, Volume 25, Issue 1, pp 253–264 | Cite as

Synthesis of PtCo/ZSM-5/C electrocatalyst and electrochemical activity

  • Ana Maria RoccoEmail author
  • Karen Vieira Melo
  • Claudio Jose de Araújo Mota
  • Marcus V. David
  • Isis Nunes de Souza
Original Paper


This study presents the synthesis and electrochemical characterization of a bimetallic PtCo electrocatalyst supported in a ZSM-5 zeolite and XC-72R Vulcan carbon 50 wt.% composite. Two synthesis methodologies were tested: reduction mediated by ethylene glycol and NaBH4. The catalyst electroactivity was assessed by measuring the electrochemical surface area, ESA, and the electrooxidation of methanol was evaluated by cyclic voltammetry and chronoamperometry in acid medium. The nanoelectrocatalysts were obtained with average particle size nearly 3.0 nm and ESA up to 44.7 m2 g−1, indicating the effectiveness of the synthesis methods and of the composite ZSM-5/C used as catalyst support. XPS studies showed that PtCo alloy was obtained by NaBH4 reduction. All samples presented good tolerance to carbonaceous species indicated by jf/jb ratio greater than 1 in methanol oxidation activity test. The 1-h chronoamperometry tests corroborated these results. Some samples obtained in the present work showed higher current density in steady state compared to the commercial sample used as reference and analyzed under the same experimental process. The results showed that the zeolite support was effective at improving catalytic activity independently of the alloy PtCo presence on the catalyst surface.


Catalyst Zeolite Electrooxidation Methanol oxidation Electrocatalyst 



The authors would like to thank Oleksii Kuznetsov for XRF measurements and CENABIO for TEM images.

Funding information

This work was supported by the Fundação Carlos Chagas Filho de Amparo à Pesquisa do Estado do Rio de Janeiro (Nos. E-26/110.665/2013 and E-26/010.001095/2015).


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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Ana Maria Rocco
    • 1
    Email author
  • Karen Vieira Melo
    • 1
  • Claudio Jose de Araújo Mota
    • 2
  • Marcus V. David
    • 1
    • 3
  • Isis Nunes de Souza
    • 1
  1. 1.Grupo de Materiais Condutores de Energia, Escola de QuímicaUniversidade Federal do Rio de JaneiroRio de JaneiroBrazil
  2. 2.Instituto de QuímicaUniversidade Federal do Rio de JaneiroRio de JaneiroBrazil
  3. 3.Divisão de Metrologia de Materiais (DIMAT), Instituto Nacional de Metrologia, Qualidade e Tecnologia (INMETRO)Duque de CaxiasBrazil

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