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Ionics

, Volume 24, Issue 10, pp 3281–3285 | Cite as

MOF-derived N-doped porous carbon anchoring Sn4P3 as an anode material for sodium ion batteries

  • Erzhuang Pan
  • Yuhong Jin
  • Chenchen Zhao
  • Qianqian Chang
  • Mengqiu Jia
Short Communication
  • 230 Downloads

Abstract

In this paper, MOF-derived N-doped porous carbon anchoring Sn4P3 (Sn4P3@NPC) composite is prepared via a low-temperature phosphidation reaction with SnO2@NPC composite as the precursor. The as-prepared Sn4P3@NPC composite exhibit a high stable capacity of 319 mAh g−1 at 0.1 A g−1 after 100 cycles and improved rate performance (the capacities of 365, 322, 260, 204, and 146 mAh g−1 at 0.1, 0.2, 0.5, 1, and 2 A g−1, respectively) for sodium ion batteries. The good electrochemical sodium storage performance of the Sn4P3@NPC composite anodes can be ascribed to the synergistic effect between porous N-doped carbon and high-active Sn4P3 nanoparticles.

Keywords

Sn4P3 Metal-organic frameworks N-doped porous carbon Nanocrystalline materials Energy storage and conversion Sodium-ion batteries 

Notes

Acknowledgments

This work was supported by the Science and Technology Program of Beijing Municipal Education Commission (SQKM201710005007) and Basic Research Foundation of Beijing University of Technology (105000546317500).

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Beijing Key Laboratory of Electrochemical Process and Technology for MaterialsBeijing University of Chemical TechnologyBeijingChina
  2. 2.Beijing Guyue New Materials Research InstituteBeijing University of TechnologyBeijingChina

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