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Enhanced electrochemical performance of Li1.2Mn0.54Ni0.13Co0.13O2 cathode material with bamboo essential oil

  • Changkun Song
  • Wangjun FengEmail author
  • Xuan Wang
  • Zhaojiao Shi
Original Paper


The lithium-rich manganese-based material Li1.2Mn0.54Ni0.13Co0.13O2 is one of the most promising cathode materials for next-generation lithium–ion batteries. However, this material has serious problems of capacity reduction and poor rate performance. The electrochemical properties of the material are improved after the addition of bamboo essential oil. Structural and elemental analysis showed that the addition of bamboo essential oil did not affect the crystal structure. The battery discharge cycle curve showed that the electrochemical performance was significantly improved after the addition, compared with the non-added bamboo essential oil. When the sample is added at a ratio of 30%, the best discharge specific capacity and cycle performance are exhibited, especially at high current density. The first discharge specific capacity at 0.1 C is as high as 291.5 mAh/g. After circulating 200 cycles at a magnification of 2 C, the capacity retention ratios were 80.96%.


Lithium-rich High capacity Electrochemical properties Sol–gel method Bamboo essential oil 


Funding information

This work was financially supported by the National Natural Science Foundation of China (Grant No.11264023) and the Natural Science Foundation of Gansu Province, China (Grant No.1210ZTC035), HongLiu First-class Disciplines Development Program of Lanzhou University of Technology.


