, Volume 25, Issue 7, pp 3059–3068 | Cite as

Few-layers of graphene modified TiO2/graphene composites with excellent electrochemical properties for lithium-ion battery

  • Chun-Yan Geng
  • Jin YuEmail author
  • Fa-Nian Shi
Original Paper


In this work, a simple, facile, and effective hydrothermal method toward TiO2/graphene composite has been developed by using tetrabutyl titanate and different layers of graphene oxide (GO) as the starting materials, exploring the influence of the layers of graphene on the lithium-ion battery composites. The structure and morphology were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR). Their electrochemistry performances were tested through galvanostatic charge–discharge, cyclic voltammetry (CV), and AC impedance (EIS). When used as anode material for lithium-ion batteries (LIBs), the reduced graphene oxide (rGO) can effectively prevent the aggregation of TiO2 nanoparticles and increase the electrical conductivity of the composites. The electrochemical tests indicate that the TiO2/rGO (few-layer) electrode exhibits higher electrochemical performance than that of TiO2/rGO (multi-layers) electrode regardless of the rate. At the current density of 100 mA g−1, the discharge capacity of TiO2/rGO (few-layers) can maintain 344.3 mAh g−1 after 100 cycles, which is higher than that of TiO2/rGO (multi-layers) 244.9 mAh g−1. TiO2/rGO (few-layers) showed reversible capacity values of 303.9 mAh g−1 and 245.6 mAh g−1 at current rates of 160 mA g−1 and 320 mA g−1, respectively, showing better rate performance. Our study demonstrates significant potential of few-layer graphene as anode materials for LIBs.


Lithium-ion battery Anode material TiO2 Graphene Layers 



This research was supported by the National Natural Science Foundation of China (21571132).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.


