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Ionics

, Volume 25, Issue 2, pp 827–834 | Cite as

Facile synthesis and electrochemical properties of LiNi0.8Co0.15Al0.05O2 with enlarged exposed active planes for Li-ion batteries

  • Hang Dong
  • Shaomin Li
  • Hao Liu
  • Jun Mei
  • Heng LiuEmail author
  • Guobiao LiuEmail author
Original Paper
  • 105 Downloads

Abstract

Because enlarged exposed active planes facilitate the improvement of the rate capability of layered cathode material by providing more points for Li+ intercalation/de-intercalation, LiNi0.8Co0.15Al0.05O2 layered cathode material with enlarged exposed {010} active planes is desirable. In this article, micro-sized LiNi0.8Co0.15Al0.05O2 particles possessing enlarged exposed {010} active planes have been synthesized using Ni0.842Co0.158(OH)2 precursor prepared by an improved co-precipitation method. As-prepared LiNi0.8Co0.15Al0.05O2 demonstrates a good rate capability. The reversible capacity is 103 mAh g−1 at 10 °C, which is explained by the enhanced Li+ diffusion coefficient detected by CV and GITT measurements and reduced charge transfer resistance calculated by EIS tests. Moreover, the as-prepared LiNi0.8Co0.15Al0.05O2 also displays a good cycling stability. The capacity retention after 100 cycles at 0.2 °C is 85%. This good cycling stability can be ascribed to the porous structure of LiNi0.8Co0.15Al0.05O2 which provides a buffer area for volume expansion of the primary particles during cycling.

Keywords

Lithium-ion battery LiNi0.8Co0.15Al0.05O2 Co-precipitation Exposed {010} planes Rate capability 

Notes

Funding information

The research was financially supported by the Sichuan Provincial Key Technology R&D Program (2016GZ0299).

Supplementary material

11581_2018_2620_MOESM1_ESM.doc (34 mb)
ESM 1 (DOC 34789 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.College of Materials Science and EngineeringSichuan UniversityChengduChina
  2. 2.Chengdu Green Energy and Green Manufacturing Technology R&D Center, Chengdu Development Center of Science and TechnologyChina Academy of Engineering PhysicsChengduChina

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