  1. 1.
    Chen JJ, Li ZD, Xiang HF, Wu WW, Cheng S, Zhang LJ, Wang QS, Wu YC (2015) Enhanced electrochemical performance and thermal stability of a CePO 4 -coated Li1.2Ni0.13Co0.13 Mn0.54O2 cathode material for lithium-ion batteries. RSC Adv 5:3031–3038CrossRefGoogle Scholar
  2. 2.
    Liu H, Chen C, Du C et al (2015) Lithium-rich Li1.2Ni0.13Co0.13Mn0.54O2 oxide coated by Li3PO4 and carbon nanocomposite layers as high performance cathode materials for lithium ion batteries. J Mater Chem A 3:2634–2641CrossRefGoogle Scholar
  3. 3.
    Zhao J, Wang Z, Guo H, Li X, He Z, Li T (2015) Synthesis and electrochemical characterization of Zn-doped Li-rich layered Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode material. Ceram Int 41:11396–11401CrossRefGoogle Scholar
  4. 4.
    Zhang L, Jin K, Wang L, Zhang Y, Li X, Song Y (2015) High capacity Li1.2Mn0.54Ni0.13Co0.13O2 cathode materials synthesized using mesocrystal precursors for lithium-ion batteries. J Alloys Compd 638:298–304CrossRefGoogle Scholar
  5. 5.
    Li B, Yan H, Ma J, Yu P, Xia D, Huang W, Chu W, Wu Z (2014) Manipulating the electronic structure of Li-rich manganese-based oxide using polyanions: towards better electrochemical performance. Adv Funct Mater 24:5112–5118CrossRefGoogle Scholar
  6. 6.
    Li J, Jia T, Liu K, Zhao J, Chen J, Cao C (2016) Facile design and synthesis of Li-rich nanoplates cathodes with habit-tuned crystal for lithium ion batteries. J Power Sources 333:37–42CrossRefGoogle Scholar
  7. 7.
    Zhang L, Jiang J, Zhang C, Wu B, Wu F (2016) High-rate layered lithium-rich cathode nanomaterials for lithium-ion batteries synthesized with the assist of carbon spheres templates. J Power Sources 331:247–257CrossRefGoogle Scholar
  8. 8.
    Dai D, Li B, Tang H, Chang K, Jiang K, Chang Z, Yuan X (2016) Simultaneously improved capacity and initial coulombic efficiency of Li-rich cathode Li[Li0.2Mn0.54Co0.13Ni0.13]O2 by enlarging crystal cell from a nanoplate precursor. J Power Sources 307:665–672CrossRefGoogle Scholar
  9. 9.
    Shi SJ, Tu JP, Tang YY, Liu XY, Zhang YQ, Wang XL, Gu CD (2013) Enhanced cycling stability of Li[Li0.2Mn0.54Ni0.13Co0.13]O2 by surface modification of MgO with melting impregnation method. Electrochim Acta 88:671–679CrossRefGoogle Scholar
  10. 10.
    Wang F, Liu Y, Zhao YF et al (2018) Facile synthesis of two-dimensional porous MgCo2O4 nanosheets as anode for lithium-ion batteries. Appl Sci 8:22CrossRefGoogle Scholar
  11. 11.
    Wang JQ, Fu XY, Zhang LL, Ding XK, Liu J, Li T, Yang XL (2019) Enhanced electrochemical performance of graphene supported LiNi1/3Co1/3Mn1/3O2/C hybrid cathode for lithium-ion batteries. J Electrochem Soc 166:A1806–A1812CrossRefGoogle Scholar
  12. 12.
    Liu GL, Cui J, Luo RJ, Liu Y, Huang X, Wu N, Jin X, Chen H, Tang S, Kim JK, Liu X (2019) 2D MoS 2 grown on biomass-based hollow carbon fibers for energy storage. Appl Surf Sci 469:854–863CrossRefGoogle Scholar
  13. 13.
    Liu Y, Wang HC, Yang KK, Yang Y, Ma J, Pan K, Wang G, Ren F, Pang H (2019) Enhanced electrochemical performance of Sb2O3 as an anode for Lithium-ion batteries by a stable cross-linked binder. Appl Sci 9:2677CrossRefGoogle Scholar
  14. 14.
    Wang M, Luo M, Chen Y, Chen L, Yan S, Ren Y, Chu M (2017) A new approach to improve the electrochemical performance of Li-rich cathode material by precursor pretreatment. J Alloys Compd 696:891–899CrossRefGoogle Scholar
  15. 15.
    Kong J-Z, Zhai H-F, Qian X, Wang M, Wang QZ, Li AD, Li H, Zhou F (2017) Improved electrochemical performance of Li1.2Mn0.54Ni0.13Co0.13O2 cathode material coated with ultrathin ZnO. J Alloys Compd 694:848–856CrossRefGoogle Scholar
  16. 16.
    Tu W, Xing L, Xia P, Xu M, Liao Y, Li W (2016) Dimethylacetamide as a film-forming additive for improving the cyclic stability of high voltage lithium-rich cathode at room and elevated temperature. Electrochim Acta 204:192–198CrossRefGoogle Scholar
  17. 17.
    Xu H, Deng S, Chen G (2014) Improved electrochemical performance of Li1.2Mn0.54Ni0.13Co0.13O2 by Mg doping for lithium ion battery cathode material. J Mater Chem A 2:15015–15021CrossRefGoogle Scholar
