Original Paper
  • 37 Downloads

Abstract

Sodium-carboxymethylcellulose (NaCMC) films have been developed by solution casting technique. The films were soaked into an optimized aqueous polysulphide electrolyte containing 4 M sodium sulphide (Na2S) and 1 M sulphur (S). The optimized aqueous polysulphide electrolyte has the ambient conductivity of (1.46 ± 0.02) × 10-1 S cm-1. The NaCMC films were soaked for different durations of 30, 60, 68 and 75 s. The highest room temperature ionic conductivity (RTIC) of (2.79 ± 0.09) × 10-5 S cm-1 is exhibited by NaCMC film soaked in polysulphide electrolyte for 68 s. The conductivity-temperature relationship of NaCMC-based polysulphide solid polymer electrolytes (SPEs) follows the Arrhenius rule. The highest conducting SPE exhibits the lowest activation energy (EA) value of 0.38 eV. Ionic coefficient of diffusion (D), ionic mobility (μ) and free ions concentration (n) of the SPEs were determined. The newly developed SPEs are used as electrolyte in quantum dot-sensitized solar cells (QDSSCs) application with the configuration FTO/TiO2/CdS/ZnS/SPE/Pt/FTO. Under 1000 W m-2 illumination, QDSSC with CMC-68 SPE exhibits the highest power conversion efficiency (PCE) of 0.90%. The values of short circuit current (JSC) and PCE are closely related to electron lifetime and recombination rate.

Keywords

Sodium-carboxymethylcellulose Solid polymer electrolyte Polysulphide Transport properties Quantum dot-sensitized solar cells 

Notes

Funding information

This study received financial support from the Malaysian Ministry of Higher Education in the form of Fundamental Research Grant Scheme (FRGS) under project No. FP053-2016, University of Malaya (RF020B-2018 and GPF045B-2018).

References

  1. 1.
    O'Regan B, Gratzel M (1991) A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature 353:737–740CrossRefGoogle Scholar
  2. 2.
    Bellaa F, Verna A, Gerbaldi C (2018) Patterning dye-sensitized solar cell photoanodes through a polymeric approach: a perspective. Mater Sci Semicond Proc 73:92–98CrossRefGoogle Scholar
  3. 3.
    Theerthagiri J, Senthil RA, Buraidah MH, Madhavan J, Arof AK, Ashokkumar M (2016) One-step electrochemical deposition of Ni1 − xMoxS ternary sulfides as an efficient counter electrode for dye-sensitized solar cells. J Mater Chem A 4:16119–16127CrossRefGoogle Scholar
  4. 4.
    Theerthagiri J, Senthil RA, Arunachalam P, Madhavan J, Buraidah MH, Santhanam A, Arof AK (2017) Synthesis of various carbon incorporated flower-like MoS2 microspheres as counter electrode for dye-sensitized solar cells. J Solid State Electrochem 21:581–590CrossRefGoogle Scholar
  5. 5.
    Theerthagiri J, Senthil RA, Arunachalam P, Amarsingh Bhabu K, Selvi A, Madhavan J, Murugan K, Arof AK (2017) Electrochemical deposition of carbon materials incorporated nickel sulfide composite as counter electrode for dye-sensitized solar cells. Ionics 23:1017–1025CrossRefGoogle Scholar
  6. 6.
    Kakiage K, Aoyama Y, Yano T, Oya K, Fujisawa, J.-i., and Hanaya, M. (2015) Highly-efficient dye-sensitized solar cells with collaborative sensitization by silyl-anchor and carboxy-anchor dyes. Chem Commun 51:15894–15897PubMedCrossRefPubMedCentralGoogle Scholar
  7. 7.
    Chaurasia S, Lin JT (2016) Metal-free sensitizers for dye-sensitized solar cells. Chem Rec 16:1311–1336PubMedCrossRefPubMedCentralGoogle Scholar
  8. 8.
    Carli S, Casarin L, Syrgiannis Z, Boaretto R, Benazzi E, Caramori S, Prato M, Bignozzi CA (2016) Single walled carbon nanohorns as catalytic counter electrodes for Co(III)/(II) electron mediators in dye sensitized cells. ACS Appl Mater Interfaces 8:14604–14612PubMedCrossRefPubMedCentralGoogle Scholar
  9. 9.
