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Ionics

, Volume 25, Issue 3, pp 1045–1055 | Cite as

Enhanced electrochemical performance of salen-type transition metal polymer with electron-donating substituents

  • Xinping Li
  • Jianling LiEmail author
  • Feiyu Kang
Original Paper
  • 32 Downloads

Abstract

Salen-type Schiff base transition metal monomers with substituents Ni (CH3-salen), Ni (CH3O-salen), and Ni (Cl-salen) have been synthesized and electro-polymerized onto the indium tin oxide substrate electrodes. The effect of electron-donating groups on the electrochemical performance of the polymer is studied. Electron-donating groups enhance the electrochemical activity of the salen-type Schiff base during the electropolymerization process. SEM images show that the morphology of poly [Ni (CH3O-salen)] is nanobelt with a width of 200–500 nm. The cyclic voltammetry plots indicate that the strong electron-donating methoxy group facilitates the polymerization of the salen-type Schiff base. Thus, Ni (CH3O-salen) shows a higher doping level than other three polymers. XPS measurement is conducted to investigate the polymerization process and the mechanism of energy storage. It is proved that the azomethine nitrogen group (−N=CH−) matters a lot in the polymerization and energy storage process. In brief, the azomethine nitrogen group was affected by the introduction of the electron-donating group so that extra redox peaks appear in the cyclic voltammetry plots. There is no chemical valence change of nickel, and the nickel atom worked as a bridge in the system. The electro-donating substituent group activates the benzene ring of the polymer and facilitates the charge transfer and leads to poly [Ni(CH3O-salen)] that exhibits the highest doping level, charge-transfer ability, and electrochemical capacity characteristics than the polymer with weaker electro-donating or electro-withdrawing substituents (polyNi(Cl-salen)). At the current density of 0.1 mA cm−2, the specific capacitance of poly [Ni(CH3O-salen)] is 270.1 F g−1, higher than that of poly [Ni(salen)](136.7 F g−1), poly [Ni(CH3-salen)](148.1 F g−1), and poly [Ni(Cl-salen)](106.0 F g−1).

Keywords

Schiff base Electron-donating substituent group Charge storage mechanism Supercapacitors 

Notes

Funding information

This work is financially supported by the National Natural Science Foundation of China (No. 51372021), and National Natural Science Foundation of China (No. 51772025 and No. 51572024).

Supplementary material

11581_2018_2819_MOESM1_ESM.pdf (1.3 mb)
ESM 1 (PDF 1322 kb)