  18. 18.
    Feng X, Yang Z, Tang D, Kong Q, Gu L, Wang Z, Chen L (2015) Performance improvement of Li-rich layer-structured Li1.2Mn0.54Ni0.13Co0.13O2 by integration with spinel LiNi0.5Mn1.5O4. Phys Chem Chem Phys 17:1257–1264CrossRefGoogle Scholar
  19. 19.
    Chen H, Hu Q, Huang Z, He Z, Wang Z, Guo H, Li X (2016) Synthesis and electrochemical study of Zr-doped Li[Li0.2Mn0.54Ni0.13Co0.13]O2 as cathode material for Li-ion battery. Ceram Int 42:263–269CrossRefGoogle Scholar
  20. 20.
    Li L, Song BH, Chang YL, Xia H, Yang JR, Lee KS, Lu L (2015) Retarded phase transition by fluorine doping in Li-rich layered Li1.2Mn0.54Ni0.13Co0.13O2 cathode material. J Power Sources 283:162–170CrossRefGoogle Scholar
  21. 21.
    Nayak PK, Grinblat J, Levi M, Levi E, Kim S, Choi JW, Aurbach D (2016) Al doping for mitigating the capacity fading and voltage decay of layered Li and Mn-rich cathodes for Li-ion batteries. Adv Energy Mater 6:1502398CrossRefGoogle Scholar
  22. 22.
    Liu X, Liu J, Huang T, Yu A (2013) CaF2-coated Li1.2Mn0.54Ni0.13Co0.13O2 as cathode materials for Li-ion batteries. Electrochim Acta 109:52–58CrossRefGoogle Scholar
  23. 23.
    Meng H, Li L, Liu J, Han X, Zhang W, Liu X, Xu Q (2017) Surface modification of Li-rich layered Li[Li0.17Ni0.17Co0.10Mn0.56]O2 oxide with LiV3O8 as a cathode material for Li-ion batteries. J Alloys Compd 690:256–266CrossRefGoogle Scholar
  24. 24.
    Wu F, Wang Z, Su Y, Yan N, Bao L, Chen S (2014) Li[Li0.2Mn0.54Ni0.13Co0.13]O2–MoO3 composite cathodes with low irreversible capacity loss for lithium ion batteries. J Power Sources 247:20–25CrossRefGoogle Scholar
  25. 25.
    Wang C, Zhou F, Chen K, Kong J, Jiang Y, Yan G, Li J, Yu C, Tang WP (2015) Electrochemical properties of α-MoO3-coated Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode material for Li-ion batteries. Electrochim Acta 176:1171–1181CrossRefGoogle Scholar
  26. 26.
    Chen D, Zheng F, Li L, Chen M, Zhong X, Li W, Lu L (2017) Effect of Li3PO4 coating of layered lithium-rich oxide on electrochemical performance. J Power Sources 341:147–155CrossRefGoogle Scholar
  27. 27.
    Lee Y, Lee J, Lee KY, Mun J, Lee JK, Choi W (2016) Facile formation of a Li3PO4 coating layer during the synthesis of a lithium-rich layered oxide for high-capacity lithium-ion batteries. J Power Sources 315:284–293CrossRefGoogle Scholar
  28. 28.
    Wang J, Yuan G, Zhang M, Qiu B, Xia Y, Liu Z (2012) The structure, morphology, and electrochemical properties of Li1+xNi1/6Co1/6Mn4/6O2.25+x/2 (0.1≤x≤0.7) cathode materials. Electrochim Acta 66:61–66CrossRefGoogle Scholar
  29. 29.
    Li J, Klöpsch R, Stan MC, Nowak S, Kunze M, Winter M, Passerini S (2011) Synthesis and electrochemical performance of the high voltage cathode material Li[Li0.2Mn0.56Ni0.16Co0.08]O2 with improved rate capability. J Power Sources 196:4821–4825CrossRefGoogle Scholar
  30. 30.
    Tang T, Zhang H-L (2016) Synthesis and electrochemical performance of lithium-rich cathode material Li[Li0.2Ni0.15Mn0.55Co0.1-xAlx]O2. Electrochim Acta 191:263–269CrossRefGoogle Scholar
  31. 31.
    Jiao LF, Zhang M, Yuan HT, Zhao M, Guo J, Wang W, Zhou XD, Wang YM (2007) Effect of Cr doping on the structural, electrochemical properties of Li[Li0.2Ni0.2−x/2Mn0.6−x/2Crx]O2 (x=0, 0.02, 0.04, 0.06, 0.08) as cathode materials for lithium secondary batteries. J Power Sources 167:178–184CrossRefGoogle Scholar
  32. 32.
    Xiang Y, Sun Z, Li J, Wu X, Liu Z, Xiong L, He Z, Long B, Yang C, Yin Z (2017) Improved electrochemical performance of Li1.2Ni0.2Mn0.6O2 cathode material for lithium ion batteries synthesized by the polyvinyl alcohol assisted sol-gel method. Ceram Int 43:2320–2324CrossRefGoogle Scholar
  33. 33.
    Yi T-F, Tao W, Chen B, Zhu YR, Yang SY, Xie Y (2016) High-performance xLi2MnO3·(1-x)LiMn1/3Co1/3Ni1/3O2 (0.1≤x≤0.5) as cathode material for lithium-ion battery. Electrochim Acta 188:686–695CrossRefGoogle Scholar
  34. 34.