  1. 1.
    Han Z, Wang B, Liu X, Wang G, Wang H, Bai J (2018) Peapod-like one-dimensional (1D) CoP hollow nanorods embedded into graphene networks as an anode material for lithium-ion batteries. J Mater Sci 53:8445–8459CrossRefGoogle Scholar
  2. 2.
    Chen Y, Li J, Yue G, Luo X (2017) Novel Ag@nitrogen-doped porous carbon composite with high electrochemical performance as anode materials for lithium-ion batteries. Nano-Micro Lett 9:32CrossRefGoogle Scholar
  3. 3.
    Lu J, Chen Z, Pan F, Cui Y, Amine K (2018) High-performance anode materials for rechargeable lithium-ion batteries. Electrochem Energy Rev 1:35–53CrossRefGoogle Scholar
  4. 4.
    Long B, Chen S, Wang B, Tang J, Yang J, Zhou X (2018) A facile synthesis of heteroatom-doped carbon framework anchored with TiO2 nanoparticles for high performance lithium ion battery anodes. J Nanopart Res 20:164CrossRefGoogle Scholar
  5. 5.
    Tang Y-P, Wang S-M, Tan X-X, Hou G-Y, Zheng G-Q (2014) TiO2/graphene nanocomposites as anode materials for high rate lithium-ion batteries. J Cent South Univ 21:1714–1718CrossRefGoogle Scholar
  6. 6.
    Zheng C, He C, Zhang H, Wang W, Lei X (2014) TiO2-reduced graphene oxide nanocomposite for high-rate application of lithium ion batteries. Ionics 21:51–58CrossRefGoogle Scholar
  7. 7.
    Jiao J, Qiu W, Tang J, Chen L, Jing L (2016) Synthesis of well-defined Fe3O4 nanorods/N-doped graphene for lithium-ion batteries. Nano Res 9:1256–1266CrossRefGoogle Scholar
  8. 8.
    Wu B, Gao W (2017) LiMn0.7Fe0.3PO4 nanorods grown on graphene sheets synthesized in situ by modified microwave-assisted solvothermal method as high-performance cathode materials. J Mater Sci 53:4433–4443CrossRefGoogle Scholar
  9. 9.
    Hu J, Diao H, Luo W, Song YF (2017) Dawson-type polyoxomolybdate anions (P2Mo18 O62 6-) captured by ionic liquid on graphene oxide as high-capacity anode material for lithium-ion batteries. Chemistry 23:8729–8735CrossRefGoogle Scholar
  10. 10.
    Zhai W, Ai Q, Chen L, Wei S, Li D, Zhang L, Si P, Feng J, Ci L (2017) Walnut-inspired microsized porous silicon/graphene core-shell composites for high-performance lithium-ion battery anodes. Nano Res 10:4274–4283CrossRefGoogle Scholar
  11. 11.
    Wang D, Choi D, Li J, Yang Z, Nie Z, Kou R, Hu D, Wang C, Saraf LV, Zhang J, Aksay IA, Liu J (2009) Self-assembled TiO2-graphene hybrid nanostructures for enhanced Li-ion insertion. ACS Nano 3:907–914CrossRefGoogle Scholar
  12. 12.
    Petnikota S, Rotte NK, Srikanth VVSS, Kota BSR, Reddy MV, Loh KP, Chowdari BVR (2013) Electrochemical studies of few-layered graphene as an anode material for Li ion batteries. J Solid State Electrochem 18:941–949CrossRefGoogle Scholar
  13. 13.
    Lian X, Cai M, Qin L, Cao Y, Wu Q-H (2016) Synthesis of hierarchical nanospheres Fe2O3/graphene composite and its application in lithium-ion battery as a high-performance anode material. Ionics 22:2015–2020CrossRefGoogle Scholar
  14. 14.
    Yang X, Liu L, Yuan R, Lee C-S (2016) Self-assembly of metal-organic frameworks and graphene oxide as precursors for lithium-ion battery applications. J Nanopart Res 18:313CrossRefGoogle Scholar
  15. 15.
    Grishanov DA et al (2017) Graphene oxide-supported β-tin telluride composite for sodium-and lithium-ion battery anodes. Energ Technol 6:127–133CrossRefGoogle Scholar
  16. 16.
    Duraia E-SM, Niu S, Beall GW, Rhodes CP (2018) Humic acid-derived graphene-SnO2 nanocomposites for high capacity lithium-ion battery anodes. J Mater Sci Mater Electron 29:8456–8464CrossRefGoogle Scholar
  17. 17.
    Zhu S-C, Tao H-C, Yang X-L, Zhang L-L, Ni S-B (2015) Synthesis of N-doped graphene/SnS composite and its electrochemical properties for lithium ion batteries. Ionics 21:2735–2742CrossRefGoogle Scholar
  18. 18.
    Wang D-W, Fang H-T, Li F, Chen Z-G, Zhong Q-S, Lu GQ, Cheng H-M (2008) Aligned titania nanotubes as an intercalation anode material for hybrid electrochemical energy storage. Adv Funct Mater 18:3787–3793CrossRefGoogle Scholar
  19. 19.
    Fan S-S, Zhong H, Yu H-T, Lou M, Xie Y, Zhu Y-R (2017) Hollow and hierarchical Na2Li2Ti6O14 microspheres with high electrochemical performance as anode material for lithium-ion battery. Sci China Mater 60:427–437CrossRefGoogle Scholar
  20. 20.
    Han W, Qin X, Wu J, Li Q, Liu M, Xia Y, du H, Li B, Kang F (2018) Electrosprayed porous Fe3O4/carbon microspheres as anode materials for high-performance lithium-ion batteries. Nano Res 11:892–904CrossRefGoogle Scholar
  21. 21.
    Li D, Shi D, Liu Z, Liu H, Guo Z (2013) TiO2 nanoparticles on nitrogen-doped graphene as anode material for lithium ion batteries. J Nanopart Res 15:1674CrossRefGoogle Scholar
  22. 22.
    He D, Xue W, Zhao R, Hu W, Marsden AJ, Bissett MA (2018) Reduced graphene oxide/Fe-phthalocyanine nanosphere cathodes for lithium-ion batteries. J Mater Sci 53:9170–9179CrossRefGoogle Scholar
  23. 23.
    Liu S, Hou H, Liu X, Duan J, Yao Y, Liao Q (2017) High performance binder-free reduced graphene oxide nanosheets/Cu foam anode for lithium ion battery. J Porous Mater 24:141–147CrossRefGoogle Scholar
  24. 24.
    Jiao Z, Gao R, Tao H, Yuan S, Xu L, Xia S, Zhang H (2016) Intergrown SnO2-TiO2@graphene ternary composite as high-performance lithium-ion battery anodes. J Nanopart Res 18:307CrossRefGoogle Scholar
  25. 25.
    Zhang Q et al (2012) Synthesis and characterization of Li4Ti5O12/graphene composite as anode material with enhanced electrochemical performance. Ionics 19:717–723CrossRefGoogle Scholar
  26. 26.
    Wang J, Xie S, Cao D, Lu X, Meng L, Yang G, Wang H (2016) Facile synthesis of ultrafine SnO2 nanoparticles on graphene nanosheets via thermal decomposition of tin-octoate as anode for lithium ion batteries. J Nanopart Res 18:280CrossRefGoogle Scholar
  27. 27.
    Cai D, Lian P, Zhu X, Liang S, Yang W, Wang H (2012) High specific capacity of TiO2-graphene nanocomposite as an anode material for lithium-ion batteries in an enlarged potential window. Electrochim Acta 74:65–72CrossRefGoogle Scholar
  28. 28.
    Meng R, Hou H, Liu X, Duan J, Liu S (2015) Binder-free combination of graphene nanosheets with TiO2 nanotube arrays for lithium ion battery anode. J Porous Mater 23:569–575CrossRefGoogle Scholar
  29. 29.
    Yue P, Wang Z, Zhang Q, Yan G, Guo H, Li X (2013) Synthesis and electrochemical performance of LiNi0.6Co0.2Mn0.2O2/reduced graphene oxide cathode materials for lithium-ion batteries. Ionics 19:1329–1334CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.College of ScienceShenyang University of TechnologyShenyangChina

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