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Ionics

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Synthetic, spectroscopic characterization, empirical and theoretical investigations on the corrosion inhibition characteristics of mild steel in molar hydrochloric acid by three novel 8-hydroxyquinoline derivatives

  • M. Rbaa
  • M. Galai
  • Ashraf S. Abousalem
  • B. Lakhrissi
  • M. Ebn Touhami
  • I. Warad
  • Abdelkader ZarroukEmail author
Original Paper
  • 13 Downloads

Abstract

The newly synthesized quinoline derivatives were characterized using FTIR, NMR, and elemental analysis, and then they were evaluated as inhibitors against corrosion of mild steel (MS) in 1.0 M HCl. The corrosion testing and evaluation were performed thoroughly employing the weight loss method, electrochemical measurements, and surface analysis. We have demonstrated also that the 8-hydroxyquinoline derivatives react as mixed-type inhibitors. Experimental data show that the three inhibitors are effective against corrosion of steel in 1.0 M HCl and that the inhibitory efficiency reached at an optimum value of 96% for the Q-CH3 compound. In addition, the surface of the MS has been analyzed by SEM-EDS and the dissolution of steel in the gravimetric solution was analyzed by UV-visible spectrometry (UV-vis). The DFT calculations and Monte Carlo (MC) simulations were performed to understand the mechanism of inhibition of compounds with steel.

Keywords

Organic synthesis Electrochemical techniques Surface morphology study UV-visible spectrometry Monte Carlo simulations 

Notes

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • M. Rbaa
    • 1
  • M. Galai
    • 2
  • Ashraf S. Abousalem
    • 3
    • 4
  • B. Lakhrissi
    • 1
  • M. Ebn Touhami
    • 2
  • I. Warad
    • 5
    • 6
  • Abdelkader Zarrouk
    • 7
    Email author
  1. 1.Laboratory of Agro-Resources, Polymers and Process Engineering, Department of Chemistry, Faculty of ScienceIbn Tofail UniversityKenitraMorocco
  2. 2.Laboratory of Materials Engineering and Environment: Modeling and Application, Faculty of ScienceIbn Tofail UniversityKenitraMorocco
  3. 3.Department of Chemistry, Faculty of ScienceMansoura UniversityMansouraEgypt
  4. 4.Quality Control Laboratory, Operations DepartmentJOTUNCairoEgypt
  5. 5.Department of Chemistry, Science CollegeAn-Najah National UniversityNablusPalestine
  6. 6.Department of Chemistry and Earth SciencesQatar UniversityDohaQatar
  7. 7.Laboratory of Materials, Nanotechnology and Environment, Faculty of SciencesMohammed V UniversityRabatMorocco

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