References

  1. 1.
    Halim M, Liu G, Ardhi REA, Hudaya C, Wijaya O, Lee S, Kim A, Lee JK (2017) Pseudocapacitive characteristics of low-carbon silicon oxycarbide for lithium-ion capacitors. ACS Appl Mater Interfaces 24:20566–20576CrossRefGoogle Scholar
  2. 2.
    Zhou H, Ding X, Liu G, Jiang Y, Yin Z (2015) Electrochimica acta preparation and characterization of ultralong spinel lithium manganese oxide nano fiber cathode via electrospinning method. Electrochim Acta 152:274–279CrossRefGoogle Scholar
  3. 3.
    Woo J, Kim A, Kyu M, Lee S, Sun Y, Liu G, Kee J (2017) Cu 3 Si-doped porous-silicon particles prepared by simplified chemical vapor deposition method as anode material for high-rate and long- cycle lithium-ion batteries. J Alloys Compd 701:425–432CrossRefGoogle Scholar
  4. 4.
    Kim JY, Kim A, Liu G, Woo J, Kim H, Lee JK (2018) Li 4 SiO 4 - based artificial passivation thin film for improving interfacial stability of Li metal anodes. 10:8692–8701Google Scholar
  5. 5.
    Enggar R, Ardhi A, Liu G, Tran MX, Hudaya C, Kim JY, Yu H, Lee JK (2018) Self-relaxant superelastic matrix derived from. ACS Nano 12:5588–5604CrossRefGoogle Scholar
  6. 6.
    González A, Goikolea E, Andoni J, Mysyk R (2016) Review on supercapacitors : technologies and materials. Renew Sust Energ Rev 58:1189–1206CrossRefGoogle Scholar
  7. 7.
    Miller JR, Simon P (2008) Materials science: electrochemical capacitors for energy management. Science (80-. ) 321:651–652CrossRefGoogle Scholar
  8. 8.
    Salanne M, Rotenberg B, Naoi K, Kaneko K, Taberna P-L, Grey CP, Dunn B, Simon P (2016) Efficient storage mechanisms for building better supercapacitors. Nat Energy 1:16070CrossRefGoogle Scholar
  9. 9.
    Vilas-boas M, Santos IC, Henderson MJ, Freire C, Hillman AR, Vieil E (2003) Electrochemical behavior of a new precursor for the design of poly [Ni (salen)] -based modified electrodes. ACS Publ 19:7460–7468Google Scholar
  10. 10.
    Mendoza-Sánchez Y, Gogotsi B (2016) Synthesis of two-dimensional materials for capacitive energy storage. Adv Mater 28:6104–6135CrossRefGoogle Scholar
  11. 11.
    Augustyn V, Dunn B (2014) Pseudocapacitive oxide materials for high-rate electrochemical energy storage. Energy Environ Sci 7:1597–1614CrossRefGoogle Scholar
  12. 12.
    Sharma P, Bhatti TS (2010) A review on electrochemical double-layer capacitors. Energy Convers Manag 51:2901–2912CrossRefGoogle Scholar
  13. 13.
    Shukla AK, Banerjee A, Ravikumar MK, Jalajakshi A (2012) Electrochemical capacitors: technical challenges and prognosis for future markets. Electrochim Acta 84:165–173CrossRefGoogle Scholar
  14. 14.
    Yu G, Xie X, Pan L, Bao Z, Cui Y (2013) Hybrid nanostructured materials for high-performance electrochemical capacitors. Nano Energy 2:213–234CrossRefGoogle Scholar
  15. 15.
    Boota M, Hatzell KB, Alhabeb M, Kumbur EC, Gogotsi Y (2015) Graphene-containing flowable electrodes for capacitive energy storage. Carbon N Y 92:142–149CrossRefGoogle Scholar
  16. 16.
    Van Aken KL, Pérez CR, Oh Y, Beidaghi M, Joo Jeong Y, Islam MF, Gogotsi Y (2015) High rate capacitive performance of single-walled carbon nanotube aerogels. Nano Energy 15:662–669CrossRefGoogle Scholar
  17. 17.
    Amir FZ, Pham VH, Mullinax DW (2016) Enhanced performance of HRGO-RuO2, solid state flexible supercapacitors fabricated by electrophoretic deposition. Carbon 107:338–343CrossRefGoogle Scholar
  18. 18.
    Van Aken KL, Mathis T, Navarro-su AM (2018) Development of asymmetric supercapacitors with titanium carbide-reduced graphene oxide couples as electrodes. Electrochim Acta 259:752–761CrossRefGoogle Scholar
  19. 19.
    Zhang Y, Li J, Gao F, Kang F, Wang X, Ye F, Yang J (2012) Electropolymerization and electrochemical performance of salen-type redox polymer on different carbon supports for supercapacitors. Electrochim Acta 76:1–7CrossRefGoogle Scholar
  20. 20.
    Alekseeva EV, Chepurnaya IA, Malev VV, Timonov AM, Levin OV (2017) Polymeric nickel complexes with salen-type ligands for modi fi cation of supercapacitor electrodes: impedance studies of charge transfer and storage properties. Electrochim Acta 225:378–391CrossRefGoogle Scholar