    Elbohy H, El-Mahalawy H, El-Ghamaz NA, Zidan H (2019) Hysteresis analysis in dye-sensitized solar cell based on different metal alkali cations in the electrolyte. Electrochim Acta 319:110–117CrossRefGoogle Scholar
  10. 10.
    Li CT, Lin RY, Lin JT (2017) Sensitizers for aqueous-based solar cells. Chem Asian J 12:486–496PubMedCrossRefPubMedCentralGoogle Scholar
  11. 11.
    Law C, Pathirana SC, Li X, Anderson AY, Barnes PRF, Listorti A, Ghaddar TH, O′Regan, B. C. (2010) Water-based electrolytes for dye-sensitized solar cells. Adv Mater 22:4505–4509PubMedCrossRefPubMedCentralGoogle Scholar
  12. 12.
    Bella F, Galliano S, Piana G, Giacona G, Viscardi G, Gratzel M, Barolo C, Gerbaldi C (2019) Boosting the efficiency of aqueous solar cells: a photoelectrochemical estimation on the effectiveness of TiCl4 treatment. Electrochim Acta 302:31–37CrossRefGoogle Scholar
  13. 13.
    Xu J, Chen Y, Dai L (2015) Efficiently photo-charging lithium-ion battery by perovskite solar cell. Nat Commun 6:8103PubMedPubMedCentralCrossRefGoogle Scholar
  14. 14.
    Zhang W, Liu P, Zhang X (2018) A solar rechargeable flow battery based on electroactive organic redox couples. IOP Conf Ser Mater Sci Eng 452:032068CrossRefGoogle Scholar
  15. 15.
    Liang J, Zhu G, Lu Z, Zhao P, Wang C, Ma Y, Xu Z, Wang Y, Hu Y, Ma L, Chen T, Tie Z, Liu J, Jin Z (2018) Integrated perovskite solar capacitors with high energy conversion efficiency and fast photo-charging rate. J Mater Chem A 6:2047–2052CrossRefGoogle Scholar
  16. 16.
    Liu R, Liu Y, Zou H, Song T, Sun B (2017) Integrated solar capacitors for energy conversion and storage. Nano Res 10:1545–1559CrossRefGoogle Scholar
  17. 17.
    Scalia A, Bella F, Lamberti A, Gerbaldi C, Tresso E (2019) Innovative multipolymer electrolyte membrane designed by oxygen inhibited UV-crosslinking enables solid-state in plane integration of energy conversion and storage devices. Energy 166:789–795CrossRefGoogle Scholar
  18. 18.
    Pedico A, Lamberti A, Gigot A, Fontana M, Bella F, Rivolo P, Cocuzza M, Fabrizio Pirri C (2018) High-performing and stable wearable supercapacitor exploiting rGO aerogel decorated with copper and molybdenum sulfides on carbon fibers. ACS Appl Energy Mater 1:4440–4447CrossRefGoogle Scholar
  19. 19.
    Cai F, Yang F, Zhang Y, Ke C, Cheng C, Zhao Y, Yan G (2014) PbS sensitized TiO2 nanotube arrays with different sizes and filling degrees for enhancing photoelectrochemical properties. Phys Chem Chem Phys 16:23967–23974PubMedCrossRefGoogle Scholar
  20. 20.
    Chebrolu VT, Kim H-J (2019) Recent progress in quantum dot sensitized solar cells: an inclusive review of photoanode, sensitizer, electrolyte, and the counter electrode. J Mater Chem C 7:4911–4933CrossRefGoogle Scholar
  21. 21.
    Jun HK, Careem MA, Arof AK (2013) Quantum dot-sensitized solar cells—perspective and recent developments: a review of Cd chalcogenide quantum dots as sensitizers. Renew Sust Energ Rev 22:148–167CrossRefGoogle Scholar
  22. 22.
    Lee Y-L, Chang C-H (2008) Efficient polysulfide electrolyte for CdS quantum dot-sensitized solar cells. J Power Sources 185:584–588CrossRefGoogle Scholar
  23. 23.
    Mingsukang MA, Buraidah MH, Careem MA (2017) Development of gel polymer electrolytes for application in quantum dot-sensitized solar cells. Ionics 23:347–355CrossRefGoogle Scholar
  24. 24.
    Chen H-Y, Lin L, Yu X-Y, Qiu K-Q, Lü X-Y, Kuang D-B, Su C-Y (2013) Dextran based highly conductive hydrogel polysulfide electrolyte for efficient quasi-solid-state quantum dot-sensitized solar cells. Electrochim Acta 92:117–123CrossRefGoogle Scholar
  25. 25.
