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Ionics

pp 1–11 | Cite as

Synthesis and physical properties of new low-viscosity sulfonium ionic liquids

  • Zheng Yue
  • Hamza Dunya
  • Xinyi Mei
  • Christopher McGarry
  • Braja K. MandalEmail author
Original Paper
  • 30 Downloads

Abstract

Several new sulfonium ionic liquids (ILs) with dicyanamide ([DCA]) and bis(trifluoromethylsulfonyl)imide ([TFSI]) counter anions have been synthesized. Their viscosity and ionic conductivity values were determined. The ILs with [DCA] were previously prepared by the metathesis reaction involving silver dicyanamide (AgDCA). We report here a very convenient and much less expensive method using an ion-exchange resin. The structures of these ILs have been confirmed by 1H-NMR, 13C-NMR, and elemental analysis. Some of these sulfonium ILs displayed low viscosity (< 30 cP) and high ionic conductivity (> 10 mS cm−1). A concluding remark on structure-property relationship has also been drawn involving alicyclic and cyclic sulfonium cations vs. [DCA] and [TFSI] anions.

Keywords

Ionic liquids Ion-exchange resins Sulfonium cation TFSI anion DCA anion Li-ion battery electrolytes 

Notes

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Zheng Yue
    • 1
  • Hamza Dunya
    • 1
  • Xinyi Mei
    • 2
  • Christopher McGarry
    • 1
  • Braja K. Mandal
    • 1
    Email author
  1. 1.Department of ChemistryIllinois Institute of TechnologyChicagoUSA
  2. 2.National Academy of Economic SecurityBeijing Jiaotong UniversityBeijingChina

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