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Ionics

, Volume 25, Issue 6, pp 2563–2574 | Cite as

Effects of functional binders on electrochemical performance of graphite anode in potassium-ion batteries

  • Xuan Wu
  • Zheng XingEmail author
  • Yi Hu
  • Ya Zhang
  • Yongwen Sun
  • Zhicheng JuEmail author
  • Jinlong LiuEmail author
  • Quanchao Zhuang
Original Paper
  • 164 Downloads

Abstract

Electrochemical properties of the graphite electrode in potassium-ion batteries (KIBs) depend on the selection of the proper binder. The results in our experiment show that compared with the conventional binders of poly(vinylidene fluoride) (PVDF) and carboxymethylcellulose sodium (CMCNa), the polyacrylate sodium (PAANa) binder can greatly improve the electrochemical performance during the potassiation and depotassiation. Specifically, the initial discharge and charge capacity of the graphite-PAANa electrode are 415.4 and 238.5 mAh g−1, respectively. Even after 50 cycles, it still has a high charge capacity retention of 96.9%. Considering the good swelling property of the PAANa binder, the adhesive and mechanical strength of composite electrodes are obviously enhanced. In addition, the graphite-PAANa electrode can also decrease the electrolyte decomposition on the graphite particle surface and restrain the capacity fading resulted from the repeatedly volume expansion.

Keywords

Potassium-ion battery Graphite anode Binder Electrochemical performance Diffusion coefficient 

Notes

Funding information

The authors would like to thank the financial supports by the Fundamental Research Funds for the Central Universities (2012LWB05).

Supplementary material

11581_2018_2763_MOESM1_ESM.docx (655 kb)
ESM 1 (DOCX 655 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.The Jiangsu Province Engineering Laboratory of High Efficient Energy Storage Technology and Equipments, School of Materials Science and EngineeringChina University of Mining and TechnologyXuzhouChina
  2. 2.The Xuzhou City Key Laboratory of High Efficient Energy Storage Technology and EquipmentsChina University of Mining and TechnologyXuzhouChina

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