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Ionics

, Volume 25, Issue 3, pp 1177–1185 | Cite as

Preparation and application of malachite green molecularly imprinted/gold nanoparticle composite film–modified glassy carbon electrode

  • Yaqing Xu
  • Zhiyue Gao
  • Wen ChenEmail author
  • Er WangEmail author
  • Yan Li
Original Paper
  • 48 Downloads

Abstract

A kind of new malachite green (MG) polypyrrole (PPy) molecularly imprinted (MIP)/gold nanoparticle composite (AuNPs) film–modified glassy carbon electrode (MG-MIPPPy/AuNPs/GCE) was prepared by potentiostatic deposition of gold nanoparticle on glassy carbon electrode at − 0.2 V (vs. SCE) for 100 s, pyrrole (Py) as monomer, and MG as template molecule (molar ratio = 1:1) by cyclic voltammetry (CV) electropolymerization. And various modified electrodes were characterized by SEM and EIS and CV methods. Potassium ferricyanide was used as a probe; the concentration of MG was indirectly detected by the linear relationship between the current change value (ΔIDPV) and the logarithm value of concentration of MG. Under the optimal conditions, there was a linear relationship between the ΔIDPV and the negative logarithm of concentration in the range of 2.73 × 10−9 M ~ 2.74 × 10−6 M (R = 0.9961). The detection limit is 3.57 × 10−11 M (S/N = 3). The sample recovery was 98.82 to 103.38%. These analysis results of real samples were satisfactory.

Keywords

Molecularly imprinted polymer Gold nanoparticles Malachite green Glassy carbon electrode 

