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Ionics

, Volume 25, Issue 7, pp 3021–3030 | Cite as

The effects of Cr substitution on LiNi0.65Co0.1Mn0.25O2 for lithium-ion batteries

  • Lamei Sun
  • Lingzhi ZhuEmail author
  • Chen Mi
  • Enshan Han
  • Mei Shang
  • Zhenzhen Zeng
Original Paper
  • 64 Downloads

Abstract

LiNi0.65-xCo0.1Mn0.25CrxO2 were synthesized via hydroxide co-precipitation method. The electrochemical test results show that compared with the pure phase material, the charge and discharge performance of the doped material at high current density is better. The initial discharge specific capacity of LiNi0.64Co0.1Mn0.25Cr0.01O2 is 210.1, 199.2, 167.1, and 122.7 mAh/g at 0.1C, 0.2C, 0.5C, and 1C, respectively, which is higher than other materials. The capacity retention rate is 93.56% after 10 cycles at 1C, showing good cycle performance and rate performance. The improved electrochemical energy source forms a stable main structure after the Cr enters LiNi0.65Co0.1Mn0.25O2.

Keywords

Co-precipitation LiNi0.65-xCo0.1Mn0.25CrxO2 High current density 

Notes

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Lamei Sun
    • 1
  • Lingzhi Zhu
    • 1
    Email author
  • Chen Mi
    • 1
  • Enshan Han
    • 1
  • Mei Shang
    • 1
  • Zhenzhen Zeng
    • 1
  1. 1.School of Chemical Engineering and TechnologyHebei University of TechnologyTianjinPeople’s Republic of China

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