  21. 21.
    Chepurnaya IA, Gaman’kov PV, Rodyagina TY, Vasil’eva SV, Timonov AM (2003) Electropolymerization of palladium and nickel complexes with Schiff bases: the effect of structure of the source compounds. Russ J Electrochem 39:314–317CrossRefGoogle Scholar
  22. 22.
    Novozhilova MV, Smirnova EA, Karushev MP, Timonov AM, Malev VV (2016) Synthesis and study of catalysts of electrochemical oxygen reduction reaction based on polymer complexes of nickel and cobalt with Schiff bases. Russ J Electrochem 52:1183–1190CrossRefGoogle Scholar
  23. 23.
    Chen C, Li X, Deng F, Li J (2016) RSC advances behavior of nickel Schiff base complexes with different groups between imine linkages. RSC Adv 6:79894–79899CrossRefGoogle Scholar
  24. 24.
    Tedim J, Gonc F, Pereira MFR, Figueiredo JL (2008) Preparation and characterization of poly [Ni(salen)(crown receptor)]/ multi-walled carbon nanotube composite films. Electrochim Acta 53:6722–6731CrossRefGoogle Scholar
  25. 25.
    Leung ACW, MacLachlan MJ (2007) Schiff base complexes in macromolecules. J Inorg Organomet Polym Mater 17:57–89CrossRefGoogle Scholar
  26. 26.
    Yan G, Li J, Zhang Y, Gao F, Kang F (2014) Electrochemical polymerization and energy storage for poly [Ni(salen)] as supercapacitor electrode material. J Phys Chem C 118:9911–9917CrossRefGoogle Scholar
  27. 27.
    Gao F, Li J, Kang F, Zhang Y, Wang X, Ye F, Yang J (2011) Preparation and characterization of a poly [Ni(salen )]/ multiwalled carbon nanotube composite by in situ electropolymerization as a capacitive material. J Phys Chem C 115:11822–11829CrossRefGoogle Scholar
  28. 28.
    Biesinger MC, Payne BP, Grosvenor AP, Lau LWM, Gerson AR, Smart RSC (2011) Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni. Appl Surf Sci 257:2717–2730CrossRefGoogle Scholar
  29. 29.
    Shagisultanova GA, Shchukarev AV, Semenistaya TV (2005) Possibilities of X-ray photoelectron spectroscopy in studying the structure and properties of polymers based on transition metal complexes with Schiff bases. Russ J Inorg Chem 50:912–924Google Scholar
  30. 30.
    Rodionova LI, Smirnov AV, Borisova NE, Khrustalev VN, Moiseeva AA, Grünert W (2012) Binuclear cobalt complex with Schiff base ligand: synthesis, characterization and catalytic properties in partial oxidation of cyclohexane. Inorg Chim Acta 392:221–228CrossRefGoogle Scholar
  31. 31.
    Grosvenor AP, Biesinger MC, Smart RSC, McIntyre NS (2006) New interpretations of XPS spectra of nickel metal and oxides. Surf Sci 600:1771–1779CrossRefGoogle Scholar
  32. 32.
    Casella IG, Contursi M (2013) Pulsed electrodeposition of nickel/palladium globular particles from an alkaline gluconate bath. An electrochemical, XPS and SEM investigation. J Electroanal Chem 692:80–86CrossRefGoogle Scholar
  33. 33.
    Cruz AI, Biernacki K, Magalh AL, Moura C, Hillman AR, Freire C (2010) Novel layer-by-layer interfacial [Ni(salen)] - polyelectrolyte hybrid films. Langmuir 26:10842–10853CrossRefGoogle Scholar
  34. 34.
    Choudhary A, Das B, Ray S (2016) Enhanced catalytic activity and magnetization of encapsulated nickel Schiff-base complexes in zeolite-Y: a correlation with the adopted. Dalton Trans 45:18967–18976CrossRefGoogle Scholar
  35. 35.
    Maschke M, Merz K, Shishkin OV, Zubatyuk RI, Metzler-Nolte N (2016) Influence of chlorine substituents on the aggregation behavior of chlorobenzoyl-substituted ferrocene derivates. Struct Chem 27:377–387CrossRefGoogle Scholar
  36. 36.
    Deng F, Li X, Ding F, Niu B, Li J (2018) Pseudocapacitive energy storage in Schiff base polymer with salphen-type ligands. J Phys Chem C 122:5325–5333CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.School of Metallurgical and Ecological EngineeringUniversity of Science and Technology BeijingBeijingChina
  2. 2.Lab of Advanced Materials, Department of Materials Science and EngineeringTsinghua UniversityBeijingChina

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