Notes

References

  1. 1.
    Culp SJ, Mellick PW, Trorrer RW (2006) Carcinogenicity of malachite green chloride and leucomalachite green in B6C3F1 mice and F344 rats. Food Chem Toxicol 44:1204–1212CrossRefGoogle Scholar
  2. 2.
    Program NT (2005) Toxicology and carcinogenesis studies of malachite green chloride and leucomalachite green. (CAS NOS. 569–64-2 and 129–73-7) in F344/N rats and B6C3F1 mice (feed studies). Natl Toxicol Program Tech Rep 527:1–312Google Scholar
  3. 3.
    Wang LL, Feng XP, Hu EP (2007) Survey of malachite green residues in aquatic foods and pool water from restaurant in Zhuhai. Chin J Health Lab Technol 17:1687–1689Google Scholar
  4. 4.
    Hernando MD, Mezcua M, Suárez-Barcena JM (2006) Liquid chromatography with time-of-flight mass spectrometry for simultaneous determination of chemotherapeutant residues in salmon. Anal Chim Acta 562:176–178CrossRefGoogle Scholar
  5. 5.
    Chen G, Miao S (2010) HPLC determination and MS confirmation of malachite green, gentian violet, and their leuco metabolite residues in channel catfish muscle. J Agric Food Chem 58:7109–7114CrossRefGoogle Scholar
  6. 6.
    Sadi A, Leonardi LS, Cury J (2014) Graphene oxide magnetic nanocomposites for the preconcentration of trace amounts of malachite green from fish and water samples prior to determination by fiber optic-linear array detection spectrophotometry. Anal Methods 6:7744–7751CrossRefGoogle Scholar
  7. 7.
    Liu LJ (2011) Time-Offset Compensation Based Time Synchronization Approach for Wireless Sensor Network. Chin J Spectrosc Lab 28:41–46Google Scholar
  8. 8.
    Xing W, He L, Yang H, Sun C, Li D, Yang X, Li Y, Deng A (2009) Development of a sensitive and group-specific polyclonal antibody-based enzyme-linked immunosorbent assay (ELISA) for detection of malachite green and leucomalachite green in water and fish samples. J Sci Food Agric 89:2165–2173CrossRefGoogle Scholar
  9. 9.
    Wang F, Wang H, Shen Y et al (2016) Bispecific Monoclonal Antibody-Based Multianalyte ELISA for Furaltadone Metabolite, Malachite Green, and Leucomalachite Green in Aquatic Products. J Agric Food Chem 64:8054–8061CrossRefGoogle Scholar
  10. 10.
    Zhu D, Li QQ, Pan XM et al (2016) A sensitive electrochemical impedance immunosensor for determination of malachite green and leucomalachite green in the aqueous environment. Anal Bioanal Chem 408:5593–5600CrossRefGoogle Scholar
  11. 11.
    Hou J, Bei F, Wang M, Ai S (2013) Electrochemical determination of malachite green at graphene quantum dots–gold nanoparticles multilayers–modified glassy carbon electrode. J Appl Electrochem 43:689–696CrossRefGoogle Scholar
  12. 12.
    Liu YY, Ning BA, Bai JL, et al. (2014) AuNPs-chitosan/MWNTs modified GCE used for detection of trace malachite green in water. J Food Saf Qual 5:1468–1474Google Scholar
  13. 13.
    Sacara AM, Cristea C, Muresan LM (2017) Electrochemical detection of Malachite Green using glassy carbon electrodes modified with CeO 2 nanoparticles and Nafion. J Electroanal Chem 792:23–30CrossRefGoogle Scholar
  14. 14.
    Yi H, Qu W, Huang W (2008) Electrochemical determination of malachite green using a multi-wall carbon nanotube modified glassy carbon electrode. Microchimica Acta 160(1-2): 291–296CrossRefGoogle Scholar
  15. 15.
    Tan F, Cong LC, Li XN et al (2016) An electrochemical sensor based on molecularly imprinted polypyrrole/graphene quantum dots composite for detection of bisphenol A in water samples. Sensors Actuators B Chem 233:599–606CrossRefGoogle Scholar
  16. 16.
    Silva Hd, Pacheco J, Silva J (2015) Molecularly imprinted sensor for voltammetric detection of norfloxacin. Sensors Actuators B Chem 219:301–307CrossRefGoogle Scholar
  17. 17.
    Sharafzadeh S, Nezamzadeh-Ejhieh A (2015) Using of anionic adsorption property of a surfactant modified clinoptilolite nano-particles in modification of carbon paste electrode as effective ingredient for determination of anionic ascorbic acid species in presence of cationic dopamine species. Electrochim Acta 184:371–380CrossRefGoogle Scholar
  18. 18.
    Mahdavi M, Nezamzadeh-Ejhieh A (2017) An aluminum selective electrode via modification of PVC membrane by modified clinoptilolite nanoparticles with hexadecyltrimethyl ammonium bromide (HDTMA-Br) surfactant containing Arsenazo III. J Colloid Interface Sci 494:317–324CrossRefGoogle Scholar
  19. 19.
    Hasheminejad M, Nezamzadeh-Ejhieh A (2015) A novel citrate selective electrode based on surfactant modified nano-clinoptilolite. Food Chem 172:794–801CrossRefGoogle Scholar
  20. 20.