    Yeh M-H, Lee C-P, Chou C-Y, Lin L-Y, Wei H-Y, Chu C-W, Vittal R, Ho K-C (2011) Conducting polymer-based counter electrode for a quantum-dot-sensitized solar cell (QDSSC) with a polysulfide electrolyte. Electrochim Acta 57:277–284CrossRefGoogle Scholar
  26. 26.
    Yu J, Wang W, Pan Z, Du J, Ren Z, Xue W, Zhong X (2017) Quantum dot sensitized solar cells with efficiency over 12% based on tetraethyl orthosilicate additive in polysulfide electrolyte. J Mater Chem A 5:14124–14133CrossRefGoogle Scholar
  27. 27.
    Zhang L, Pan Z, Wang W, Du J, Ren Z, Shen Q, Zhong X (2017) Copper deficient Zn–Cu–In–Se quantum dot sensitized solar cells for high efficiency. J Mater Chem A 5:21442–21451CrossRefGoogle Scholar
  28. 28.
    Duan J, Tang Q, He B, Chen H (2015) All-solid-state quantum dot-sensitized solar cell from plastic crystal electrolyte. RSC Adv 5:33463–33467CrossRefGoogle Scholar
  29. 29.
    Duan J, Tang Q, Sun Y, He B, Chen H (2014) Solid-state electrolytes from polysulfide integrated polyvinylpyrrolidone for quantum dot-sensitized solar cells. RSC Adv 4:60478–60483CrossRefGoogle Scholar
  30. 30.
    Selvakumar K, Kalaiselvimary J, Rajendran S, Prabhu MR (2016) Novel proton-conducting polymer electrolytes based on poly(vinylidene fluoride-co-hexafluoropropylene)–ammonium thiocyanate. Polym-Plast Technol Eng 55:1940–1948CrossRefGoogle Scholar
  31. 31.
    Sikkanthar S, Karthikeyan S, Selvasekarapandian S, Arunkumar D, Nithya H, Junichi K (2016) Structural, electrical conductivity, and transport analysis of PAN–NH4Cl polymer electrolyte system. Ionics 22:1085–1094CrossRefGoogle Scholar
  32. 32.
    Nithya S, Selvasekarapandian S, Karthikeyan S, Inbavalli D, Sikkinthar S, Sanjeeviraja C (2014) AC impedance studies on proton-conducting PAN : NH4SCN polymer electrolytes. Ionics 20:1391–1398CrossRefGoogle Scholar
  33. 33.
    Deraman SK, Mohamed NS, Subban RHY (2014) Ionic liquid incorporated pvc based polymer electrolytes: electrical and dielectric properties. Sains Malays 43:877–883Google Scholar
  34. 34.
    Theerthagiri J, Senthil RA, Buraidah MH, Madhavan J, Arof AK (2015) Effect of tetrabutylammonium iodide content on PVDF-PMMA polymer blend electrolytes for dye-sensitized solar cells. Ionics 21:2889–2896CrossRefGoogle Scholar
  35. 35.
    Theerthagiri J, Senthil RA, Buraidah MH, Madhavan J, Mohd Arof AK (2015) Studies of solvent effect on the conductivity of 2-mercaptopyridine-doped solid polymer blend electrolytes and its application in dye-sensitized solar cells. J Appl Polym Sci 132:42489CrossRefGoogle Scholar
  36. 36.
    Samsudin AS, Lai HM, Isa MIN (2014) Biopolymer materials based carboxymethyl cellulose as a proton conducting biopolymer electrolyte for application in rechargeable proton battery. Electrochim Acta 129:1–13CrossRefGoogle Scholar
  37. 37.
    Grumezescu AM, Andronescu E, Ficai A, Bleotu C, Mihaiescu DE, Chifiriuc MC (2012) Synthesis, characterization and in vitro assessment of the magnetic chitosan–carboxymethylcellulose biocomposite interactions with the prokaryotic and eukaryotic cells. Int J Pharm 436:771–777PubMedCrossRefGoogle Scholar
  38. 38.
    Pawlicka A, Donoso JP (2010) Polymer electrolytes based on natural polymers. In: Sequeira C, Santos D (eds) Polymer electrolytes. Woodhead Publishing, Portugal, pp 95–128CrossRefGoogle Scholar
  39. 39.
    Haleem N, Arshad M, Shahid M, Tahir MA (2014) Synthesis of carboxymethyl cellulose from waste of cotton ginning industry. Carbohydr Polym 113:249–255PubMedCrossRefGoogle Scholar
  40. 40.