    Li L, Xu M, Chen Z, Zhou X, Zhang Q, Zhu H, Wu C, Zhang K (2015) High-performance lithium-rich layered oxide materials: effects of chelating agents on microstructure and electrochemical properties. Electrochim Acta 174:446–455CrossRefGoogle Scholar
  35. 35.
    Zhang X, Yu C, Huang X, Zheng J, Guan X, Luo D, Li L (2012) Novel composites Li[LixNi0.34−xMn0.47Co0.19]O2 (0.18≤x≤0.21): synthesis and application as high-voltage cathode with improved electrochemical performance for lithium ion batteries. Electrochim Acta 81:233–238CrossRefGoogle Scholar
  36. 36.
    Kong J-Z, Wang C-L, Qian X, Tai GA, Li AD, Wu D, Li H, Zhou F, Yu C, Sun Y, Jia D, Tang WP (2015) Enhanced electrochemical performance of Li1.2Mn0.54Ni0.13Co0.13O2 by surface modification with graphene-like lithium-active MoS2. Electrochim Acta 174:542–550CrossRefGoogle Scholar
  37. 37.
    Xue Q, Li J, Xu G, Zhou H, Wang X, Kang F (2014) In situ polyaniline modified cathode material Li[Li0.2Mn0.54Ni0.13Co0.13]O2 with high rate capacity for lithium ion batteries. J Mater Chem A 2:18613–18623CrossRefGoogle Scholar
  38. 38.
    Fan J, Li G, Luo D, Fu C, Li Q, Zheng J, Li L (2015) Hydrothermal-assisted synthesis of Li-rich layered oxide microspheres with high capacity and superior rate-capability as a cathode for lithium-ion batteries. Electrochim Acta 173:7–16CrossRefGoogle Scholar
  39. 39.
    Lu C, Yang SQ, Wu H, Zhang Y, Yang X, Liang T (2016) Enhanced electrochemical performance of Li-rich Li1.2Mn0.52Co0.08Ni0.2O2 cathode materials for Li-ion batteries by vanadium doping. Electrochim Acta 209:448–455CrossRefGoogle Scholar
  40. 40.
    Shin S-S, Sun Y-K, Amine K (2002) Synthesis and electrochemical properties of Li[Li(1−2x)/3NixMn(2−x)/3]O2 as cathode materials for lithium secondary batteries. J Power Sources 112:634–638CrossRefGoogle Scholar
  41. 41.
    Johnson CS, Li N, Lefief C, Vaughey JT, Thackeray MM (2008) Synthesis, characterization and electrochemistry of lithium battery electrodes: xLi2MnO3·(1−x)LiMn0.333Ni0.333Co0.333O2 (0≤x≤0.7). Chem Mater 20:6095–6106CrossRefGoogle Scholar
  42. 42.
    Liu Y, Ning D, Zheng L, Zhang Q, Gu L, Gao R, Zhang J, Franz A, Schumacher G, Liu X (2018) Improving the electrochemical performances of Li-rich Li1.20Ni0.13Co0.13Mn0.54O2 through a cooperative doping of Na+ and PO4 3− with Na3PO4. J Power Sources 375:1–10CrossRefGoogle Scholar
  43. 43.
    Wang YX, Shang KH, He W, Ai XP, Cao YL, Yang HX (2015) Magnesium-doped Li1.2[Co0.13Ni0.13Mn0.54]O2 for lithium-ion battery cathode with enhanced cycling stability and rate capability. ACS Appl Mater Interfaces 7:13014–13021CrossRefGoogle Scholar
  44. 44.
    Prakasha KR, Prakash AS (2015) A time and energy conserving solution combustion synthesis of nano Li1.2Ni0.13Mn0.54Co0.13O2 cathode material and its performance in Li-ion batteries. RSC Adv 5:94411–94417CrossRefGoogle Scholar
  45. 45.
    Cao Y, Feng WJ, Su WX (2018) Biosynthesis and characterization of LiFePO4/C composite using Baker’s yeast. Int J Electrochem Sci 13:8022–8029CrossRefGoogle Scholar
  46. 46.
    Li L, Song BH, Chang YL et al (2015) Retarded phase transition by fluorine doping in Li-rich layered Li1.2Mn0.54Ni0.13Co0.13O2 cathode material. J PowerSources 283:162–170Google Scholar
  47. 47.
    Yang H, Wu H, Ge M et al (2019) Simultaneously dual modification of Ni-rich layered oxide cathode for high-energy lithium-ion batteries. Adv Funct Mater 29:1808825CrossRefGoogle Scholar
  48. 48.
    Li XC, Zheng LL, Zang Z, Liu T, Cao F, Sun X, Sun S, Niu Q, Lu Y, Ohsaka T, Wu J (2018) Multiply depolarized composite cathode of Li1.2Mn0.54Ni0.13Co0.13O2 embedded in a combinatory conductive network for lithium-ion battery with superior overall performances. J Alloys Compd 744:41–50CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Changkun Song
    • 1
  • Wangjun Feng
    • 1
    • 2
    Email author
  • Xuan Wang
    • 1
    • 2
  • Zhaojiao Shi
    • 1
  1. 1.School of ScienceLanzhou University of TechnologyLanzhouChina
  2. 2.State Key Laboratory of Advanced Processing and Recycling Nonferrous MetalsLanzhou University of TechnologyLanzhouChina

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