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Ionics

, Volume 24, Issue 10, pp 2983–2993 | Cite as

TiN synergetic with micro-/mesoporous carbon for enhanced performance lithium–sulfur batteries

  • Qiong Tang
  • Heqin Li
  • Yuanyuan Pan
  • Jing Zhang
  • Zhiwei Lin
  • Yong Chen
  • Xia Shu
  • Weiyu Qi
Original Paper
  • 186 Downloads

Abstract

Porous carbon has high specific area and total pore volume but weak interaction with dissolved polysulfides. Conductive polar metal compound has strong chemical adsorption of polysulfides but difficult to attain high porosity to encapsulate sulfur series. Instead of efforts on the cathode, we prepared a composite made up of titanium nitride and three-dimensional micro-/mesoporous carbon by a facile and economic way. This composite was coated on the commercial Celgard separator as a polysulfide interceptor to enhance the performances of lithiumsulfur battery. The strategy exerts the synergetic merits of porosity, chemical adsorption, physical interception, and benign conductivity. The hierarchical carbon possesses a high specific surface area of 1571 m2/g and total pore volume of 1.56 cm3/g with the pore size centered at 1.27 and 5.30 nm. TiN can immobilize sulfur intermediates by strong chemical interaction. In addition, excellent electrical conductivity of TiN facilitates redox kinetics. The pure sulfur cathode with the modified separator delivers high initial capacity of 1130 mAh/g at 1 C (1 C = 1675 mAh/g) and retains 500 mAh/g after 400 cycles, demonstrating superior cycling stability, rate capabilities. Discharge-charge profiles, electrochemical impedance spectrum, and cyclic voltammetry curves of batteries were investigated to support the prominent electrochemistry of the material. Further analysis and observation on the modified separator disassembled from the coin cells after cycling were conducted to probe the evolution and reaction mechanism of the coating.

Keywords

Lithium–sulfur battery TiN Porosity Polarity Adsorption 

Notes

Acknowledgements

The authors gratefully acknowledge the support of the “Strategic Priority Research Program” of the Chinese Academy of Science (No. XDA03040000), and the “Student’s Platform for Innovation and Entrepreneurship Training Program” of the Ministry of Education of China (No. 201710359071).

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Qiong Tang
    • 1
    • 2
  • Heqin Li
    • 1
  • Yuanyuan Pan
    • 1
  • Jing Zhang
    • 1
    • 2
  • Zhiwei Lin
    • 1
  • Yong Chen
    • 1
  • Xia Shu
    • 1
  • Weiyu Qi
    • 1
  1. 1.School of Materials Science and EngineeringHefei University of TechnologyHefeiChina
  2. 2.School of Electronic Science and Applied PhysicsHefei University of TechnologyHefeiChina

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