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In-situ grown ultrathin MoS2 nanosheets on MoO2 hollow nanospheres to synthesize hierarchical nanostructures and its application in lithium-ion batteries

  • Jingru Xie
  • Kunjie Zhu
  • Jie Min
  • Linyu Yang
  • Jianzhe Luo
  • Jun LiuEmail author
  • Ming Lei
  • Ruizhi Zhang
  • Lu Ren
  • Ziye Wang
Original Paper
  • 5 Downloads

Abstract

A unique hierarchical hollow-nanostructure consists of ultrathin MoS2 nanosheets and hollow MoO2 nanospheres has been designed as anode material for lithium batteries. And a simple process for producing ultrathin MoS2 nanosheets in-situ grown on hollow MoO2 nanospheres is reported. Such a hierarchical nanostructure has four advantages: Firstly, the high electric conductivity of the MoO2 core can effectively increase the performance of the composite. Secondly, the shell of MoS2 nanosheets with highly exposed active sites can improve the electrochemical reaction activity of this heterostructure. Thirdly, the reciprocal hybridization between the MoO2 core and MoS2 shell can availably prevent the aggregation of MoS2 nanosheets. Owing to the unique hierarchical MoO2@MoS2 hollow-nanostructure, it exhibits great electrochemical performance and can deliver reversible capacity as high as 820.7 mA h g−1 at a current density of 0.5 A g−1 after 100 cycles, while it is used as a new anode material for lithium-ion batteries.

Keywords

Transitional metal oxides and chalcogenides Ultrathin MoS2 nanosheets Hierarchical hollow nanostructures Lithium-ion batteries 

Notes

Funding information

This work is supported by the National Natural Science Foundation of China (Grant Nos. 51772331, 51472271), the National Basic Research Program of China (973 Program) grant No. 2013CB932901, and the Project of Innovation-driven Plan in Central South University (2016CX002).

Supplementary material

11581_2019_2863_MOESM1_ESM.docx (280 kb)
ESM 1 (DOCX 280 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Jingru Xie
    • 1
  • Kunjie Zhu
    • 1
  • Jie Min
    • 2
  • Linyu Yang
    • 3
  • Jianzhe Luo
    • 1
  • Jun Liu
    • 1
    Email author
  • Ming Lei
    • 4
  • Ruizhi Zhang
    • 1
  • Lu Ren
    • 1
  • Ziye Wang
    • 5
  1. 1.School of Materials Science and EngineeringCentral South UniversityChangshaChina
  2. 2.Research Institute of Tsinghua University in ShenzhenShenzhenChina
  3. 3.School of Physics and TechnologyXin Jiang University, UrumqiXinjiangChina
  4. 4.State Key Laboratory of Information Photonics and Optical Communications & School of ScienceBeijing University of Posts and TelecommunicationsBeijingChina
  5. 5.School of Mechanical Electronic & Information EngineeringChina University of Mining and TechnologyBeijingChina

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