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Ionics

, Volume 25, Issue 6, pp 2645–2656 | Cite as

Montmorillonite incorporated polymethylmethacrylate matrix containing lithium trifluoromethanesulphonate (LTF) salt: thermally stable polymer nanocomposite electrolyte for lithium-ion batteries application

  • Emad M. MasoudEmail author
Original Paper
  • 85 Downloads

Abstract

High and low content of montmorillonite incorporated polymethylmethacrylate matrix in the presence of lithiumtriflate salt was investigated and studied. All samples were synthesized using the solution cast technique method. Different techniques (X-ray diffraction, FT-IR, DSC, TG, and SEM) were used for structure characterization. X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) analyses confirmed the complete dissolution of lithiumtriflate salt and intercalation of montmorillonite within the polymethylmethacrylate matrix. The different contents of montmorillonite showed different behaviors in both of structure and properties. The sample containing the low content of 5 wt% montmorillonite showed the highest AC- conductivity value (σAc = 2.09 × 10−6 Ω−1.cm−1, at room temperature) with a big difference to the other ones. The same sample also showed a good thermal stability (Td = 378 °C). Electrochemical stability of the same sample was also studied. All results were collected and discussed.

Graphical abstract

Low MMT content incorporated PMMA matrix containing LTF salt: polymer nanocomposite electrolyte exhibiting good conductivity and thermally stable behavior.

Keywords

Montmorillonite Electrical properties Polymer nanocomposites electrolytes Electrochemical stability Lithium ion batteries 

Notes

Acknowledgments

The author (Emad M. Masoud) of this research paper would like to thank the science and technology development fund (STDF), Egypt, (http://www.stdf.org.eg/index.php/en/) for the financial support of this scientific research work through Short –Term Fellowship (STF) Project (Project ID: 23173).

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Chemistry Department, Faculty of scienceBenha UniversityBenhaEgypt

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