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Ionics

, Volume 25, Issue 1, pp 111–123 | Cite as

Electrochemical impedance spectroscopy characterization and parameterization of lithium nickel manganese cobalt oxide pouch cells: dependency analysis of temperature and state of charge

  • Rahul GopalakrishnanEmail author
  • Yi Li
  • Jelle Smekens
  • Ahmed Barhoum
  • Guy Van Assche
  • Noshin Omar
  • Joeri Van Mierlo
Original Paper
  • 154 Downloads

Abstract

Characterizing lithium-ion batteries is of prime importance as it helps in understanding the safety, working temperature, voltage range, and power capabilities. Based on these results, we can then choose operating conditions which include safety protocols, application, and working environment. In this study, EIS studies of commercially available 20-Ah lithium-ion battery and a 28-Ah prototype cell with nickel manganese cobalt oxide (NMC)/graphite chemistry are used to determine the contribution of temperature and state of charge (SoC) towards the electrochemical impedance spectroscopy. These cells are manufactured for electric vehicle (EV) application. The electrode structure, particle size, stacking of the electrodes, and other entities for both the cells are provided to compare the similarities and differences between both the cells. Equivalent circuit modeling is used to analyze and comprehend the variation in impedance spectrum obtained for both the cells. It is observed that the ohmic resistance varies with both temperature and SoC and the variation with temperature is more significant for the prototype cell. The prototype cell showed better charge-transfer characteristics at lower temperatures when compared to the commercial cell.

Keywords

State of charge Separators Electrolytes Electrochemical impedance spectroscopy Electric vehicle 

Notes

Acknowledgements

We acknowledge the support to our research team from “Flanders Make.”

Funding information

The research leading to these results has received funding from the [European Union’s] [European Atomic Energy Community’s] Seventh Framework Programme ([FP7/2007-2013] [FP7/2007-2011]) under grant agreement no. 608936 (see Article II.30. of the Grant Agreement).

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Rahul Gopalakrishnan
    • 1
    • 2
    Email author
  • Yi Li
    • 1
    • 2
  • Jelle Smekens
    • 1
    • 2
  • Ahmed Barhoum
    • 3
    • 4
  • Guy Van Assche
    • 3
  • Noshin Omar
    • 1
    • 2
  • Joeri Van Mierlo
    • 1
    • 2
  1. 1.Mobility, Logistic and Automotive Technology Research Center (MOBI), Department of Electrical Engineering and Energy Technology (ETEC)ElseneBelgium
  2. 2.Flanders MakeLeuvenBelgium
  3. 3.Department of Materials and ChemistryVrije Universiteit Brussel (VUB)BrusselsBelgium
  4. 4.Chemistry Department, Faculty of ScienceHelwan UniversityHelwanEgypt

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