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Ionics

, Volume 25, Issue 9, pp 4075–4082 | Cite as

Nano-scale hollow structure carbon-coated LiFePO4 as cathode material for lithium ion battery

  • Junjie Lu
  • Wenlong Li
  • Chao Shen
  • Dongmei Tang
  • Lanxuan Dai
  • Guowang Diao
  • Ming ChenEmail author
Original Paper
  • 176 Downloads

Abstract

In this paper, carbon-coated LiFePO4 nano-hollow spheres (LFP@C HSs) were successfully synthesized using lithium phosphate (Li3PO4) nano-spheres as templates and precursors. The X-ray diffractometer (XRD) demonstrated the crystal structure of LFP@C HSs. The morphology of LFP@C HSs was determined by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Compared with LiFePO4 nano-hollow spheres without carbon coating (LFP HSs) and commercial LiFePO4 (commercial LFP), the rate performance of LFP@C HSs has been evidently improved by carbon coating and hollow structure. At the highest rate of 5 C, LFP@C HSs still maintains a capacity of 101.4 mA h−1 g−1. LFP@C HSs show excellent cycling performance at a current density of 1 C, maintaining 92.5% of the initial capacity after 500 cycles.

Keywords

Carbon-coated LiFePO4 Hollow spheres Rate performance Cathode material Lithium ion batteries 

Notes

Funding information

The funding support was from the National Natural Science Foundation of China (Grant No. 21773203), Natural Science Foundation of Jiangsu Province (BK20161329), and a Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Junjie Lu
    • 1
  • Wenlong Li
    • 1
  • Chao Shen
    • 1
  • Dongmei Tang
    • 1
  • Lanxuan Dai
    • 1
  • Guowang Diao
    • 1
  • Ming Chen
    • 1
    Email author
  1. 1.School of Chemistry and Chemical EngineeringYangzhou UniversityYangzhouPeople’s Republic of China

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