    Heinze T, Koschella A (2005) Carboxymethyl ethers of cellulose and starch—a review. Macromol Symp 223:13–40CrossRefGoogle Scholar
  41. 41.
    Feng W, Zhao L, Du J, Li Y, Zhong X (2016) Quasi-solid-state quantum dot sensitized solar cells with power conversion efficiency over 9% and high stability. J Mater Chem A 4:14849–14856CrossRefGoogle Scholar
  42. 42.
    Hashem M, Sharaf S, Abd El-Hady MM, Hebeish A (2013) Synthesis and characterization of novel carboxymethylcellulose hydrogels and carboxymethylcellulolse-hydrogel-ZnO-nanocomposites. Carbohydr Polym 95:421–427PubMedPubMedCentralCrossRefGoogle Scholar
  43. 43.
    Ramlli MA, Isa MIN (2015) Solid biopolymer electrolytes based carboxymethyl cellulose doped with ammonium fluoride: ionic transport and conduction mechanism. Polym Renew Resour 6:55–63Google Scholar
  44. 44.
    Bella F, Galliano S, Falco M, Viscardi G, Barolo C, Grätzel M, Gerbaldi C (2017) Approaching truly sustainable solar cells by the use of water and cellulose derivatives. Green Chem 19:1043–1051CrossRefGoogle Scholar
  45. 45.
    Bella F, Nair JR, Gerbaldi C (2013) Towards green, efficient and durable quasi-solid dye-sensitized solar cells integrated with a cellulose-based gel-polymer electrolyte optimized by a chemometric DoE approach. RSC Adv 3:15993–16001CrossRefGoogle Scholar
  46. 46.
    Yu ZX, Zhang QX, Qin D, Luo YH, Li DM, Shen Q, Toyoda T, Meng QB (2010) Highly efficient quasi-solid-state quantum-dot-sensitized solar cell based on hydrogel electrolytes. Electrochem Commun 12:1776–1779CrossRefGoogle Scholar
  47. 47.
    Wang S, Zhang Q-X, Xu Y-Z, Li D-M, Luo Y-H, Meng Q-B (2013) Single-step in-situ preparation of thin film electrolyte for quasi-solid state quantum dot-sensitized solar cells. J Power Sources 224:152–157CrossRefGoogle Scholar
  48. 48.
    Selvalakshmi S, Vijaya N, Selvasekarapandian S, Premalatha M (2017) Biopolymer agar-agar doped with NH4SCN as solid polymer electrolyte for electrochemical cell application. J Appl Polym Sci 134:44702CrossRefGoogle Scholar
  49. 49.
    Samsudin AS, Isa MIN (2013) Conductivity and transport properties study of plasticized carboxymethyl cellulose (CMC) based solid biopolymer electrolytes (SBE). Adv Mater Res 856:118–122CrossRefGoogle Scholar
  50. 50.
    Tripathi S, Gupta A, Kumari M (2012) Studies on electrical conductivity and dielectric behaviour of PVdF–HFP–PMMA–NaI polymer blend electrolyte. Bull Mater Sci 35:969–975CrossRefGoogle Scholar
  51. 51.
    Pan Z, Zhong X (2016) A ZnS and metal hydroxide composite passivation layer for recombination control in high efficiency quantum dot sensitized solar cells. J Mater Chem A 4:18976–18982CrossRefGoogle Scholar
  52. 52.
    Jun H, Careem M, Arof A (2014) Efficiency improvement of CdS and CdSe quantum dot-sensitized solar cells by TiO2 surface treatment. J Renew Sustain Energy 6:023107CrossRefGoogle Scholar
  53. 53.
    Guijarro N, Campina JM, Shen Q, Toyoda T, Lana-Villarreal T, Gomez R (2011) Uncovering the role of the ZnS treatment in the performance of quantum dot sensitized solar cells. Phys Chem Chem Phys 13:12024–12032PubMedCrossRefPubMedCentralGoogle Scholar
  54. 54.
    Lue S, Lo P, Huang F, Cheng K, Tung Y (2015) Correlation between dye-sensitized solar cell performance and internal resistance using electrochemical impedance spectroscopy. J Phys Chem Biophys 5:1Google Scholar
  55. 55.