    Nosuhi M, Nezamzadeh-Ejhieh A (2018) An indirect application aspect of zeolite modified electrodes for voltammetric determination of iodate. J Electroanal Chem 810:119–128CrossRefGoogle Scholar
  21. 21.
    Kan X, Liu T, Zhou H (2010) Molecular imprinting polymer electrosensor based on gold nanoparticles for theophylline recognition and determination. Microchim Acta 171:423–429CrossRefGoogle Scholar
  22. 22.
    Yola M L, Atar N, Eren T, et al. (2015) Correction: Sensitive and selective determination of aqueous triclosan based on gold nanoparticles on polyoxometalate/reduced graphene oxide nanohybrid. Rsc Advances 5:65953–65962CrossRefGoogle Scholar
  23. 23.
    Stobiecka M, Deeb J, Hepel M (2009) Molecularly Templated Polymer Matrix Films for Biorecognition Processes: Sensors for Evaluating Oxidative Stress and Redox Buffering Capacity. ECS Trans 19:15–32CrossRefGoogle Scholar
  24. 24.
    Zhang J, Wang Y, Lv R (2010) Electrochemical tolazoline sensor based on gold nanoparticles and imprinted poly-aminothiophenol film. Electrochima Acta 55:4039–4044CrossRefGoogle Scholar
  25. 25.
    Chao ZG, Yong S, Dong ZQ, et al. (2014) Study on bisphenol A imprinted sensor based on the film of gold nanoparticles. J Funct Mater 45:01099–01103Google Scholar
  26. 26.
    Riskin M, Telvered R, Frasconi M (2010) Stereoselective and chiroselective surface plasmon resonance (SPR) analysis of amino acids by molecularly imprinted Au-nanoparticle composites. Chem Eur J 16:7114–7120CrossRefGoogle Scholar
  27. 27.
    Tan F, Zhao Q, Teng F, Sun D, Gao J, Quan X, Chen J (2014) Molecularly imprinted polymer/mesoporous carbon nanoparticles as electrode sensing material for selective detection of ofloxacin. Mater Lett 129:95–97CrossRefGoogle Scholar
  28. 28.
    Nosuhi M, Nezamzadeh-Ejhieh A (2018) A sensitive and simple modified zeolitic carbon paste electrode for indirect voltammetric determination of nitrate. Ionics 24:2135–2145CrossRefGoogle Scholar
  29. 29.
    Zhao WR, Kang TF, Lu LP, Shen FX, Cheng SY (2017) A novel electrochemical sensor based on gold nanoparticles and molecularly imprinted polymer with binary functional monomers for sensitive detection of bisphenol A. J Electroanal Chem 786:102–111CrossRefGoogle Scholar
  30. 30.
    Xue F, Gao ZY, Sun XM (2015) Electrochemical determination of environmental hormone nonylphenol based on composite film modified gold electrode. J Electrochem Soc 162:H338–H344CrossRefGoogle Scholar
  31. 31.
    Kiss L, David V, David LG et al (2016) Electropolymerized molecular imprinting on glassy carbon electrode for voltammetric detection of dopamine in biological samples. Talanta 160:489–498CrossRefGoogle Scholar
  32. 32.
    Wang F, Zhu LH, Zhang JD (2014) Electrochemical sensor for levofloxacin based on molecularly imprinted polypyrrole–graphene–gold nanoparticles modified electrode. Sensors Actuators B Chem 192:642–647CrossRefGoogle Scholar
  33. 33.
    Amani-Beni Z, Nezamzadeh-Ejhieh A (2018) NiO nanoparticles modified carbon paste electrode as a novel sulfasalazine sensor. Anal Chim Acta 1031:47–59CrossRefGoogle Scholar
  34. 34.
    Ji Z, Chen W, Wang E (2017) Electropolymerized Molecular Imprinting & Graphene Modified Electrode for Detection of Melamine. Int J Electrochem Sci 12:11942–11954CrossRefGoogle Scholar
  35. 35.
    Zhou J, He XW, Li YJ (1999) Binding study on 5,5-diphenylhydantoin imprinted polymer constructed by utilizing an amide functional group1Project 29775011 supported by National Natural Science Foundation of China.1. Anal Chim Acta 394:353–359CrossRefGoogle Scholar
  36. 36.
    Wang CL, Hu XL, Ping G (2015) Superparamagnetic Molecularly Imprinting Polymers for Adsorbent and Separation Pentapeptides by Surface ATRP. Sep Sci Technol 50:1768–1775CrossRefGoogle Scholar
  37. 37.
    Niknezhadi A, Nezamzadeh-Ejhieh A (2017) A novel and sensitive carbon paste electrode with clinoptilolite nano-particles containing hexadecyltrimethyl ammonium surfactant and dithizone for the voltammetric determination of Sn(II). J Colloid Interface Sci 501:321–329CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.College of Materials and Chemistry & Chemical EngineeringChengdu University of TechnologyChengduPeople’s Republic of China
  2. 2.Mineral Resources Chemistry Key Laboratory of Sichuan Higher Education InstitutionChengduPeople’s Republic of China
  3. 3.Sichuan Provincial Chuanjian Institute of Investigation and DesignChengduPeople’s Republic of China
  4. 4.Analysis Laboratory 280 Research Institute of Nuclear IndustryGuanghanPeople’s Republic of China

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