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Ionics

, Volume 25, Issue 1, pp 51–59 | Cite as

Li1.1Na0.1Mn0.534Ni0.133Co0.133O2 as cathode with ameliorated electrochemical performance based on dual Li+/Na+ electrolyte

  • Yu Zhou
  • Xianhua HouEmail author
  • Kaixiang Shen
  • Shaofeng Wang
  • Fuming Chen
  • Yajie Li
  • Hedong Chen
  • Bei Wang
Original Paper
  • 83 Downloads

Abstract

Layered Li-rich cathode materials Li1.2Mn0.534Ni0.133Co0.133O2 (LNCMN-0) and Na doping Li1.1Na0.1Mn0.534Ni0.133Co0.133O2 (LNCMN-0.1) are prepared successfully by a co-precipitation method and several consecutive calcination treatments. Besides, the phase structure, morphology, and electrochemical properties of the four samples are studied in detail using X-ray diffraction (XRD), scanning electron microscope (SEM), galvanostatic charge-discharge test, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). Although the discharge capacity of spherical LNCMN-0.1 decreases slightly at 0.1 C (1 C = 250 mA g−1), compared to the pristine LNCMN-0, it is noteworthy that the LNCMN-0.1 matched with dual Li+/Na+ electrolyte exhibit superior stability performance at 1 C, as well as enhanced rate capability. The LNCMN-0.1 (Li+/Na+) delivers an initial discharge specific capacity of 267.61 mAh g−1 at 0.1 C between 2.0 and 4.8 V at room temperature and initial coulombic efficiency of 83.51%, which is higher than the LNCMN-0 samples (76.42 and 81.54%). The experimental results verify that Na doping combined with dual Li+/Na+ electrolyte can generate a synergistic effect, which is a promising idea to ameliorate the electrochemical performance for this material.

Keywords

Li-rich layered cathode materials Na doping Dual Li+/Na+ electrolyte Synergistic effect 

Notes

Funding information

This work is financially supported by the union project of National Natural Science Foundation of China and Guangdong Province (No. U1601214), the Scientific and Technological Plan of Guangdong Province (2016B010114002, 2017B090901027), the Scientific and Technological Plan of Guangzhou City (201607010322), the LanDun information security technology open fund (LD20170210), and the Innovation Project of Graduate School of South China Normal University (2017LKXM081).

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Yu Zhou
    • 1
    • 2
  • Xianhua Hou
    • 1
    • 2
    Email author
  • Kaixiang Shen
    • 1
    • 2
  • Shaofeng Wang
    • 1
    • 2
  • Fuming Chen
    • 1
    • 2
  • Yajie Li
    • 1
    • 2
  • Hedong Chen
    • 1
    • 2
  • Bei Wang
    • 1
    • 2
  1. 1.Guangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials, School of Physics and Telecommunication EngineeringSouth China Normal UniversityGuangzhouPeople’s Republic of China
  2. 2.Guangdong Engineering Technology Research Center of Efficient Green Energy and Environment Protection MaterialsGuangzhouPeople’s Republic of China

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