    Buraidah MH, Teo LP, Majid SR, Arof AK (2009) Ionic conductivity by correlated barrier hopping in NH4I doped chitosan solid electrolyte. Physica B 404:1373–1379CrossRefGoogle Scholar
  56. 56.
    Dahlan NA, Pushpamalar J, Veeramachineni AK, Muniyandy S (2018) Smart hydrogel of carboxymethyl cellulose grafted carboxymethyl polyvinyl alcohol and properties studied for future material applications. J Polym Environ 26:2061–2071CrossRefGoogle Scholar
  57. 57.
    Kristály F (2013) Implications of cellulose in modeling the behavior of vegetal additive materials in clay based ceramics: technical and archaeological issues. In: Cellulose-Fundamental Aspects. IntechOpenGoogle Scholar
  58. 58.
    Doh SJ, Lee JY, Lim DY, Im JN (2014) Manufacturing and analyses of wet-laid nonwoven consisting of carboxymethyl cellulose fibers. Fiber Polym 14:2176–2184CrossRefGoogle Scholar
  59. 59.
    Preisinger A, Mereiter K, Baumgartner O, Heger G, Mikenda W, Steidl H (1982) Hydrogen bonds in Na2S·9D2O: Neutron diffraction, X-ray diffraction and vibrational spectroscopic studies. Inorg Chim Acta 57:237–246CrossRefGoogle Scholar
  60. 60.
    Monisha S, Mathavan T, Selvasekarapandian S, Benial AMF, Aristatil G, Mani N, Premalatha M, Pandi DV (2017) Investigation of bio polymer electrolyte based on cellulose acetate-ammonium nitrate for potential use in electrochemical devices. Carbohydr Polym 157:38–47PubMedCrossRefPubMedCentralGoogle Scholar
  61. 61.
    Salleh NS, Aziz SB, Aspanut Z, Kadir MFZ (2016) Electrical impedance and conduction mechanism analysis of biopolymer electrolytes based on methyl cellulose doped with ammonium iodide. Ionics 22:2157–2167CrossRefGoogle Scholar
  62. 62.
    Luna-Martinez JF, Hernandez-Uresti DB, Reyes-Melo ME, Guerrero-Salazar CA, Gonzalez-Gonzalez VA, Sepulveda-Guzman S (2011) Synthesis and optical characterization of ZnS-sodium carboxymethyl cellulose nanocomposite films. Carbohydr Polym 84:566–570CrossRefGoogle Scholar
  63. 63.
    Arof AK, Amirudin S, Yusof SZ, Noor IM (2014) A method based on impedance spectroscopy to determine transport properties of polymer electrolytes. Phys Chem Chem Phys 16:1856–1867PubMedCrossRefPubMedCentralGoogle Scholar
  64. 64.
    Aziz SB, Woo TJ, Kadir MFZ, Ahmed HM (2018) A conceptual review on polymer electrolytes and ion transport models. J Sci Adv Mater Devices 3:1–17CrossRefGoogle Scholar
  65. 65.
    Yap KS, Teo LP, Sim LN, Majid SR, Arof AK (2012) Investigation on dielectric relaxation of PMMA-grafted natural rubber incorporated with LiCF3SO3. Physica B 407:2421–2428CrossRefGoogle Scholar
  66. 66.
    Aziz SB (2013) Li+ ion conduction mechanism in poly (ε-caprolactone)-based polymer electrolyte. Iran Polym J 22:877–883CrossRefGoogle Scholar
  67. 67.
    Hamsan MH, Shukur MF, Kadir MFZ (2016) The effect of NH4NO3 towards the conductivity enhancement and electrical behavior in methyl cellulose-starch blend based ionic conductors. Ionics 23:1137–1154CrossRefGoogle Scholar
  68. 68.
    Woo HJ, Majid SR, Arof AK (2012) Dielectric properties and morphology of polymer electrolyte based on poly(ɛ-caprolactone) and ammonium thiocyanate. Mater Chem Phys 134:755–761CrossRefGoogle Scholar
  69. 69.
    Shukur MF, Ithnin R, Kadir MFZ (2016) Ionic conductivity and dielectric properties of potato starch-magnesium acetate biopolymer electrolytes: the effect of glycerol and 1-butyl-3-methylimidazolium chloride. Ionics 22:1113–1123CrossRefGoogle Scholar
  70. 70.
    Arya A, Sharma AL (2018) Effect of salt concentration on dielectric properties of Li-ion conducting blend polymer electrolytes. J Mater Sci Mater Electron 29:17903–17920CrossRefGoogle Scholar
  71. 71.
    Bandara TMWJ, Mellander B-E (2011) Evaluation of mobility, diffusion coefficient and density of charge carriers in ionic liquids and novel electrolytes based on a new model for dielectric response. In: Ionic liquids: theory, properties, new approaches. InTechGoogle Scholar
  72. 72.
    Tripathi M, Tripathi SK (2017) Electrical studies on ionic liquid-based gel polymer electrolyte for its application in EDLCs. Ionics 23:2735–2746CrossRefGoogle Scholar
  73. 73.
    Feng WL, Li Y, Du J, Wang W, Zhong XH (2016) Highly efficient and stable quasi-solid-state quantum dot-sensitized solar cells based on a superabsorbent polyelectrolyte. J Mater Chem A 4:1461–1468CrossRefGoogle Scholar
  74. 74.
    Yang S, Kou H, Wang H, Cheng K, Wang J (2010) Efficient electrolyte of N,N′-bis(salicylidene)ethylenediamine zinc(ii) iodide in dye-sensitized solar cells. New J Chem 34:313–317CrossRefGoogle Scholar
  75. 75.
    Liberatore M, Decker F, Burtone L, Zardetto V, Brown TM, Reale A, Di Carlo A (2009) Using EIS for diagnosis of dye-sensitized solar cells performance. J Appl Electrochem 39:2291CrossRefGoogle Scholar
  76. 76.
    Kamarudin MA, Khan AA, Tan E, Rughoobur G, Said SM, Qasim MM, Wilkinson TD (2017) Induced alignment of a reactive mesogen-based polymer electrolyte for dye-sensitised solar cells. RSC Adv 7:31989–31996CrossRefGoogle Scholar
  77. 77.
    Gopi CVVM, Venkata-Haritha M, Seo H, Singh S, Kim S-K, Shiratani M, Kim H-J (2016) Improving the performance of quantum dot sensitized solar cells through CdNiS quantum dots with reduced recombination and enhanced electron lifetime. Dalton Trans 45:8447–8457PubMedCrossRefGoogle Scholar
  78. 78.
    Salvador GP, Pugliese D, Bella F, Chiappone A, Sacco A, Bianco S, Quaglio M (2014) New insights in long-term photovoltaic performance characterization of cellulose-based gel electrolytes for stable dye-sensitized solar cells. Electrochim Acta 146:44–51CrossRefGoogle Scholar
  79. 79.
    Tao L, Huo Z, Ding Y, Li Y, Dai S, Wang L, Zhu J, Pan X, Zhang B, Yao J, Nazeeruddin MK, Grätzel M (2015) High-efficiency and stable quasi-solid-state dye-sensitized solar cell based on low molecular mass organogelator electrolyte. J Mater Chem A 3:2344–2352CrossRefGoogle Scholar
  80. 80.
    Pavithra N, Asiri AM, Anandan S (2015) Fabrication of dye sensitized solar cell using gel polymer electrolytes consisting poly(ethylene oxide)-acetamide composite. J Power Sources 286:346–353CrossRefGoogle Scholar
  81. 81.
    Lee Y-S, Gopi CVVM, Venkata-Haritha M, Kim H-J (2016) Recombination control in high-performance quantum dot-sensitized solar cells with a novel TiO2/ZnS/CdS/ZnS heterostructure. Dalton Trans 45:12914–12923PubMedCrossRefGoogle Scholar
  82. 82.
    Han L, Wang YF, Zeng JH (2014) Effective solid electrolyte based on benzothiazolium for dye-sensitized solar cells. ACS Appl Mater Interfaces 6:22088–22095PubMedCrossRefGoogle Scholar
  83. 83.
    Yang Y, Wang W (2015) A new polymer electrolyte for solid-state quantum dot sensitized solar cells. J Power Sources 285:70–75CrossRefGoogle Scholar
  84. 84.
    Kang M-S, Ahn K-S, Lee J-W (2008) Quasi-solid-state dye-sensitized solar cells employing ternary component polymer-gel electrolytes. J Power Sources 180:896–901CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • N. N. S. Baharun
    • 1
  • M. A. Mingsukang
    • 1
  • M. H. Buraidah
    • 1
    Email author
  • H. J. Woo
    • 1
  • L. P. Teo
    • 1
  • A. K. Arof
    • 1
  1. 1.Centre for Ionics University of Malaya, Department of Physics, Faculty of ScienceUniversity of MalayaKuala LumpurMalaysia

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